Imperial College London

DrMatthewGenge

Faculty of EngineeringDepartment of Earth Science & Engineering

Senior Lecturer in Earth and Planetary Science
 
 
 
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Contact

 

+44 (0)20 7594 6499m.genge

 
 
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Location

 

1.45Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Publication Type
Year
to

125 results found

Suttle MD, Folco L, Genge MJ, Russell SS, Najorka J, van Ginneken Met al., 2019, Intense aqueous alteration on C-type asteroids: Perspectives from giant fine-grained micrometeorites, GEOCHIMICA ET COSMOCHIMICA ACTA, Vol: 245, Pages: 352-373, ISSN: 0016-7037

Journal article

Genge MJ, 2018, Electrostatic levitation of volcanic ash into the ionosphere and its abrupt effect on climate, Geology, Vol: 46, Pages: 835-838, ISSN: 0091-7613

Large volcanic eruptions cause short-term climate change owing to the convective rise of fine ash and aerosols into the stratosphere. Volcanic plumes are, however, also associated with large net electrical charges that can also influence the dynamics of their ash particles. Here I show that electrostatic levitation of ash from plumes with a net charge is capable of injecting volcanic particles <500 nm in diameter into the ionosphere in large eruptions lasting more than a few hours. Measured disturbances in the ionosphere during eruptions, and the first discovery of polar mesospheric clouds after the A.D. 1883 Krakatau (Indonesia) eruption, are both consistent with levitation of ash into the mesosphere. Supervolcano eruptions are likely to inject significant quantities of charged ash into the ionosphere, resulting in disturbance or collapse of the global electrical circuit on time scales of 102 s. Because atmospheric electrical potential moderates cloud formation, large eruptions may have abrupt effects on climate through radiative forcing. Average air temperature and precipitation records from the 1883 eruption of Krakatau are consistent with a sudden effect on climate.

Journal article

Genge MJ, Van Ginneken M, Suttle M, Harvey Ret al., 2018, Accumulation mechanisms of micrometeorites in an ancient supra-glacial moraine at Larkman Nunatak, Antarctica, Meteoritics and Planetary Science, Vol: 53, Pages: 2051-2066, ISSN: 1086-9379

We report the discovery of a large accumulation of micrometeorites in a supraglacial moraine at Larkman Nunatak in the Grosvenor Mountains of the Transantarctic Range in Antarctica. The micrometeorites are present in abundances of ~600 particles Kg-1 of moraine sediment and include a near complete collection of micrometeorite types similar to those observed in Antarctic blue ice and within bare-rock traps in the Antarctic. The size distribution of the observed particles is consistent with those collected from snow collections suggesting the moraine has captured a representative collection of cosmic spherules with significant loss of only the smallest particles (<100 m) by wind. The presence of microtektites with compositions similar to those of the Australasian strewn field suggests the moraine has been accumulating for 780 ka with dust-sized debris. On the basis of this age estimate it is suggested that accumulation occurs principally through ice sublimation. Direct in-fall of fines is suggested to be limited by snow layers that act as barriers to accumulation and can be removed by wind erosion. Micrometeorite accumulation in many areas in Antarctica, therefore, may not be continuous over long periods and can be subject to climatic controls. On the basis of the interpretation of microtektites as Australasian, Larkman Nunatak deposit is the oldest known supraglacial moraine and its survival through several glacial maxima and interglacial periods is surprising. We suggest that stationary ice produced by the specific ice flow conditions at Larkman Nunatak explains its longevity and provides a new type of record of the East Antarctic ice sheet.

Journal article

Shah J, Williams W, Almeida TP, Nagy L, Muxworthy AR, Kovacs A, Valdez-Grijalva MA, Fabian K, Russell SS, Genge M, Dunin-Borkowski REet al., 2018, The oldest magnetic record in our solar system identified using nanometric imaging and numerical modeling, Nature Communications, Vol: 9, ISSN: 2041-1723

Recordings of magnetic fields, thought to be crucial to our Solar System’s rapid accretion, are potentially retained in unaltered nanometric low-Ni kamacite (~metallic Fe) grains encased within dusty olivine crystals, found in the chondrules of unequilibrated chondrites. However, most of these kamacite grains are magnetically non-uniform, so their ability to retain four-billion-year-old magnetic recordings cannot be estimated by previous theories, which assume only uniform magnetization. Here, we demonstrate that non-uniformly magnetized nanometric kamacite grains are stable over Solar System timescales and likely the primary carrier of remanence in dusty olivine. By performing in-situ temperature-dependent nanometric magnetic measurements using off-axis electron holography, we demonstrate the thermal stability of multi-vortex kamacite grains from the chondritic Bishunpur meteorite. Combined with numerical micromagnetic modeling, we determine the stability of the magnetization of these grains. Our study shows that dusty olivine kamacite grains are capable of retaining magnetic recordings from the accreting Solar System.

Journal article

Van Ginneken M, Genge MJ, Harvey R, 2018, A new type of highly-vaporized microtektite from the Transantarctic Mountains, Geochimica et Cosmochimica Acta, Vol: 228, Pages: 81-94, ISSN: 0016-7037

We report on the discovery of microtektites (microscopic impact glass spherules) in a glacial moraine near Larkman Nunatak in the Transantarctic Mountains, Antarctica. The microtektites were identified based on their physical and chemical properties. Major and trace element compositions of the particles suggest that they may be related to the Australasian strewn field. This would further extend the current strewn field ~800 km southward. Depletion in volatiles and enrichment in refractory elements in Larkman Nunatak microtektites fit the volatilization trend defined by Australasian microtektites, suggesting that they may represent a new highly vapor fractionated member thereof. This observation is supported by their low vesicularity and absence of mineral inclusions. This discovery has strong implications for the formation of microtektites (i.e. their evolution with respect to the distance from the source crater). Finally, the discovery of potentially old (i.e. 0.8 Ma) microtektites in moraine has implications for the stability of the East Antarctic Ice Sheet in the Larkman Nunatak area over the last ~1 Ma and, as a consequence, the high efficiency of such moraines as traps for other extraterrestrial materials (e.g. micrometeorites and meteoritic ablation debris).

Journal article

Genge MJ, Van Ginneken M, 2017, Comment on “Unmelted Cosmic Metal Particles in the Indian Ocean” by Prasad et al., Meteoritics and Planetary Science, Vol: 53, Pages: 326-332, ISSN: 1086-9379

Journal article

Suttle M, Genge MJ, 2017, Diagenetically altered fossil micrometeorites suggest cosmic dust is common in the geological record, Earth and Planetary Science Letters, Vol: 476, Pages: 132-142, ISSN: 0012-821X

We report the discovery of fossil micrometeorites from Late Cretaceous chalk. Seventy-six cosmic spherules were recovered from Coniacian (87±1 Ma) sediments of the White Chalk Supergroup. Particles vary from pristine silicate and iron-type spherules to pseudomorphic spherules consisting of either single-phase recrystallized magnetite or Fe-silicide. Pristine spherules are readily identified as micrometeorites on the basis of their characteristic mineralogies, textures and compositions. Both magnetite and silicide spherules contain dendritic crystals and spherical morphologies, testifying to rapid crystallisation of high temperature iron-rich metallic and oxide liquids. These particles also contain spherical cavities, representing weathering and removal of metal beads and irregular cavities, representing vesicles formed by trapped gas during crystallization; both features commonly found among modern Antarctic Iron-type (I-type) cosmic spherules. On the basis of textural analysis, the magnetite and Fe-silicide spherules are shown to be I-type cosmic spherules that have experienced complete secondary replacement during diagenesis (fossilization). Our results demonstrate that micrometeorites, preserved in sedimentary rocks, are affected by a suite of complex diagenetic processes, which can result in disparate replacement minerals, even within the same sequence of sedimentary beds. As a result, the identification of fossil micrometeorites requires careful observation of particle textures and comparisons with modern Antarctic collections. Replaced micrometeorites imply that geochemical signatures the extraterrestrial dust are subject to diagenetic remobilisation that limits their stratigraphic resolution. However, this study demonstrates that fossil, pseudomorphic micrometeorites can be recognised and are likely common within the geological record.

Journal article

Genge MJ, Davies B, Suttle M, Van Ginneken M, Tomkins AGet al., 2017, The mineralogy and petrology of I-type cosmic spherules: Implications for their sources, origins and identification in sedimentary rocks, Geochimica et Cosmochimica Acta, Vol: 218, Pages: 167-200, ISSN: 0016-7037

I-type cosmic spherules are micrometeorites that formed by melting during atmospheric entry and consist mainly of iron oxides and FeNi metal. I-types are important because they can readily be recovered from sedimentary rocks allowing study of solar system events over geological time. We report the results of a study of the mineralogy and petrology of 88 I-type cosmic spherules recovered from Antarctica in order to evaluate how they formed and evolved during atmospheric entry, to constrain the nature of their precursors and to establish rigorous criteria by which they may be conclusively identified within sediments and sedimentary rocks. Two textural types of I-type cosmic spherule are recognised: (1) metal bead-bearing (MET) spherules dominated by Ni-poor (<1.5 w%) wüstite and FeNi metal (10-95 wt% Ni) with minor magnetite, and (2) metal bead-free (OX) spherules dominated by Ni-rich wüstite (0.5-22.5 wt%) and magnetite. Two varieties of OX spherule are distinguished, magnetite-poor dendritic spherules and magnetite-rich coarse spherules. Six OXMET particles having features of both MET and OX spherules were also observed. The wüstite to magnetite ratios and metal contents of the studied particles testify to their formation by melting of extraterrestrial FeNi grains during progressive oxidation in the atmosphere. Precursors are suggested to be mainly kamacite and rare taenite grains. Vesicle formation within metal beads and extrusion of metallic liquid into surrounding wüstite grain boundaries suggests an evaporated iron sulphide or carbide component within at least 23% of particles. The Ni/Co ratios of metal vary from 14 to >100 and suggest that metal from H-group ordinary, CM, CR and iron meteorites may form the majority of particles. Oxidation during entry heating increases in the series MET<magnetite-poor OX<magnetite-rich OX spherules owing to differences in particle size, entry angle and velocity. Magnetite-poor OX spherules are s

Journal article

Genge MJ, Russell SS, 2017, A MICROCHONDRULE-BEARING MICROMETEORITE., 80th Annual Meeting of the Meteoritical Society 2017

Introduction: The Earth receives a continuous flux of cosmic dust derived from young disrupted asteroids andsublimating short period comets [1,2]. Occasionally unique micrometeorites with distinct petrographies are reported[3]. These samples expand the inventory of asteroid parent bodies and provide further clues to the formation andevolution of the solar system. In this study we report the discovery of an unusual dehydroxylated fine-grained micrometeoritecontaining a devitrified microchondrule droplet. This spherule contains a volatile-rich composition indicatingformation in an energetic high density plume.Methods: A single micrometeorite, recovered from the Cap Prudhomme blue-ice micrometeorite collection [4]was analysed by SEM-EMPA, BSE, X-ray element mapping and mid-IR spectroscopy.Results: Particle CP94-050-182 (78x108μm) is a fine-grained micrometeorite, surrounded by a partial magnetiterim. A single spherical object (<10μm diameter) composed of devitrified glass is located near the micrometeorite’sperimeter and contains a non-chondritic volatile-rich composition. Relative to Ivuna, Na, K and Cl concentrations areelevated an order of magnitude above chondritic values at 7.8, 19.8 and 9.4 times, while refractory Al and Ca showapproximately chondritic abundances. The internal mineralogy is a heterogeneous mix of anhydrous silicates suspendedin a fine-grained, porous, nanocrystalline groundmass. Anhydrous silicates are present either as low-Fe(<3wt%), Ca-rich (12-15wt%) pyroxene or high-Fe (~18wt%), Ca-poor (<0.5wt%) olivine. Pyroxene grains containmoderate Mn (0.8-1.7wt%), Cr (~1.4wt%) and Al (~2.0wt%) concentrations, while olivines contain minimal traceelement contamination (Mn,Cr,Al<0.8wt%). Both anhydrous phases appear as anhedral clusters or isolated grains,intergrown with, or mantled by, a coarse non-stoichiometric Fe-rich phase. The surrounding groundmass containsrandomly orientated dehydration cracks and rounded submicron vesicles.

Conference paper

Shah J, Bates H, Muxworthy AR, Hezel DC, Russell SS, Genge MJet al., 2017, Long-lived magnetism in chondrite parent bodies, Earth and Planetary Science Letters, Vol: 475, Pages: 106-118, ISSN: 1385-013X

We present evidence for both early- and late-stage magnetic activity on the CV and L/LL parent bodies respectively from chondrules in Vigarano and Bjurböle. Using micro-CT scans to re-orientate chondrules to their in-situ positions, we present a new micron-scale protocol for the paleomagnetic conglomerate test. The paleomagnetic conglomerate test determines at 95% confidence, whether clasts within a conglomerate were magnetized before or after agglomeration, i.e., for a chondritic meteorite whether the chondrules carry a pre- or post-accretionary remanent magnetization. We found both meteorites passed the conglomerate test, i.e., the chondrules had randomly orientated magnetizations. Vigarano's heterogeneous magnetization is likely of shock origin, due to the 10 to 20 GPa impacts that brecciated its precursor material on the parent body and transported it to re-accrete as the Vigarano breccia. The magnetization was likely acquired during the break-up of the original body, indicating a CV parent body dynamo was active ∼9 Ma after Solar System formation. Bjurböle's magnetization is due to tetrataenite, which transformed from taenite as the parent body cooled to below 320 °C, when an ambient magnetic field imparted a remanence. We argue either the high intrinsic anisotropy of tetrataenite or brecciation on the parent body manifests as a randomly orientated distribution, and a L/LL parent body dynamo must have been active at least 80 to 140 Ma after peak metamorphism. Primitive chondrites did not originate from entirely primitive, never molten and/or differentiated parent bodies. Primitive chondrite parent bodies consisted of a differentiated interior sustaining a long-lived magnetic dynamo, encrusted by a layer of incrementally accreted primitive meteoritic material. The different ages of carbonaceous and ordinary chondrite parent bodies might indicate a general difference between carbonaceous and ordinary chondrite parent bodies, and/or format

Journal article

Genge MJ, Suttle M, Van Ginneken, 2017, Thermal shock fragmentation of Mg silicates within scoriaceous micrometeorites reveal hydrated asteroidal sources, Geology, Vol: 45, Pages: 891-894, ISSN: 1943-2682

Scoriaceous micrometeorites are highly vesicular extraterrestrial dust particles that have experienced partial melting during atmo-spheric entry. We report the occurrence of clusters of anhedral relict forsterite crystals within these particles that testify to in situ frag-mentation. The absence of similar clusters within unmelted micro-meteorites suggests that fragmentation occurs during atmospheric entry rather than by parent body shock reprocessing. Clusters of broken forsterite crystals are shown to form as a result of fracturing owing to thermal stress developed during entry heating and require thermal gradients of >200 K μm–1 in order for differential thermal expansion to exceed the critical shear strength of olivine. Thermal gradients of this magnitude significantly exceed those resulting from thermal conduction and require the endothermic decomposition of phyllosilicates. Fragmented relict forsterite within scoriaceous micro-meteorites, therefore, indicate that the precursor grains were similar to CI and CM2 chondrites and retained phyllosilicate prior to atmo-spheric entry and thus were not dehydrated on the parent asteroid by shock or thermal metamorphism. Explosive fragmentation of hydrous asteroids during collisions, therefore, does not significantly bias the interplanetary dust population.

Journal article

Suttle MD, Genge MJ, 2017, THE DIAGENESIS AND REPLACEMENT OF COSMIC DUST IN THE GEOLOGICAL RECORD., 80th Annual Meeting of the Meteoritical-Society, Publisher: WILEY, Pages: A338-A338, ISSN: 1086-9379

Conference paper

Suttle MD, Genge MJ, Russell SS, 2017, Shock fabrics in fine-grained micrometeorites, Meteoritics & Planetary Science, Vol: 52, Pages: 2258-2274, ISSN: 1086-9379

The orientations of dehydration cracks and fracture networks in fine-grained, unmelted micrometeorites were analyzed using rose diagrams and entropy calculations. As cracks exploit pre-existing anisotropies, analysis of their orientation provides a mechanism with which to study the subtle petrofabrics preserved within fine-grained and amorphous materials. Both uniaxial and biaxial fabrics are discovered, often with a relatively wide spread in orientations (40°–60°). Brittle deformation cataclasis and rotated olivine grains are reported from a single micrometeorite. This paper provides the first evidence for impact-induced shock deformation in fine-grained micrometeorites. The presence of pervasive, low-grade shock features in CM chondrites and CM-like dust, anomalously low-density measurements for C-type asteroids, and impact experiments which suggest CM chondrites are highly prone to disruption all imply that CM parent bodies are unlikely to have remained intact and instead exist as a collection of loosely aggregated rubble-pile asteroids, composed of primitive shocked clasts.

Journal article

van Ginneken M, Gattacceca J, Rochette P, Sonzogni C, Alexandre A, Vidal V, Genge MJet al., 2017, The parent body controls on cosmic spherule texture: Evidence from the oxygen isotopic compositions of large micrometeorites, Geochimica et Cosmochimica Acta, Vol: 212, Pages: 196-210, ISSN: 0016-7037

High-precision oxygen isotopic compositions of eighteen large cosmic spherules (>500 µm diameter) from the Atacama Desert, Chile, were determined using IR-laser fluorination – Isotope Ratio Mass spectrometry. The four discrete isotopic groups defined in a previous study on cosmic spherules from the Transantarctic Mountains (Suavet et al., 2010) were identified, confirming their global distribution. Approximately 50% of the studied cosmic spherules are related to carbonaceous chondrites, 38% to ordinary chondrites and 12% to unknown parent bodies. Approximately 90% of barred olivine (BO) cosmic spherules show oxygen isotopic compositions suggesting they are related to carbonaceous chondrites. Similarly, ∼90% porphyritic olivine (Po) cosmic spherules are related to ordinary chondrites and none can be unambiguously related to carbonaceous chondrites. Other textures are related to all potential parent bodies. The data suggests that the textures of cosmic spherules are mainly controlled by the nature of the precursor rather than by the atmospheric entry parameters. We propose that the Po texture may essentially be formed from a coarse-grained precursor having an ordinary chondritic mineralogy and chemistry. Coarse-grained precursors related to carbonaceous chondrites (i.e. chondrules) are likely to either survive atmospheric entry heating or form V-type cosmic spherules. Due to the limited number of submicron nucleation sites after total melting, ordinary chondrite-related coarse-grained precursors that suffer higher peak temperatures will preferentially form cryptocrystalline (Cc) textures instead of BO textures. Conversely, the BO textures would be mostly related to the fine-grained matrices of carbonaceous chondrites due to the wide range of melting temperatures of their constituent mineral phases, allowing the preservation of submicron nucleation sites. Independently of the nature of the precursors, increasing peak temperatures form glassy textures

Journal article

Genge MJ, 2017, The entry heating and abundances of basaltic micrometeorites, Meteoritics & Planetary Science, Vol: 52, Pages: 1000-1013, ISSN: 1086-9379

Basaltic micrometeorites (MMs) derived from HED-like parent bodies have been found amongst particles collected from the Antarctic and from Arctic glaciers and are to date the only achondritic particles reported amongst cosmic dust. The majority of Antarctic basaltic particles are completely melted cosmic spherules with only one unmelted particle recognised from the region. This paper investigates the entry heating of basaltic MMs in order to predict the relative abundances of unmelted to melted basaltic particles and to evaluate how mineralogical differences in precursor materials influence the final products of atmospheric entry collected on the Earth's surface. Thermodynamic modelling is used to simulate the melting behaviour of particles with compositions corresponding to eucrites, diogenites and ordinary chondrites in order to evaluate degree of partial melting and to make a comparison between the behaviour of chondritic particles that dominate the terrestrial dust flux and basaltic micrometeroids. The results of 120,000 simulations were compiled to predict relative abundances and indicate that the phase relations of precursor materials are crucial in determining the relative abundances of particle types. Diogenite and ordinary chondrite materials exhibit similar behaviour, although diogenite precursors are more likely to form cosmic spherules under similar entry parameters. Eucrite particles, however, are much more likely to melt due to their lower liquidus temperatures and small temperature interval of partial melting. Eucrite MMs, therefore, usually form completely molten cosmic spherules except at particle diameters <100 m. The low abundance of unmelted basaltic MMs compared with spherules, if statistically valid, is also shown to be inconsistent with a low velocity population (12 km s-1) and is more compatible with higher velocities which may suggest a Near Earth Asteroid sources dominates the current dust production of basaltic MMs.

Journal article

Suttle MD, Genge MJ, Folco L, Russell SSet al., 2017, The thermal decomposition of fine-grained micrometeorites, observations from mid-IR spectroscopy, Geochimica et Cosmochimica Acta, Vol: 206, Pages: 112-136, ISSN: 1872-9533

We analysed 44 fine-grained and scoriaceous micrometeorites. A bulk mid-IR spectrum (8–13 μm) for each grain was collected and the entire micrometeorite population classified into 5 spectral groups, based on the positions of their absorption bands. Corresponding carbonaceous Raman spectra, textural observations from SEM-BSE and bulk geochemical data via EMPA were collected to aid in the interpretation of mid-IR spectra. The 5 spectral groups identified correspond to progressive thermal decomposition. Unheated hydrated chondritic matrix, composed predominantly of phyllosilicates, exhibit smooth, asymmetric spectra with a peak at ∼10 μm. Thermal decomposition of sheet silicates evolves through dehydration, dehydroxylation, annealing and finally by the onset of partial melting. Both CI-like and CM-like micrometeorites are shown to pass through the same decomposition stages and produce similar mid-IR spectra. Using known temperature thresholds for each decomposition stage it is possible to assign a peak temperature range to a given micrometeorite. Since the temperature thresholds for decomposition reactions are defined by the phyllosilicate species and the cation composition and that these variables are markedly different between CM and CI classes, atmospheric entry should bias the dust flux to favour the survival of CI-like grains, whilst preferentially melting most CM-like dust. However, this hypothesis is inconsistent with empirical observations and instead requires that the source ratio of CI:CM dust is heavily skewed in favour of CM material. In addition, a small population of anomalous grains are identified whose carbonaceous and petrographic characteristics suggest in-space heating and dehydroxylation have occurred. These grains may therefore represent regolith micrometeorites derived from the surface of C-type asteroids. Since the spectroscopic signatures of dehydroxylates are distinctive, i.e. characterised by a reflectance peak at 9.0–9.5

Journal article

Genge MJ, 2017, Vesicular parachutes increase the abundance of micrometeorites from water-rich asteroids on Earth, Geophysical Research Letters, Vol: 44, ISSN: 1944-8007

Micrometeorites (MMs) are extraterrestrial dust particles that survive atmospheric entry and can be recovered from sedimentary rocks. Fossil MMs allow events beyond the Earth, such as the collisional breakup of asteroids, to be identified. Here the effects of vesicle formation during melting of dust are investigated through numerical modeling and observations of Antarctic MMs. Vesicle formation is shown to cause a parachute effect that causes rapid deceleration, decreasing peak temperature. Vesicular parachuting enhances the abundance of melted MMs formed from phyllosilicate-bearing C-type asteroid dust on the Earth surface by a factor of 2. Micrometeorites recovered from the geological record, therefore, are biased toward breakup events involving hydrated C-type asteroids, whilst those involving phyllosilicate-poor particles are diluted by the enhanced background flux of hydrous dust. The parachute effect is also likely to increase the delivery of 3He to ocean sediments by C-type asteroid dust.

Journal article

Genge MJ, Larsen J, Van Ginneken M, Suttle Met al., 2017, An urban collection of modern-day large micrometeorites: evidence for variations in the extraterrestrial dust flux through the Quaternary, Geology, Vol: 45, Pages: 119-122, ISSN: 1943-2682

We report the discovery of significant numbers (500) of large micrometeorites (>100 μm) from rooftops in urban areas. The identification of particles as micrometeorites is achieved on the basis of their compositions, mineralogies, and textures. All particles are silicate-dominated (S type) cosmic spherules with subspherical shapes that form by melting during atmospheric entry and consist of quench crystals of magnesian olivine, relict crystals of forsterite, and iron-bearing olivine within glass. Four particles also contain Ni-rich metal-sulfide beads. Bulk compositions are chondritic apart from depletions in the volatile, moderately volatile, and siderophile elements, as observed in micrometeorites from other sources. The reported particles are likely to have fallen on Earth in the past 6 yr and thus represent the youngest large micrometeorites collected to date. The relative abundance ratio of barred olivine to cryptocrystalline spherule types in the urban particles of 1.45 is shown to be higher than a Quaternary average of ∼0.9, suggesting variations in the extraterrestrial dust flux over the past 800 k.y. Changes in the entry velocities of dust caused by quasi-periodic gravitational perturbation during transport to Earth are suggested to be responsible. Variations in cosmic spherule abundance within the geologic column are thus unavoidable and can be a consequence of dust transport as well as major dust production events.

Journal article

Shah J, Muxworthy AR, Almeida TP, Kovacs A, Russell SS, Genge M, Dunin-Borkowski Ret al., 2017, Dusty olivine: our oldest record of rock magnetism? (invited), Magnetic Interactions, Edinburgh

Conference paper

Genge MJ, 2016, Vesicle dynamics during the atmospheric entry heating of cosmic spherules, Meteoritics & Planetary Science, Vol: 52, Pages: 443-457, ISSN: 1086-9379

Cosmic spherules are unique igneous objects that form by melting due to gas drag heating during atmospheric entry heating. Vesicles are an important component of many cosmic spherules since they suggest their precursors had finite volatile contents. Vesicle abundances in spherules decrease through the series porphyritic, glassy, barred, to cryptocrystalline spherules. Anomalous hollow spherules, with large off-centre vesicles occur in both porphyritic and glassy spheres. Numerical simulation of the dynamic behaviour of vesicles during atmospheric flight is presented that indicates vesicles rapidly migrate due to deceleration and separate from non-porphyritic particles. Modest rotation rates of tens of radians s-1 are, however, sufficient to impede loss of vesicles and may explain the presence of small solitary vesicles in barred, cryptocrystalline and glassy spherules. Rapid rotation at spin rates of several thousand radians s-1 are required to concentrate vesicles at the rotational axis and leads to rapid growth by coalescence and either separation or retention depending on the orientation of the rotational axis. Complex rapid rotations that concentrate vesicles in the core of particles are proposed as a mechanism for the formation of hollow spherules. High vesicle contents in porphyritic spherules suggest volatile-rich precursors, however, calculation of volatile retention indicates these have lost >99.9% of volatiles to degassing prior to melting. The formation of hollow spherules, by rapid spin, necessarily implies pre-atmospheric rotations of several thousand radians s-1. These particles are suggested to represent immature dust, recently released from parent bodies, in which rotations have not been slowed by magnetic damping.

Journal article

Genge MJ, Suttle M, Van Ginneken M, 2016, Olivine settling in cosmic spherules during atmospheric deceleration: An indicator of the orbital eccentricity of interplanetary dust, Geophysical Research Letters, Vol: 43, Pages: 10646-10653, ISSN: 1944-8007

A new type of cosmic spherule is reported with textures suggesting settling of olivine during atmospheric deceleration. Numerical simulations of entry heating reveal that relict forsterite, which survives melting, can settle over the 1-2s of flight at high entry angles and entry velocities up to 16 km s-1. Enhanced crystallisation of phenocrysts by heterogeneous nucleation on accumulated relict forsterites is the most likely origin of the observed cumulate textures in cosmic spherules. Such textures in cosmic spherules reveal interplanetary dust with higher encounter velocity with the Earth that correspond to orbital eccentricities >0.3. The relative abundance of cumulate spherules suggests 14% of ordinary chondrite-related, S(IV)-type asteroid dust over the last 800 kyr had relatively high orbital eccentricity owing to secular and planetary perturbations. The textures of cosmic spherules collected from sediments can therefore be used to trace dust orbital variations with time which may influence terrestrial climate.

Journal article

Shah J, Bates H, Muxworthy AR, Russell SS, Genge MJet al., 2016, A micro-CT conglomerate test (poster), 15th Castle Meeting

Conference paper

Shah J, Muxworthy AR, Almeida TP, Kovacs A, Russell SS, Genge M, Williams W, Dunin-Borkowski REet al., 2016, Determining the magnetic recording fidelity of chondrule dusty olivine, 15th Castle Meeting

Conference paper

Genge MJ, Davies B, Suttle MD, Van Ginneken M, Tomkins Aet al., 2016, VOLATILE-BEARING PHASES IN THE PRECURSORS OF IRON-TYPE COSMIC SPHERULES, 79th Annual Meeting of the Meteoritical-Society, Publisher: WILEY-BLACKWELL, Pages: A282-A282, ISSN: 1086-9379

Conference paper

Suttle MD, Genge MJ, Russell S, 2016, SHOCK FABRICS IN FINE-GRAINED MICROMETEORITES., 79th Annual Meeting of the Meteoritical-Society, Publisher: WILEY-BLACKWELL, Pages: A607-A607, ISSN: 1086-9379

Conference paper

Larsen J, Genge MJ, 2016, THE COLLECTION OF URBAN MMS - NOT AN URBAN MYTH, 79th Annual Meeting of the Meteoritical-Society, Publisher: WILEY-BLACKWELL, Pages: A401-A401, ISSN: 1086-9379

Conference paper

Suttle MD, Genge MJ, Russell S, 2016, THE THERMAL DECOMPOSITION OF MICROMETEORITES FROM MID-INFRARED SPECTROSCOPY AND COMPARISON WITH T-TAURI STAR SYSTEMS., 79th Annual Meeting of the Meteoritical-Society, Publisher: WILEY, Pages: A608-A608, ISSN: 1086-9379

Conference paper

Genge MJ, Tomkins AG, Bowlt L, Wilson S, Brand HEA, Wykes JLet al., 2016, Ancient micrometeorites suggestive of an oxygen-rich Archaean upper atmosphere, Nature, Vol: 533, Pages: 235-238, ISSN: 0028-0836

It is widely accepted that Earth’s early atmosphere contained less than 0.001 per cent of the present-day atmospheric oxygen (O2) level, until the Great Oxidation Event resulted in a major rise in O2 concentration about 2.4 billion years ago1. There are multiple lines of evidence for low O2 concentrations on early Earth, but all previous observations relate to the composition of the lower atmosphere2 in the Archaean era; to date no method has been developed to sample the Archaean upper atmosphere. We have extracted fossil micrometeorites from limestone sedimentary rock that had accumulated slowly 2.7 billion years ago before being preserved in Australia’s Pilbara region. We propose that these micrometeorites formed when sand-sized particles entered Earth’s atmosphere and melted at altitudes of about 75 to 90 kilometres (given an atmospheric density similar to that of today3). Here we show that the FeNi metal in the resulting cosmic spherules was oxidized while molten, and quench-crystallized to form spheres of interlocking dendritic crystals primarily of magnetite (Fe3O4), with wüstite (FeO)+metal preserved in a few particles. Our model of atmospheric micrometeorite oxidation suggests that Archaean upper-atmosphere oxygen concentrations may have been close to those of the present-day Earth, and that the ratio of oxygen to carbon monoxide was sufficiently high to prevent noticeable inhibition of oxidation by carbon monoxide. The anomalous sulfur isotope (Δ33S) signature of pyrite (FeS2) in seafloor sediments from this period, which requires an anoxic surface environment4, implies that there may have been minimal mixing between the upper and lower atmosphere during the Archaean.

Journal article

Genge MJ, 2016, The Origins of I-type Spherules and the Atmospheric Entry of Iron Micrometeoroids., Meteoritics and Planetary Science, Vol: 51, Pages: 1063-1081, ISSN: 1086-9379

The Earth's extraterrestrial dust flux includes a wide variety of dust particles that include FeNi metallicgrains. During their atmospheric entry iron micrometeoroids melt and oxidize to form cosmicspherules termed I-type spherules. These particles are chemically resistant and readily collected bymagnetic separation and are thus the most likely micrometeorites to be recovered from modern andancient sediments. Understanding their behavior during atmospheric entry is crucial in constrainingtheir abundance relative to other particle types and the nature of the zodiacal dust population at 1AU. This paper presents numerical simulations of the atmospheric entry heating of iron meteoroids inorder to investigate the abundance and nature of these materials. The results indicate that ironmicrometeoroids experience peak temperatures 300-800K higher than silicate particles explaining therarity of unmelted iron particles which can only be present at sizes of <50 m. The lower evaporationrates of liquid iron oxide leads to greater survival of iron particles compared with silicates, whichenhances their abundance amongst micrometeorites by a factor of 2. The abundance of I-types isshown to be broadly consistent with the abundance and size of metal in ordinary chondrites and thecurrent day flux of ordinary chondrite-derived MMs arriving at Earth. Furthermore, carbonaceousasteroids and cometary dust are suggested to make negligible contributions to the I-type spheruleflux. Events involving such objects, therefore, cannot be recognized from I-type spherule abundancesin the geological record.

Journal article

van Ginneken M, Genge MJ, Folco L, Harvey RPet al., 2016, The weathering of micrometeorites from the Transantarctic Mountains, Geochimica et Cosmochimica Acta, Vol: 179, Pages: 1-31, ISSN: 1872-9533

Micrometeorites are cosmic dust particles recovered from the Earth’s surface that dominate the influx of extraterrestrial material accreting to our planet. This paper provides the first in-depth study of the weathering of micrometeorites within the Antarctic environment that will allow primary and secondary features to be distinguished. It is based on the analysis of 366 particles from Larkman Nunatak and 25 from the Transantarctic Mountain collection. Several important morphological categories of weathering effects were identified: (1) irregular and faceted cavities, (2) surface etch pits, (3) infilled cavities, (4) replaced silicate phases, and (5) hydrated and replaced metal. These features indicate that congruent dissolution of silicate phases, in particular olivine, is important in generating new pore space within particles. Comparison of the preservation of glass and olivine also indicates preferential dissolution of olivine by acidic solutions during low temperature aqueous alteration. Precipitation of new hydrous phases within cavities, in particular ferrihydrite and jarosite, results in pseudomorph textures within heavily altered particles. Glass, in contrast, is altered to palagonite gels and shows a sequential replacement indicative of varying water to rock ratios. Metal is variably replaced by Fe-oxyhydroxides and results in decreases in Ni/Fe ratio. In contrast, sulphides within metal are largely preserved. Magnetite, an essential component of micrometeorites formed during atmospheric entry, is least altered by interaction with the terrestrial environment. The extent of weathering in the studied micrometeorites is sensitive to differences in their primary mineralogy and varies significantly with particle type. Despite these differences, we propose a weathering scale for micrometeorites based on both their degree of terrestrial alteration and the level of encrustation by secondary phases. The compositions and textures of weathering products, howeve

Journal article

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