Imperial College London

ProfessorMartinHeeney

Faculty of Natural SciencesDepartment of Chemistry

Professor of Organic Materials
 
 
 
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Contact

 

+44 (0)20 7594 1248m.heeney Website

 
 
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Location

 

401GMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Meindl:2020:10.1021/acs.joc.0c00826,
author = {Meindl, B and Pfennigbauer, K and Stöger, B and Heeney, M and Glöcklhofer, F},
doi = {10.1021/acs.joc.0c00826},
journal = {Journal of Organic Chemistry},
pages = {8240--8244},
title = {Double ring-closing approach for the synthesis of 2,3,6,7-substituted anthracene derivatives.},
url = {http://dx.doi.org/10.1021/acs.joc.0c00826},
volume = {85},
year = {2020}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - A method for the synthesis of 2,3,6,7-substituted anthracene derivatives, one of the most challenging anthracene substitution patterns to obtain, is presented. The method is exemplified by the preparation of 2,3,6,7-anthracenetetracarbonitrile and employs a newly developed, stable, protected 1,2,4,5-benzenetetracarbaldehyde as the precursor. The precursor can be obtained in two scalable synthetic steps from 2,5-dibromoterephthalaldehyde and is converted into the anthracene derivative by a double intermolecular Wittig reaction under very mild conditions, followed by a deprotection and intramolecular double ring-closing condensation reaction.
AU - Meindl,B
AU - Pfennigbauer,K
AU - Stöger,B
AU - Heeney,M
AU - Glöcklhofer,F
DO - 10.1021/acs.joc.0c00826
EP - 8244
PY - 2020///
SN - 0022-3263
SP - 8240
TI - Double ring-closing approach for the synthesis of 2,3,6,7-substituted anthracene derivatives.
T2 - Journal of Organic Chemistry
UR - http://dx.doi.org/10.1021/acs.joc.0c00826
UR - https://www.ncbi.nlm.nih.gov/pubmed/32447951
UR - https://pubs.acs.org/doi/10.1021/acs.joc.0c00826
UR - http://hdl.handle.net/10044/1/79962
VL - 85
ER -