412 results found
Jais AA, Ali SAM, Anwar M, et al., 2017, Enhanced ionic conductivity of scandia-ceria-stabilized-zirconia (10Sc1CeSZ) electrolyte synthesized by the microwave-assisted glycine nitrate process, Ceramics International, Vol: 43, Pages: 8119-8125, ISSN: 0272-8842
Scandia-stabilized-zirconia is a potential zirconia-based electrolyte for intermediate temperature solid oxide fuel cells (IT-SOFCs). In this study, the properties of zirconia co-doped with 10 mol% Sc and 1 mol% Ce (scandia-ceria-stabilized-zirconia, 10Sc1CeSZ) electrolyte synthesized by the microwave-assisted glycine nitrate process (MW-GNP) were determined. The effects of microwave heating on the sintering temperature, microstructure, densification and ionic conductivity of the 10Sc1CeSZ electrolyte were evaluated. The phase identification, microstructure and specific surface area of the prepared powder were investigated using X-ray diffraction, transmission electron microscopy and the Brunauer-Emmett-Teller technique, respectively. Using microwave heating, a single cubic-phase powder was produced with nanosized crystallites (19.2 nm) and a high specific surface area (16 m2/g). It was found that the relative density, porosity and total ionic conductivity of the 10Sc1CeSZ electrolyte are remarkably influenced by the powder processing method and the sintering temperature. The pellet sintered at 1400 °C exhibited a maximum ionic conductivity of 0.184 S/cm at 800 °C. This is the highest conductivity value of a scandia-stabilized-zirconia based electrolyte reported in the literature for this electrolyte type. The corresponding value of the activation energy of electrical conductivity was found to be 0.94 eV in the temperature range of 500–800 °C. Overall, the use of microwave heating has successfully improved the properties of the 10Sc1CeSZ electrolyte for application in an IT-SOFC.
Somalu MR, Muchtar A, Brandon NP, 2017, Properties of screen-printed nickel/scandia-stabilized-zirconia anodes fabricated using rheologically optimized inks during redox cycles, JOURNAL OF MATERIALS SCIENCE, Vol: 52, Pages: 7175-7185, ISSN: 0022-2461
Jamil Z, Ruiz-Trejo E, Brandon NP, 2017, Nickel Electrodeposition on Silver for the Development of Solid Oxide Fuel Cell Anodes and Catalytic Membranes, Journal of The Electrochemical Society, Vol: 164, Pages: D210-D217, ISSN: 1945-7111
Nickel was electrodeposited on porous Ag/GDC (silver/Ce0.9Gd0.1O2-x) scaffolds and dense Ag/GDC composites for the fabricationof SOFC electrodes and catalytic membranes respectively. To control the distribution and amount of nickel deposition on the Ag/GDCsurfaces; first, a systematic cyclic voltammetry study of nickel electrodeposition from a Watts bath on silver foils was carried outto understand the influence of operating conditions on the electrodeposition process. From the cyclic voltammetry study, it can beconcluded that suitable operating conditions for nickel electrodeposition into porous Ag/GDC scaffolds and catalytic membranesare: 1.1 M Ni2+ concentration in Watts bath; deposition potential between −0.65 to −1.0 V vs. Ag/AgCl; a temperature at 55◦C;sodium dodecyl sulfate (SDS) as the surfactant; pH 4.0 ± 0.2 and an agitation rate of 500 rpm. It was observed that the nickel surfacemicrostructure changed with the deposition current densities due to the co-evolution of H2. Pulse and continuous electrodepositionmodes allow nickel to be deposited throughout porous Ag/GDC scaffolds and onto catalytic membranes. The pulse electrodepositionmode is favored as this is shown to result in an even Ni distribution within the porous scaffolds at minimum H2 pitting.
Chen Z, Atkinson A, Brandon N, 2017, Characterization of deformation and damage in porous sofc components via spherical indentation and simulation, 40th International Conference on Advanced Ceramics and Composites, Pages: 143-157
© 2018 by World Scientific Publishing Europe Ltd. The aim of this work is to present the methodology to characterize deformation and contact damage initiation and evolution in porous bulk and film components used in solid oxide fuel cells, based on indentation and simulation. Spherical indentation tests at a broad range of loads (50-10000 mN) were carried out on porous bulk and film electrodes with different levels of porosity, and on bilayer system. An axisymmetric model based on the Gurson model used for porous materials was developed to simulate the indentation processes. Elasticity and hardness of each component were reliably determined via both experiments and modelling. Inverse analysis via comparison of experimental indentation response curves and simulation-generated curves shows a very different relation between hardness and yield stress, compared with dense materials. Cracking behaviour was examined and appropriately explained by FEM results. Further insight of the deformation and damage behaviour was also obtained based on microstructural study using FIB-SEM. Overall, the study shows that the model developed in this work is highly applicable for the description the deformation and damage characteristics in porous bulk and film ceramics.
Cooper SJ, Brandon NP, 2017, An Introduction to Solid Oxide Fuel Cell Materials, Technology and Applications, ISBN: 9780081011027
© 2017 Elsevier Ltd. All rights reserved. This chapter begins with a brief history of fuel cell development and introduces solid oxide fuel cells (SOFCs) as high efficiency energy conversion devices. Following this the fundamentals of SOFC performance and cell design are explored, with special focus given to the significance of operating temperature and microstructure. Next the current commercial status of SOFCs is outlined in brief. Finally, SOFC degradation, the major theme of this book, is introduced; the various mechanisms are split into the two broad categories of physical and chemical degradation.
Tariq F, Ruiz-Trejo E, Bertei A, et al., 2017, Microstructural Degradation: Mechanisms, Quantification, Modeling and Design Strategies to Enhance the Durability of Solid Oxide Fuel Cell Electrodes, Solid Oxide Fuel Cell Lifetime and Reliability: Critical Challenges in Fuel Cells, Pages: 79-99, ISBN: 9780081011027
© 2017 Elsevier Ltd. All rights reserved. Electrode microstructure is one of the main factors determining the performance and durability of solid oxide fuel cells (SOFCs). The degradation is intimately linked to the microstructure, which in turn depends upon manufacturing and operation conditions. In this chapter we discuss the main causes for degradation of electrodes, concentrating mainly on the anode and present the techniques-both typical and state-of-the-art to follow these changes. We emphasize the need to quantitatively link the microstructural properties (e.g., triple-phase boundaries, porosity, and tortuosity) with the electrochemical responses measured and, most importantly, to link the change in microstructure to the performance degradation via suitable models. The knowledge gained must then be used to design new electrodes that can extend the lifetime of SOFCs once the critical parameters have been identified.
Brandon NP, Ruiz-Trejo E, Boldrin P, 2017, Solid Oxide Fuel Cell Lifetime and Reliability: Critical Challenges in Fuel Cells, ISBN: 9780081011027
© 2017 Elsevier Ltd. All rights reserved. Solid Oxide Fuel Cell Lifetime and Reliability: Critical Challenges in Fuel Cells presents in one volume the most recent research that aims at solving key issues for the deployment of SOFC at a commercial scale and for a wider range of applications. To achieve that, authors from different regions and backgrounds address topics such as electrolytes, contaminants, redox cycling, gas-tight seals, and electrode microstructure. Lifetime issues for particular elements of the fuel cells, like cathodes, interconnects, and fuel processors, are covered as well as new materials. They also examine the balance of SOFC plants, correlations between structure and electrochemical performance, methods for analysis of performance and degradation assessment, and computational and statistical approaches to quantify degradation. For its holistic approach, this book can be used both as an introduction to these issues and a reference resource for all involved in research and application of solid oxide fuel cells, especially those developing understanding in industrial applications of the lifetime issues. This includes researchers in academia and industrial R&D, graduate students and professionals in energy engineering, electrochemistry, and materials sciences for energy applications. It might also be of particular interest to analysts who are looking into integrating SOFCs into energy systems. Brings together in a single volume leading research and expert thinking around the broad topic of SOFC lifetime and durability. Explores issues that affect solid oxide fuel cells elements, materials, and systems with a holistic approach. Provides a practical reference for overcoming some of the common failure mechanisms of SOFCs. Features coverage of integrating SOFCs into energy systems.
Chen J, Ruiz-Trejo E, Atkinson A, et al., 2017, Microstructural and Electrochemical Characterisation of Degradation in Nickel Impregnated Scandia-stabilised Zirconia Electrode during Isothermal Annealing, 15th International Symposium on Solid Oxide Fuel Cells (SOFC), Publisher: ELECTROCHEMICAL SOC INC, Pages: 1125-1137, ISSN: 1938-5862
Mukerjee S, Leah R, Selby M, et al., 2017, Life and Reliability of Solid Oxide Fuel Cell-Based Products: A Review, Solid Oxide Fuel Cell Lifetime and Reliability: Critical Challenges in Fuel Cells, Pages: 173-191, ISBN: 9780081011027
© 2017 Elsevier Ltd. All rights reserved. Solid oxide fuel cells (SOFCs) are a technology rapidly developing toward widespread commercialization, with hundreds of megawatts of generation capacity installed in the field for large-scale power generation (100. kW-1. MW), and small-scale distributed power generation (<5. kW scale) undergoing large precommercial field trials in Europe and Japan. Although rapidly improving, challenges still remain in achieving SOFC stack operating lives of up to 90,000. h at a cost competitive with more established power generation technology. This chapter provides a review of the current development status of the main SOFC developers and technology variants based on publicly available literature. The techniques being developed to accelerate technology development cycles by enabling lifetime prediction from relatively short-duration tests are also discussed.
Bertei A, Tariq F, Yufit V, et al., 2016, Guidelines for the rational design and engineering of 3D manufactured solid oxide fuel cell composite electrodes, Journal of the Electrochemical Society, Vol: 164, Pages: F89-F98, ISSN: 0013-4651
The growth of 3D printing has opened the scope for designing microstructures for solid oxide fuel cells(SOFCs) with improved power density and lifetime. This technique can introduce structural modifications at a scale larger than particle size but smaller than cell size, such as by insertingelectrolyte pillars of ~5-100 µm. This study sets the minimum requirements for the rational design of 3D printedelectrodes based on an electrochemical model and analytical solutions for functional layers with negligible electronic resistanceand no mixed conduction. Results show that this structural modification enhances the power density when the ratio keffbetween effective conductivity and bulk conductivity of the ionic phase is smaller than 0.5. The maximum performance improvement is predicted as a function of keff. A design study on a wide range of pillar shapes indicates that improvements are achieved by any structural modification which provides ionic conduction up to a characteristic thickness ~10-40 µm without removing active volume at the electrolyte interface. The best performance is reached for thin (< ~2 µm) and long (> ~80 µm) pillars when the compositeelectrode is optimised for maximum three-phase boundarydensity, pointing towards the design of scaffolds with well-defined geometry and fractal structures.
Parkes MA, Tompsett DA, d'Avezac M, et al., 2016, The atomistic structure of yttria stabilised zirconia at 6.7 mol%: an ab initio study., Physical Chemistry Chemical Physics, Vol: 18, Pages: 31277-31285, ISSN: 1463-9084
Yttria stabilized zirconia (YSZ) is an important oxide ion conductor used in solid oxide fuel cells, oxygen sensing devices, and for oxygen separation. Doping pure zirconia (ZrO2) with yttria (Y2O3) stabilizes the cubic structure against phonon induced distortions and this facilitates high oxide ion conductivity. The local atomic structure of the dopant is, however, not fully understood. X-ray and neutron diffraction experiments have established that, for dopant concentrations below 40 mol% Y2O3, no long range order is established. A variety of local structures have been suggested on the basis of theoretical and computational models of dopant energetics. These studies have been restricted by the difficulty of establishing force field models with predictive accuracy or exploring the large space of dopant configurations with first principles theory. In the current study a comprehensive search for all symmetry independent configurations (2857 candidates) is performed for 6.7 mol% YSZ modelled in a 2 × 2 × 2 periodic supercell using gradient corrected density functional theory. The lowest energy dopant structures are found to have oxygen vacancy pairs preferentially aligned along the 〈210〉 crystallographic direction in contrast to previous results which have suggested that orientation along the 〈111〉 orientation is favourable. Analysis of the defect structures suggests that the Y(3+)-Ovac interatomic separation is an important parameter for determining the relative configurational energies. Current force field models are found to be poor predictors of the lowest energy structures. It is suggested that the energies from a simple point charge model evaluated at unrelaxed geometries is actually a better descriptor of the energy ordering of dopant structures. Using these observations a pragmatic procedure for identifying low energy structures in more complicated material models is suggested. Calculation of the oxygen vacancy migration activat
Boldrin P, Ruiz Trejo E, Mermelstein J, et al., Strategies for carbon and sulfur tolerant solid oxide fuel cell materials, incorporating lessons from heterogeneous catalysis, Chemical Reviews, Vol: 116, Pages: 13633-13684, ISSN: 1520-6890
Solid oxide fuel cells (SOFCs) are a rapidly emerging energy technology for a low carbon world, providing high efficiency, potential to use carbonaceous fuels and compatibility with carbon capture and storage. However, current state-of-the-art materials have low tolerance to sulfur, a common contaminant of many fuels, and are vulnerable to deactivation due to carbon deposition when using carbon-containing compounds. In this review we first study the theoretical basis behind carbon and sulfur poisoning, before examining the strategies towards carbon and sulfur tolerance used so far in the SOFC literature. We then study the more extensive relevant heterogeneous catalysis literature for strategies and materials which could be incorporated into carbon and sulfur tolerant fuel cells.
Chakrabarti BK, Nir DP, Yufit V, et al., 2016, Studies of performance enhancement of rGO-modified carbon electrodes for Vanadium Redox Flow Systems, ChemElectroChem, Vol: 4, Pages: 194-200, ISSN: 2196-0216
Reduced graphene oxide (rGO) suspended in an N,N′-dimethylformamide (DMF) solvent underwent electrophoretic deposition (EPD) on carbon paper (CP) electrodes. X-ray computed micro-tomography (XMT) indicates a 24 % increase in the specific surface area of CP modified with rGO in comparison to the untreated sample. Furthermore, XMT confirms that the deposition also penetrates into the substrate. Raman analysis shows that the rGO deposited is more amorphous than the CP electrode. A significant reduction in charge-transfer resistance of the VO2+/VO2+ reaction is also observed (from impedance measurements) in modified samples in comparison to untreated CP electrodes.
Cooper SJ, Bertei A, Shearing PR, et al., 2016, TauFactor: An open-source application for calculating tortuosity factors from tomographic data, SoftwareX, Vol: 5, Pages: 203-210, ISSN: 2352-7110
TauFactor is a MatLab application for efficiently calculating the tortuosity factor, as well as volume fractions, surface areas and triple phase boundary densities, from image based microstructural data. The tortuosity factor quantifies the apparent decrease in diffusive transport resulting from convolutions of the flow paths through porous media. TauFactor was originally developed to improve the understanding of electrode microstructures for batteries and fuel cells; however, the tortuosity factor has been of interest to a wide range of disciplines for over a century, including geoscience, biology and optics. It is still common practice to use correlations, such as that developed by Bruggeman, to approximate the tortuosity factor, but in recent years the increasing availability of 3D imaging techniques has spurred interest in calculating this quantity more directly. This tool provides a fast and accurate computational platform applicable to the big datasets (>10^8 voxels) typical of modern tomography, without requiring high computational power.
Chen Z, Wang X, Brandon N, et al., 2016, Analysis of spherical indentation of porous ceramic films, Journal of the European Ceramic Society, Vol: 37, Pages: 1031-1038, ISSN: 1873-619X
Spherical indentation of a porous brittle La0.6Sr0.4Co0.2Fe0.8O3 ceramic film (porosity=39.7%) on a stiffer elastic Ce0.9Gd0.1O1.95 substrate is simulated by finite element modelling incorporating the Gurson model to account for densification. The simulated load-displacement curves, apparent elastic modulus E, indentation hardness H and densification profile are all in good agreement with experimental data for the film. The simulations show that E and H are not sensitive to film residual stress. However E is very sensitive to the indent depth-film thickness ratio f, although H is less so for f<0.3. The simulated dependence of E and H on f are highly consistent with experimental data, supporting the extrapolation of E and H measured for 0.1<f<0.3, to zero depth for good estimates of the film-alone properties. The inclusion of densification in the simulation makes only a small difference to E, but has a large influence on H as a function of indentation depth.
Ruiz Trejo E, Puolamaa M, Sum B, et al., 2016, New method for the deposition of nickel oxide in porous scaffolds for electrodes in solid oxide fuel cells and electrolyzers, Chemsuschem, Vol: 10, Pages: 258-265, ISSN: 1864-564X
A simple chemical bath deposition is used to coat a complex porous ceramic scaffold with a conformal nickel layer. The resulting composite is used as a Solid Oxide Fuel Cell electrode and its electrochemical response is measured in humidified hydrogen. X-Ray tomography is used to determine microstructural parameters of the uncoated and Ni-coated porous structure, among other, the surface area to total volume, the radial pore size and size of the necks between pores.
Direct metal laser sintering is used to create 3D hierarchical porous metallic scaffolds which are then functionalized with a co-electrodeposition of MnO2, Mn2O3, and doped conducting polymer. This approach of functionalizing metal 3D printed scaffolds thus opens new possibilities for structural energy storage devices with enhanced performance and lifetime characteristics.
Balcombe P, Anderson K, Speirs J, et al., 2016, The natural gas supply chain: the importance of methane and carbon dioxide emissions, ACS Sustainable Chemistry & Engineering, Vol: 5, Pages: 3-20, ISSN: 2168-0485
Natural gas is typically considered to be the cleaner-burning fossil fuel that could play an important role within a restricted carbon budget. While natural gas emits less CO2 when burned than other fossil fuels, its main constituent is methane, which has a much stronger climate forcing impact than CO2 in the short term. Estimates of methane emissions in the natural gas supply chain have been the subject of much controversy, due to uncertainties associated with estimation methods, data quality, and assumptions used. This Perspective presents a comprehensive compilation of estimated CO2 and methane emissions across the global natural gas supply chain, with the aim of providing a balanced insight for academia, industry, and policy makers by summarizing the reported data, locating the areas of major uncertainty, and identifying where further work is needed to reduce or remove this uncertainty. Overall, the range of documented estimates of methane emissions across the supply chain is vast among an aggregation of different geological formations, technologies, plant age, gas composition, and regional regulation, not to mention differences in estimation methods. Estimates of combined methane and CO2 emissions ranged from 2 to 42 g CO2 eq/MJ HHV, while methane-only emissions ranged from 0.2% to 10% of produced methane. The methane emissions at the extraction stage are the most contentious issue, with limited data available but potentially large impacts associated with well completions for unconventional gas, liquids unloading, and also the transmission stage. From the range of literature estimates, a constrained range of emissions was estimated that reflects the most recent and reliable estimates: total supply chain GHG emissions were estimated to be between 3.6 and 42.4 g CO2 eq/MJ HHV, with a central estimate of 10.5. The presence of “super emitters”, a small number of facilities or equipment that cause extremely high emissions, is found across all supply chai
Bertei A, Ruiz-Trejo E, Tariq F, et al., 2016, Validation of a physically-based solid oxide fuel cell anode model combining 3D tomography and impedance spectroscopy, International Journal of Hydrogen Energy, Vol: 41, Pages: 22381-22393, ISSN: 1879-3487
This study presents a physically-based model for the simulation of impedance spectra in solid oxide fuel cell (SOFC) composite anodes. The model takes into account the charge transport and the charge-transfer reaction at the three-phase boundary distributed along the anode thickness, as well as the phenomena at the electrode/electrolyte interface and the multicomponent gas diffusion in the test rig. The model is calibrated with experimental impedance spectra of cermet anodes made of nickel and scandia-stabilized zirconia and satisfactorily validated in electrodes with different microstructural properties, quantified through focused ion beam SEM tomography. Besides providing the material-specific kinetic parameters of the electrochemical hydrogen oxidation, this study shows that the correlation between electrode microstructure and electrochemical performance can be successfully addressed by combining physically-based modelling, impedance spectroscopy and 3D tomography. This approach overcomes the limits of phenomenological equivalent circuits and is suitable for the interpretation of experimental data and for the optimisation of the electrode microstructure.
Merla Y, Wu B, Yufit V, et al., 2016, Extending battery life: A low-cost practical diagnostic technique for lithium-ion batteries, Journal of Power Sources, Vol: 331, Pages: 224-231, ISSN: 1873-2755
Modern applications of lithium-ion batteries such as smartphones, hybrid & electric vehiclesand grid scale electricity storage demand long lifetime and high performance which typicallymakes them the limiting factor in a system. Understanding the state-of-health during operationis important in order to optimise for long term durability and performance. However, thisrequires accurate in-operando diagnostic techniques that are cost effective and practical. Wepresent a novel diagnosis method based upon differential thermal voltammetry demonstratedon a battery pack made from commercial lithium-ion cells where one cell was deliberately agedprior to experiment. The cells were in parallel whilst being thermally managed with forced airconvection. We show for the first time, a diagnosis method capable of quantitativelydetermining the state-of-health of four cells simultaneously by only using temperature and 2voltage readings for both charge and discharge. Measurements are achieved using low-costthermocouples and a single voltage measurement at a frequency of 1Hz, demonstrating thefeasibility of implementing this approach on real world battery management systems. Thetechnique could be particularly useful under charge when constant current or constant power iscommon, this therefore should be of significant interest to all lithium-ion battery users.
Biton M, Yufit V, Tariq F, et al., 2016, Enhanced Imaging of Lithium Ion Battery Electrode Materials, Journal of the Electrochemical Society, Vol: 164, Pages: A6032-A6038, ISSN: 0013-4651
In this study we present a novel method of lithium ion battery electrode sample preparation with a new type of epoxy impregnation,brominated (Br) epoxy, which is introduced here for the first time for this purpose and found suitable for focused ion beam scanningelectron microscope (FIB-SEM) tomography. The Br epoxy improves image contrast, which enables higher FIB-SEM resolution (3Dimaging), which is amongst the highest ever reported for composite LFP cathodes using FIB-SEM. In turn it means that the particlesare well defined and the size distribution of each phase can be analyzed accurately from the complex 3D electrode microstructureusing advanced quantification algorithms.The authors present for the first time a new methodology of contrast enhancement for 3D imaging, including novel advancedquantification, on a commercial Lithium Iron Phosphate (LFP) LiFePO4 cathode. The aim of this work is to improve the quality ofthe 3D imaging of challenging battery materials by developing methods to increase contrast between otherwise previously poorlydifferentiated phases. This is necessary to enable capture of the real geometry of electrode microstructures, which allows measurementof a wide range of microstructural properties such as pore/particle size distributions, surface area, tortuosity and porosity. Theseproperties play vital roles in determining the performance of battery electrodes.
Liu X, Wu B, Brandon NP, et al., 2016, Tough ionogel-in-mask hybrid gel electrolytes in supercapacitors with durable pressure and thermal tolerances, Energy Technology, Vol: 5, Pages: 220-224, ISSN: 2194-4288
A primary challenge of gel electrolytes in development of flexible and wearable devices is their weak mechanical performances, including their compressive stress, tensile strength, and puncture resistance. Here we prepare an ionogel-mask hybrid gel electrolyte, which successfully achieves synergic advantages of the high mechanical strength of the mask substance and the superior electrochemical and thermal characteristics of the ionogel. The fabricated supercapacitor can maintain a relatively stable capacitive performance even under a high pressure of 3236 kPa. Meanwhile, with the good thermal stability of the composite gel electrolyte, the solid-state supercapacitor can be operated at high temperatures ranging from 25 °C to 200 °C. The ionogel-mask hybrid gel can be superior tough gel electrolyte for solid-state flexible supercapacitors with durable advantages in both high temperatures and pressures.
Wu B, Parkes MP, de Benedetti L, et al., 2016, Real-time monitoring of proton exchange membrane fuel cell stack failure, Journal of Applied Electrochemistry, Vol: 46, Pages: 1157-1162, ISSN: 1572-8838
Uneven pressure drops in a 75-cell 9.5-kWe protonexchange membrane fuel cell stack with a U-shaped flowconfiguration have been shown to cause localised flooding.Condensed water then leads to localised cell heating, resultingin reduced membrane durability. Upon purging of the anodemanifold, the resulting mechanical strain on the membranecan lead to the formation of a pin-hole/membrane crack and arapid decrease in open circuit voltage due to gas crossover.This failure has the potential to cascade to neighbouring cellsdue to the bipolar plate coupling and the current densityheterogeneities arising from the pin-hole/membrane crack.Reintroduction of hydrogen after failure results in cell voltageloss propagating from the pin-hole/membrane crack locationdue to reactant crossover from the anode to the cathode, giventhat the anode pressure is higher than the cathode pressure.Through these observations, it is recommended that purging isavoided when the onset of flooding is observed to preventirreparable damage to the stack.
Dong J, Wu X, Chen Y, et al., 2016, A study on Pb2+/Pb electrodes for soluble lead redox flow cells prepared with methanesulfonic acid and recycled lead, Journal of Applied Electrochemistry, Vol: 46, Pages: 861-868, ISSN: 1572-8838
Electrodeposition and electrodissolution reactionsof the Pb2?/Pb electrode were studied on a glassy carbonrotating disk electrode in aqueous solutions of CH3SO3H andPb(CH3SO3)2. The electrolytic parameters, kinematic viscosityand ionic conductivity, were determined with variousconcentrations of CH3SO3H and Pb(CH3SO3)2. The diffusioncoefficient of Pb2? in this electrolyte prepared with CH3SO3Hwas determined by the Levich Equation. Both the concentrationsof CH3SO3H and Pb(CH3SO3)2 were found responsiblefor the equilibrium potential shifts and exchange currentdensity variations. The electrochemical processes at the Pb2?/Pb electrode were identified as being under mixed ohmicdiffusioncontrol. The electrolyte conductivity and the ionicactivity of Pb2? were recognized as important parameters fordesigning the soluble lead redox flow cells. During constantcurrent charge–discharge measurement, the specific capacityof the Pb2?/Pb electrode was about 253 mAh g-1Pb, about98 % of the theoretical value. The impurity elements Fe, Ba,Al, and Zn in the Pb2? electrolytes prepared with recycledlead exhibited insignificant influences on the Pb2?/Pb reactions.It is reasonable to believe that the recycled lead can beapplied in soluble lead redox flow batteries, and the cost maybe further reduced with recycled lead because expensiveimpurity-control processes seemed to be avoidable.
Chen Z, Wang X, Atkinson A, et al., 2016, Spherical indentation of porous ceramics: cracking and toughness, Journal of the European Ceramic Society, Vol: 36, Pages: 3473-3480, ISSN: 0955-2219
A combined experimental-numerical approach is used to characterise the fracture of a porous bulk ceramic material (La0.6Sr0.4Co0.2Fe0.8O3) with porosities of 5-45%, undergoing spherical indentation. The Gurson model was used in FEM to describe the densification of the porous material. Indentation-induced radial cracks were observed, when the applied nominal contact pressure exceeded threshold values, with no Hertzian ring-cone cracks found. FEM analysis indicated that the cracks propagated mainly during unloading, driven by the tensile hoop stress generated near the contact circle. The stress intensity at the crack tip was estimated using an approximate analysis of the FEM stress field to derive toughness values that were consistent with values determined by conventional methods, provided that the crack length is sufficiently large compared with the contact radius and can be measured accurately. The absence of ring-cone cracks in the elastic field during loading is due to the material’s high modulus-to-hardness ratio and the small indenter radius as predicted by established theory.
Wu B, Ibrahim KA, Brandon NP, 2016, Electrical conductivity and porosity in stainless steel 316L scaffolds for electrochemical devices fabricated using selective laser sintering, Materials and Design, Vol: 109, Pages: 51-59, ISSN: 1873-4197
Battery electrode microstructures must be porous, to provide a large active surface area to facilitate fast charge transfer kinetics. In this work, we describe how a novel porous electrode scaffold, made from stainless steel 316L powder can be fabricated using selective laser sintering by proper selection of process parameters. Porosity, electrical conductivity and optical microscopy measurements were used to investigate the properties of fabricated samples. Our results show that a laser energy density between 1.50–2.00 J/mm2 leads to a partial laser sintering mechanism where the powder particles are partially fused together, resulting in the fabrication of electrode scaffolds with 10% or higher porosity. The sample fabricated using 2.00 J/mm2 energy density (60 W–1200 mm/s) exhibited a good electrical conductivity of 1.80 × 106 S/m with 15.61% of porosity. Moreover, we have observed the porosity changes across height for the sample fabricated at 60 W and 600 mm/s, 5.70% from base and increasing to 7.12% and 9.89% for each 2.5 mm height towards the top surface offering graded properties ideal for electrochemical devices, due to the changing thermal boundary conditions. These highly porous electrode scaffolds can be used as an electrode in electrochemical devices, potentially improving energy density and life cycle.
Budinis S, Krevor S, Mac Dowell N, et al., 2016, Can technology unlock unburnable carbon?
In 2015, the Conference Of the Parties in Paris (COP21) reached a universal agreement on climate change with the aim of limiting global warming to below 2 °C. In order to stay below 2 °C, the total amount of carbon dioxide (CO2) released, or ‘carbon budget’ must be less than 1,000 gigatonnes (Gt) of CO2. At the current emission rate, this budget will be eroded within the next thirty years. Meeting this target on a global scale is challenging and will require prompt and effective climate change mitigation action.The concept of ‘unburnable carbon’ emerged in 2011, and stems from theobservation that if all known fossil fuel reserves are extracted and converted to CO2 (unabated), it would exceed the carbon budget and have a very significant effect on the climate. Therefore, if global warming is to be limited to the COP21 target, some of the known fossil fuel reserves should remain unburnt.Several recent reports have highlighted the scale of the challenge, drawing on scenarios of climate change mitigation and their implications for the projected consumption of fossil fuels. Carbon capture and storage (CCS) is a critical and available mitigation opportunity that is often overlooked. The positive contribution of CCS technology to timely and cost-effective decarbonisation of the energy system is widely recognised. However, while some studies have considered the role of CCS in enabling access to more fossil fuels, no detailed analysis on this issue has been undertaken.This White Paper presents a critical review focusing on the technologies that can be applied to enable access to, or ‘unlock’, fossil fuel reserves in a way that will meet climate targets and mitigate climate change.The paper includes an introduction to the key issues of carbon budgets and fossil fuel reserves, a detailed analysis of the current status of CCS technology, as well as a synthesis of a multi-model comparison study on global climate change mitigation strat
Blanga R, Berman M, Biton M, et al., 2016, Peculiarities of ion transport in confined-in-ceramics concentrated polymer electrolytes, Electrochimica Acta, Vol: 208, Pages: 71-79, ISSN: 1873-3859
Polyethylene-oxide/lithium-aluminate films were deposited by electrophoretic deposition. Films impregnated with lithium iodide formed highly concentrated polymer-in-ceramic solid electrolytes. Solid-state NMR, FIB-SEM tomography with modelling, and EIS studies showed that only a few percent of the interfacial lithium in the sample is capable of inducing a fast ion-migration path in the system. We suggest that despite suppressed crystallinity of PEO confined in ceramics the ion transport in the polymer medium impedes the total conductivity of the composite electrolyte at near-ambient temperatures. After melting of the polymer and its complexes, the interfacial conduction through perpendicular LiAlO2/LiI grain boundaries becomes feasible. This, together with ion transport via molten, confined polymer electrolyte is followed by the increase of the overall conductivity of the composite system.
Jamil Z, Ruiz-Trejo E, Boldrin P, et al., 2016, Anode fabrication for solid oxide fuel cells: Electroless and electrodeposition of nickel and silver into doped ceria scaffolds, International Journal of Hydrogen Energy, Vol: 41, Pages: 9627-9637, ISSN: 1879-3487
A novel fabrication method using electroless and electrodeposited Ni/Ag/GDC for SOFC anodes is presented. First a porous Ce0.9Gd0.1O2−x (GDC) scaffold was deposited on a YSZ electrolyte by screen printing and sintering. The scaffold was then metallized with silver using Tollens' reaction, followed by electrodeposition of nickel from a Watt's bath. The electrodes (Ni/Ag/GDC) were tested in both symmetrical and fuel cell configurations. The microstructures of the Ni/Ag/GDC anodes were analyzed using scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX). Nano-particles of Ni formed in the porous GDC scaffold provided triple phase boundaries (TPB). The electronic conductivity of the Ni/Ag/GDC (3.5/24.7/71.8 vol%) electrode was good even at relatively low Ni volume fractions. The electrochemical performance was examined in different concentrations of humidified hydrogen (3% H2O) and over a range of temperatures (600–750 °C). The total area specific resistance (ASR) of the anode at 750 °C in humidified 97 vol% H2 was 1.12 Ω cm2, with low-frequency polarization (R_l) as the largest contributor. The electrodes were successfully integrated into a fuel cell and operated in both H2 and syngas.
Chen Z, Brandon N, 2016, Inkjet Printing and Nanoindentation of Porous Alumina Multilayers, Ceramics International, Vol: 42, Pages: 8316-8324, ISSN: 0272-8842
The objectives of this study were to analyse the effect of inkjet 3-D printing parameters,particularly the splat overlap distance, for the fabrication of defect-free porous Al2O3 ceramicmultilayers, and to correlate the resulting porosities with the mechanical properties measured usingnanoindentation. An aqua-based alumina ink was used in this study to fabricate the multilayers ondense alumina substrates by inkjet printing. The as-printed specimens were dried and sintered at 1200– 1500 °C. The resulting microstructural features of each specimen and their corresponding porositieswere studied using FIB-SEM. Elastic modulus and hardness were determined using the sphericalnanoindentation technique. Results showed that defect-free porous alumina multilayers with excellentlayer to layer and layer to substrate integrity were successfully fabricated. The porosity-dependence ofthe elastic modulus and hardness was shown to be consistent with values predicted using empiricalexpressions, despite the presence of abnormal grain growth at higher temperatures.
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