Imperial College London
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Dr James A Bull

Faculty of Natural Sciences, Department of Chemistry

Reader in Synthetic Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 5811j.bull Website

 
 
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Location

 

501bMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{St:2017:10.1039/C7SC01218G,
author = {St, John-Campbell S and White, AJP and Bull, JA},
doi = {10.1039/C7SC01218G},
journal = {Chemical Science},
pages = {4840--4840},
title = {Single operation palladium catalysed C(sp3)–H functionalisation of tertiary aldehydes: investigations into transient imine directing groups},
url = {http://dx.doi.org/10.1039/C7SC01218G},
volume = {8},
year = {2017}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Simple amine and diamine derivatives can promote the palladium catalysed direct -C–H arylation of aliphatic aldehydes via transient imine formation. Trifluoroacetate was shown to be crucial in promoting the reaction. Sub-stoichiometric quantities of simple N-tosylethylenediamine was shown to form a bidentate directing group with an imine linkage. Isolation of an unsymmetrical palladacyle has shown different potential binding modes of the secondary NTs coordinating group by single crystal X-ray diffraction analysis, suggestive of a hemilabile ligand.
AU  - St,John-Campbell S
AU  - White,AJP
AU  - Bull,JA
DO  - 10.1039/C7SC01218G
EP  - 4840
PY  - 2017///
SN  - 2041-6539
SP  - 4840
TI  - Single operation palladium catalysed C(sp3)–H functionalisation of tertiary aldehydes: investigations into transient imine directing groups
T2  - Chemical Science
UR  - http://dx.doi.org/10.1039/C7SC01218G
UR  - http://pubs.rsc.org/en/content/articlelanding/2017/sc/c7sc01218g
UR  - http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC01218G
UR  - http://hdl.handle.net/10044/1/48387
VL  - 8
ER  -
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