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@article{Green:2016:10.1002/anie.201602491,
author = {Green, J and Han, Y and Kilmurray, R and McLachlan, M and Anthopoulos, T and Heeney, MJ},
doi = {10.1002/anie.201602491},
journal = {Angewandte Chemie - International Edition},
pages = {7148--7151},
title = {An Air-Stable Semiconducting Polymer Containing Dithieno[3,2-b:2′,3′-d]arsole},
url = {http://dx.doi.org/10.1002/anie.201602491},
volume = {55},
year = {2016}
}

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TY  - JOUR
AB  - Arsole-containing conjugated polymers are a practically unexplored class of materials despite the high interest in their phosphole analogues. Herein we report the synthesis of the first dithieno[3,2-b;2′,3′-d]arsole derivative, and demonstrate that it is stable to ambient oxidation in its +3 oxidation state. A soluble copolymer is obtained by a palladium-catalyzed Stille polymerization and demonstrated to be a p-type semiconductor with promising hole mobility, which was evaluated by field-effect transistor measurements.
AU  - Green,J
AU  - Han,Y
AU  - Kilmurray,R
AU  - McLachlan,M
AU  - Anthopoulos,T
AU  - Heeney,MJ
DO  - 10.1002/anie.201602491
EP  - 7151
PY  - 2016///
SN  - 1433-7851
SP  - 7148
TI  - An Air-Stable Semiconducting Polymer Containing Dithieno[3,2-b:2′,3′-d]arsole
T2  - Angewandte Chemie - International Edition
UR  - http://dx.doi.org/10.1002/anie.201602491
UR  - http://hdl.handle.net/10044/1/30881
VL  - 55
ER  -

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