Imperial College London

Professor David W. McComb

Faculty of EngineeringDepartment of Materials

Adjunct Professor
 
 
 
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Contact

 

+44 (0)20 7594 6750d.mccomb Website

 
 
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Location

 

Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Weber:2019:10.1021/acs.nanolett.9b01287,
author = {Weber, D and Trout, AH and McComb, DW and Goldberger, JE},
doi = {10.1021/acs.nanolett.9b01287},
journal = {Nano Lett},
pages = {5031--5035},
title = {Decomposition-Induced Room-Temperature Magnetism of the Na-Intercalated Layered Ferromagnet Fe3-xGeTe2.},
url = {http://dx.doi.org/10.1021/acs.nanolett.9b01287},
volume = {19},
year = {2019}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - The creation of 2D van der Waals materials with ferromagnetism above room temperature is an essential goal toward their practical utilization in spin-based applications. Recent studies suggest that intercalating lithium in exfoliated flakes of the ferromagnet Fe3-xGeTe2 induces a nonzero magnetization at T ∼ 300 K. However, the nanoscale nature of such experiments precludes precise observations of structural and chemical changes upon intercalation. Here, we report the preparation of sodium-intercalated NaFe2.78GeTe2 as well as the investigation into its structure and magnetic properties. Sodium readily intercalates into the van der Waals gap, as revealed by synchrotron X-ray diffraction. Concurrently, the Fe2.78GeTe2 layer becomes heavily charge doped and strained via chemical pressure, yet retains its structure and ferromagnetic transition temperature of ∼140 K. However, we observe the presence of a ferromagnetic amorphous iron germanide impurity over a wide range of synthetic conditions, leading to room-temperature magnetization. This work highlights the importance of strain and electronic control for manipulating the Curie temperature in 2D ferromagnets, while emphasizing the need for careful chemical analysis when exploring phenomena in exfoliated layers.
AU - Weber,D
AU - Trout,AH
AU - McComb,DW
AU - Goldberger,JE
DO - 10.1021/acs.nanolett.9b01287
EP - 5035
PY - 2019///
SP - 5031
TI - Decomposition-Induced Room-Temperature Magnetism of the Na-Intercalated Layered Ferromagnet Fe3-xGeTe2.
T2 - Nano Lett
UR - http://dx.doi.org/10.1021/acs.nanolett.9b01287
UR - https://www.ncbi.nlm.nih.gov/pubmed/31251638
VL - 19
ER -