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@article{Banks:2020:10.1371/journal.pone.0229925,
author = {Banks, AM and Song, L and Challis, GL and Bailey, AM and Foster, GD},
doi = {10.1371/journal.pone.0229925},
journal = {PLoS One},
pages = {1--9},
title = {Bovistol B, bovistol D and strossmayerin: Sesquiterpene metabolites from the culture filtrate of the basidiomycete Coprinopsis strossmayeri},
url = {http://dx.doi.org/10.1371/journal.pone.0229925},
volume = {15},
year = {2020}
}

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TY  - JOUR
AB  - Basidiomycete fungi are a rich source of natural products with a diverse array of potentially exploitable bioactivities. Two dimeric sesquiterpenes, bovistol B (1) and D (2), and one monomeric sesquiterpene, strossmayerin (7), were isolated from the culture filtrate of the basidiomycete fungus Coprinopsis strossmayeri. The structures were determined through a combination of MS and 1D/2D NMR spectroscopic techniques. Likely monomeric precursors, identified on the basis of HRMS analysis, allow a plausible biosynthetic pathway to be proposed for the biosynthesis of 1 and 2, involving the dimerisation of the monomer through a hetero-Diels-Alder mechanism. A gene cluster, including a putative sesquiterpene 1–11 cyclase, was identified through phylogenetic and RNA-seq analysis, and is proposed to be responsible for the biosynthesis of 1 and 2.
AU  - Banks,AM
AU  - Song,L
AU  - Challis,GL
AU  - Bailey,AM
AU  - Foster,GD
DO  - 10.1371/journal.pone.0229925
EP  - 9
PY  - 2020///
SN  - 1932-6203
SP  - 1
TI  - Bovistol B, bovistol D and strossmayerin: Sesquiterpene metabolites from the culture filtrate of the basidiomycete Coprinopsis strossmayeri
T2  - PLoS One
UR  - http://dx.doi.org/10.1371/journal.pone.0229925
UR  - https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0229925
UR  - http://hdl.handle.net/10044/1/82598
VL  - 15
ER  -

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