@article{Campbell:2014:10.1039/c4ta00628c,
author = {Campbell, J and Szekely, G and Davies, RP and Braddock, DC and Livingston, AG},
doi = {10.1039/c4ta00628c},
journal = {Journal of Materials Chemistry A},
pages = {9260--9271},
title = {Fabrication of hybrid polymer/metal organic framework membranes: mixed matrix membranes versus in situ growth},
url = {http://dx.doi.org/10.1039/c4ta00628c},
volume = {2},
year = {2014}
}

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TY  - JOUR
AB  - Hybrid polymer/metal organic framework (MOF) membranes have been prepared using either a mixed matrix membrane (MMM) or in situ growth (ISG) approach and were evaluated for application in organic solvent nanofiltration (OSN). MMMs were produced by dispersing pre-formed particles of the MOF HKUST-1 in polyimide P84 dope solutions. MMMs demonstrated both (i) higher rejections of styrene oligomers and (ii) lower flux decline than the polymeric control membranes. Furthermore, an alternative hybrid membrane fabrication methodology – in situ growth (ISG) of HKUST-1 in integrally skinned asymmetric polymer membrane supports – has been successfully demonstrated. Ultrafiltration support membranes were submerged in HKUST-1 precursor solutions in order to promote the growth of MOF within the porous structure of the polymer membranes. The presence of HKUST-1 in the membranes was proven with X-ray powder diffraction (XRPD). Energy-dispersive X-ray spectroscopy (EDX) was used to reveal the distribution of HKUST-1 throughout the ISG membranes, and was found to be even across the surface and throughout the cross-section. The ISG membranes also had higher solute rejections and lower flux decline than the MMMs.
AU  - Campbell,J
AU  - Szekely,G
AU  - Davies,RP
AU  - Braddock,DC
AU  - Livingston,AG
DO  - 10.1039/c4ta00628c
EP  - 9271
PY  - 2014///
SN  - 2050-7488
SP  - 9260
TI  - Fabrication of hybrid polymer/metal organic framework membranes: mixed matrix membranes versus in situ growth
T2  - Journal of Materials Chemistry A
UR  - http://dx.doi.org/10.1039/c4ta00628c
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000336850600040&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - https://pubs.rsc.org/en/content/articlelanding/2014/TA/C4TA00628C#!divAbstract
VL  - 2
ER  - 

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