Imperial College London
Professor Michael Bearpark

ProfessorMichaelBearpark

Faculty of Natural Sciences, Department of Chemistry

Professor & Director of User Engagement
 
 
 
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Contact

 

+44 (0)20 7594 5727m.bearpark

 
 
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Location

 

110AMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Abdullahi:2016:10.1016/j.tet.2016.07.066,
author = {Abdullahi, MH and Thompson, LM and Bearpark, MJ and Vinader, V and Afarinkia, K},
doi = {10.1016/j.tet.2016.07.066},
journal = {Tetrahedron},
pages = {6021--6024},
title = {The role of substituents in retro Diels-Alder extrusion of CO2 from 2(H)-pyrone cycloadducts},
url = {http://dx.doi.org/10.1016/j.tet.2016.07.066},
volume = {72},
year = {2016}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - An experimental and computational investigation is conducted into the role of substituents in retro Diels–Alder extrusion of CO2 from 2-oxa-bicyclo[2.2.2]oct-5-en-3-ones. We provide the first experimental evidence that loss of CO2 from the cycloadducts significantly depends on the nature and position of the substituents. For example, we show that whilst 5-carboethoxy-2-pyrone undergoes a more facile cycloaddition that 3-carboethoxy-2-pyrone, the cycloadduct from the latter pyrone undergoes a more facile loss of CO2 than the cycloadduct from the former pyrone.
AU  - Abdullahi,MH
AU  - Thompson,LM
AU  - Bearpark,MJ
AU  - Vinader,V
AU  - Afarinkia,K
DO  - 10.1016/j.tet.2016.07.066
EP  - 6024
PY  - 2016///
SN  - 1464-5416
SP  - 6021
TI  - The role of substituents in retro Diels-Alder extrusion of CO2 from 2(H)-pyrone cycloadducts
T2  - Tetrahedron
UR  - http://dx.doi.org/10.1016/j.tet.2016.07.066
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000383940000010&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - http://hdl.handle.net/10044/1/42911
VL  - 72
ER  -
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