Imperial College London

ProfessorAnthonyKucernak

Faculty of Natural SciencesDepartment of Chemistry

Professor of Physical Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 5831anthony Website

 
 
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Assistant

 

Mr Stuart Haylock +44 (0)20 7594 5717

 
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Location

 

433ChemistrySouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Malko:2017:10.1016/j.elecom.2017.09.004,
author = {Malko, D and Kucernak, ARJ},
doi = {10.1016/j.elecom.2017.09.004},
journal = {Electrochemistry Communications},
pages = {67--71},
title = {Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions.},
url = {http://dx.doi.org/10.1016/j.elecom.2017.09.004},
volume = {83},
year = {2017}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Heat treated Fe-N/C materials which are highly effective oxygen reduction catalysts in alkaline and acid, show a significant kinetic isotope effect (KIE). The values in acid (~3.4) and alkaline (~2.5) are much larger than the value for the metal free catalyst in acid (~1.8) suggesting that the rate determining step (RDS) is a proton coupled electron transfer in acid with a significant pathway involving a proton independent step under an alkaline environment
AU - Malko,D
AU - Kucernak,ARJ
DO - 10.1016/j.elecom.2017.09.004
EP - 71
PY - 2017///
SN - 1388-2481
SP - 67
TI - Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions.
T2 - Electrochemistry Communications
UR - http://dx.doi.org/10.1016/j.elecom.2017.09.004
UR - http://hdl.handle.net/10044/1/50616
VL - 83
ER -