Imperial College London

Professor Matthew J. Fuchter

Faculty of Natural SciencesDepartment of Chemistry

Professor of Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 5815m.fuchter

 
 
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Location

 

401CMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Mercea:2019:10.1039/c9cc02900a,
author = {Mercea, DM and Howlett, MG and Piascik, AD and Scott, DJ and Steven, A and Ashley, AE and Fuchter, MJ},
doi = {10.1039/c9cc02900a},
journal = {Chemical Communications},
title = {Enantioselective reduction of N-alkyl ketimines with frustrated Lewis pair catalysis using chiral borenium ions},
url = {http://dx.doi.org/10.1039/c9cc02900a},
year = {2019}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Enantioselective reduction of ketimines was demonstrated using chiral N-heterocyclic carbene (NHC)-stabilised borenium ions in frustrated Lewis pair catalysis. High levels of enantioselectivity were achieved for substrates featuring secondary N-alkyl substituents. Comparative reactivity and mechanistic studies identify key determinants required to achieve useful enantioselectivity and represent a step forward in the further development of enantioselective FLP methodologies.
AU - Mercea,DM
AU - Howlett,MG
AU - Piascik,AD
AU - Scott,DJ
AU - Steven,A
AU - Ashley,AE
AU - Fuchter,MJ
DO - 10.1039/c9cc02900a
PY - 2019///
SN - 1359-7345
TI - Enantioselective reduction of N-alkyl ketimines with frustrated Lewis pair catalysis using chiral borenium ions
T2 - Chemical Communications
UR - http://dx.doi.org/10.1039/c9cc02900a
UR - https://www.ncbi.nlm.nih.gov/pubmed/31149679
UR - http://hdl.handle.net/10044/1/70396
ER -