Imperial College London
Portrait Picture

DrBrankoBijeljic

Faculty of Engineering, Department of Earth Science & Engineering

Principal Research Fellow
 
 
 
//

Contact

 

+44 (0)20 7594 6420b.bijeljic

 
 
//

Location

 

2.53Royal School of MinesSouth Kensington Campus

//

Summary

 

Publications

Citation

BibTex format

@article{Goodarzi:2024:10.1016/j.ijhydene.2023.12.029,
author = {Goodarzi, S and Zhang, Y and Foroughi, S and Bijeljic, B and Blunt, MJ},
doi = {10.1016/j.ijhydene.2023.12.029},
journal = {International Journal of Hydrogen Energy},
pages = {1139--1151},
title = {Trapping, hysteresis and Ostwald ripening in hydrogen storage: a pore-scale imaging study},
url = {http://dx.doi.org/10.1016/j.ijhydene.2023.12.029},
volume = {56},
year = {2024}
}
Download

RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Green hydrogen, produced from surplus electricity during peak production, can be injected into subsurface reservoirs and retrieved during high-demand periods. In this study, X-ray tomography was employed to examine hysteresis resulting from repeated hydrogen injection and withdrawal. An unsteady state experiment was performed to evaluate the distribution of hydrogen and brine after drainage and imbibition cycles: images of the pore-space configuration of fluids were taken immediately once injection had stopped and after waiting for a period of 16 h with no flow. A Bentheimer sandstone sample with a length of 60 mm and diameter of 12.8 mm was used, and hydrogen was injected at ambient temperature and a pore pressure of 1 MPa. The gas flow rate was decreased from 2 ml/min to 0.08 ml/min over three cycles of gas injection followed by water flooding, while the brine injection rate was kept constant. The results showed the presence of capillary pressure hysteresis and hydrogen migration through Ostwald ripening due to the diffusion of gas dissolved in the brine. These phenomena were characterized through analysis of interfacial curvature, area, connectivity and pore occupancy. The hydrogen tended to reside in the larger pore spaces, consistent with water-wet conditions. 16 h after flow had stopped, the hydrogen aggregated into larger ganglia with a single large connected ganglion dominating the volume. Moreover, the Euler characteristic decreased after 16 h, indicating an improvement in connectivity. The work implies that Ostwald ripening – mass transport of dissolved gas – leads to less hysteresis and better connectivity than would be assumed ignoring this effect, as done in assessments of hydrocarbon flow and trapping.
AU  - Goodarzi,S
AU  - Zhang,Y
AU  - Foroughi,S
AU  - Bijeljic,B
AU  - Blunt,MJ
DO  - 10.1016/j.ijhydene.2023.12.029
EP  - 1151
PY  - 2024///
SN  - 0360-3199
SP  - 1139
TI  - Trapping, hysteresis and Ostwald ripening in hydrogen storage: a pore-scale imaging study
T2  - International Journal of Hydrogen Energy
UR  - http://dx.doi.org/10.1016/j.ijhydene.2023.12.029
UR  - http://hdl.handle.net/10044/1/110406
VL  - 56
ER  -
Download