160 results found
Kioupi V, Voulvoulis N, 2019, Education for sustainable development: A systemic framework for connecting the SDGs to educational outcomes, Sustainability, Vol: 11, Pages: 1-18, ISSN: 2071-1050
The UN 2030 agenda of Sustainable Development Goals (SDGs) envisions a future of inclusive equity, justice and prosperity within environmental limits, and places an important emphasis on education as stated in Goal 4. Education is acknowledged as a means for achieving the remaining Goals, with sustainability as a goal for education in target 4.7. However, the interconnectedness of the SDGs and the complexity of sustainability as a concept make it difficult to relate the SDGs to educational learning outcomes, with what Education for Sustainable Development (ESD) aims to achieve, left in ambiguity. Using systems thinking, we developed a framework that redefines ESD as a tool that can deliver the transformation required for society to reach a sustainable state. Using the SDGs as end points for this state, and through a participatory approach, education stakeholders and learners work together to construct a common vision of sustainability, identify the competences needed, and develop appropriate pedagogies and learning strategies. The framework allows for the development of evaluation tools that can support educational institutions to monitor and manage their progress in transforming societies towards sustainability.
Gomez-Gonzalez MA, Koronfel MA, Goode AE, et al., 2019, Spatially resolved dissolution and speciation changes of ZnO nanorods during short-term in situ incubation in a simulated wastewater environment, ACS Nano, Vol: 13, Pages: 11049-11061, ISSN: 1936-0851
Zinc oxide engineered nanomaterials (ZnO ENMs) are used in a variety of applications worldwide due to their optoelectronic and antibacterial properties with potential contaminant risk to the environment following their disposal. One of the main potential pathways for ZnO nanomaterials to reach the environment is via urban wastewater treatment plants. So far there is no technique that can provide spatiotemporal nanoscale information about the rates and mechanisms by which the individual nanoparticles transform. Fundamental knowledge of how the surface chemistry of individual particles change, and the heterogeneity of transformations within the system, will reveal the critical physicochemical properties determining environmental damage and deactivation. We applied a methodology based on spatially resolved in situ X-ray fluorescence microscopy (XFM), allowing observation of real-time dissolution and morphological and chemical evolution of synthetic template-grown ZnO nanorods (∼725 nm length, ∼140 nm diameter). Core-shell ZnO-ZnS nanostructures were formed rapidly within 1 h, and significant amounts of ZnS species were generated, with a corresponding depletion of ZnO after 3 h. Diffuse nanoparticles of ZnS, Zn3(PO4)2, and Zn adsorbed to Fe-oxyhydroxides were also imaged in some nonsterically impeded regions after 3 h. The formation of diffuse nanoparticles was affected by ongoing ZnO dissolution (quantified by inductively coupled plasma mass spectrometry) and the humic acid content in the simulated sludge. Complementary ex situ X-ray absorption spectroscopy and scanning electron microscopy confirmed a significant decrease in the ZnO contribution over time. Application of time-resolved XFM enables predictions about the rates at which ZnO nanomaterials transform during their first stages of the wastewater treatment process.
Voulvoulis N, Zogheib C, 2019, Climate change and the human-made water cycle: Implications for the UK water sector, Climate change and the human-made water cycle: Implications for the UK water sector, www.imperial.ac.uk/grantham, Publisher: The Grantham Institute, Briefing paper number 32
Climate change is already happening, and the UK’s climate will continue to change as a result of greenhouse gas emissions, with the long-term resilience of its infrastructure at risk.The water sector cannot adapt to the challenges of climate change in isolation, as policy effects in one sector will have indirect effects in others.Current demand pressures and reductions in abstraction licences – rights to draw water – are causing supply-demand deficits and this is coupled to the impacts of climate change. If no action is taken, the current high standards of service that is offered at a fair price, and without causing environmental damage, could soon be at risk.While impact on water flows might not yet be measurable, there is evidence to show that if water companies carry on with ‘business as usual’, we risk a future without enough water for people, business, farmers, wildlife and the environment.With water as the key medium that links atmospheric temperature rises to changes in human and physical systems, government, water companies and all the players in the wider sector need to play a more proactive role in accelerating the transition to a circular economy, while helping people, politicians and decision makers to understand and prepare for the risks of climate change.
Hopkinson NS, Arnott D, Voulvoulis N, 2019, Environmental consequences of tobacco production and consumption (vol 394, pg 1007, 2019), LANCET, Vol: 394, Pages: 1324-1324, ISSN: 0140-6736
Hopkinson NS, Arnott D, Voulvoulis N, 2019, Environmental consequences of tobacco production and consumption, The Lancet, Vol: 394, Pages: 1007-1008, ISSN: 0140-6736
Voulvoulis N, Pavanelli DD, 2019, Habitat equivalency analysis, a framework for forensic cost evaluation of environmental damage, Ecosystem Services, Vol: 38, ISSN: 2212-0416
When environmental damage takes place, forensic experts investigate and undertake initial damage assessments. Determining damage costs can be challenging in terms of remedial action and of assigning monetary value to losses. We develop a Habitat Equivalency Analysis (HEA) framework to assess environmental damage costs and apply it to three case studies from the Brazilian Atlantic Rainforest (BAR). Remediation costs have been used previously as proxies for valuing ecosystem services (ES). In this approach, interim losses, those ES not supplied till the damage is restored, are accounted as compensatory remediation costs, the costs of resource enhancement or creation that compensates for the loss in ES provision. We compared values derived here to those using an alternative valuation, based on a tropical forest’s average annual value (Int.$/ha/year), as described in the literature. Findings demonstrate the potential of the framework to account for interim losses, perpetual damages and the cost of remediation. Although the three study areas varied in the extent of damage and the remediation procedures, the damage cost per hectare was of the same order of magnitude and within a narrow range: 13,216; 28,024; and 19,681 (in 2017 Int.$/ha) for the Citrus; Sand Mining and Eucalyptus study areas respectively. The environmental damage costs per hectare appraised by the alternative valuation were higher and showed greater variation: 32,692; 139,389; and 38,260 (in 2017 Int.$/ha) respectively. The experimental data were shown to be within the range of theoretical results derived. As HEA valuation is solely based on ecosystem damage remediation principles, its application will provide a more robust platform for the evaluation of the total economic value of tropical forests, even in the early stages of damage assessments.
Voulvoulis N, Burgman M, 2019, The contrasting roles of science and technology in environmental challenges, Critical Reviews in Environmental Science and Technology, Vol: 49, Pages: 1079-1106, ISSN: 1064-3389
Sustainable development is widely recognised as an existential challenge. To address it, humanity needs to change its ways. However, people seem slow to act, not always understanding and often denying environmental imperatives, creating substantial social and psychological barriers. Social inertia and denial have been allegedly amplified by a public discourse increasingly distrustful of science. But is this discourse a rejection of science or an erosion of trust in how science is applied? The paper examines the main differences between environmental science and technology, reviews how the wider science- technology convergence has affected them and evaluates potential implications for sustainability challenges. We question whether the ‘convergence’ between environmental science and technology, could be behind the growing public dissatisfaction and distrust of environmental science and policies. Although environmental science plays a role in enabling understanding and communicating complexity, technology requires political, social and economic skills, beyond conventional disciplinary expertise. To avoid putting academic freedom at risk, environmental technologists, a new breed of professionals, should have a clear understanding of scientific capacity and uncertainty and be able to engage with stakeholders, policy makers and the public to design integrated, interdisciplinary and holistic solutions, and also better define the many environmental problems we face.
Giakoumis T, Voulvoulis N, 2019, Water Framework Directive programmes of measures: Lessons from the 1st planning cycle of a catchment in England, Science of The Total Environment, Vol: 668, Pages: 903-916, ISSN: 0048-9697
The European Union's Water Framework Directive (WFD) required Member States to establish programmes of measures to achieve good water status formally by 2015, but on postponing the deadline by two six-year periods, by 2027 at the latest. With many Member States facing problems with developing such measures in the first planning cycle, and limited change in ecological status since the first river basin management plans were reported, we look at the implementation of the Directive in England, where only 17% of the surface water bodies were found at good status in 2015, a reduction of 4% since 2009. Using as a case study the Broadland Rivers catchment, we examine the measures taken for Cycle 1 and changes in the classifications of water body status, to investigate whether the way the measures were developed could have limited their potential to deliver WFD objectives. While the WFD was adopted to succeed and replace management practices targeting individually non-compliant element, findings indicate that little had changed in the way measures were developed. Although considerable progress has been made on the implementation of these measures, the limited progress in improving classifications demonstrates the limits of this approach and further makes the case for what the WFD was introduced for: the harmonised transposition of the Integrated River Basin Management paradigm, as the key for delivering good ecological status.
Mohamad Ibrahim IH, Gilfoyle L, Reynolds R, et al., 2019, Integrated catchment management for reducing pesticide levels in water: Engaging with stakeholders in East Anglia to tackle metaldehyde, Science of the Total Environment, Vol: 656, Pages: 1436-1447, ISSN: 0048-9697
In the agriculture intensive eastern region of England, plant protection products are widely applied to protect crops such as wheat and oilseed rape from pests and diseases, thus creating a risk of reaching nearby water courses through surface runoff. The EU Drinking Water Directive sets a stringent limit of 0.1 μg/l and 0.5 μg/l for individual and total pesticides respectively in treated potable water. However, peak metaldehyde levels have been persistently detected in raw water and reducing them to these limits has proven challenging and costly, in particular when using conventional treatment. In line with the EU Water Framework Directive, a more suitable approach and one adopted by the local water company, Anglian Water Services Ltd., would require moving towards mitigating pollution at source, preferably through participative action with multiple stakeholders in the agricultural industry. Initial findings demonstrate the potential of product substitution for reducing metaldehyde levels in surface waters. Reviewing Anglian Water's “Slug it Out” trial, we discuss key learnings derived from their experiences and make recommendations about the potential of the catchment approach to address the wider pesticide challenge.
Iacovidou E, Voulvoulis N, 2018, A multi-criteria sustainability assessment framework: development and application in comparing two food waste management options using a UK region as a case study, Environmental Science and Pollution Research, Vol: 25, Pages: 35821-35834, ISSN: 0944-1344
Preventing food wastage is a key element of sustainable resource management. But as food waste is still generated at high volumes, priority is placed on its proper management as a resource, maximising sustainability benefits. This study, by integrating a multi-criteria decision analysis with a sustainability assessment approach, develops a screening and decision support framework for comparing the sustainability performance of food waste management options. A structured process for selecting criteria based on the consideration of environmental, economic and social aspects related to region-specific food waste system planning, policy and management has been developed. Two food waste management options, namely the use of food waste disposal units, which grind food waste at the household’s kitchen sink and discharge it to the sewer, and the anaerobic co-digestion of separately collected food waste with sewage sludge, were selected for comparison due to their potential to create synergies between local authorities, waste and water companies, with local circumstances determining which of the two options to adopt. A simplified process used for assessing and comparing the two food waste management options in the Anglian region in the UK, indicated that there are benefits in using the framework as a screening tool for identifying which option may be the most sustainable. To support decision-making, a detailed analysis that incorporates stakeholders’ perspectives is required. An additional use of the framework can be in providing recommendations for optimising food waste management options in a specific region, maximising their sustainability performance.
Giakoumis T, Voulvoulis N, 2018, A participatory ecosystems services approach for pressure prioritisation in support of the Water Framework Directive, Ecosystem Services, Vol: 34, Pages: 126-135, ISSN: 2212-0416
The pressure and impact analysis is an important process in integrated river basin management and a key procedural element of the EU Water Framework Directive. It aims to inform both the assessment of water body status and the development of management responses. However, the Directive does not provide prescriptive guidance on how it should be carried out and during the 1st river basin cycle, its application proved to be a real challenge. Incorporating ecosystem services as indicators of impacts, a participatory framework for pressure prioritisation is presented here. While various methods exist for engaging stakeholders in river basin management, the framework allows for the ecosystem approach to be operationalised through a risk assessment perspective, in the context of the pressure impact analysis. Applying this to a case study in England, we demonstrate how a ranking of pressures can be delivered based on stakeholders’ perception of how the delivery of ecosystem services is affected by each pressure and incorporating their value as indicator of the magnitude of the impact. This approach allows for a more systematic way to effectively prioritise significant pressures and therefore select appropriate programmes of measures in line with the Directive's integrated river basin management paradigm.
Giakoumis T, Voulvoulis N, 2018, The transition of EU water policy towards the Water Framework Directive’s Integrated River Basin Management paradigm, Environmental Management, Vol: 62, Pages: 819-831, ISSN: 0364-152X
Introduced in 2000 to reform and rationalise water policy and management across the European Union (EU) Member States (MS), the Water Framework Directive (WFD), the EU’s flagship legislation on water protection, is widely acknowledged as the embodiment and vessel for the application of the Integrated River Basin Management (IRBM) paradigm. Its ecological objectives, perhaps even more challenging than the prospect of statutory catchment planning itself, were for all EU waters to achieve ‘good status’ by 2015 (except where exemptions applied) and the prevention of any further deterioration. In support of the upcoming WFD review in 2019, the paper reviews the transition of EU policies that led to the adoption of the WFD, to identify the reasons why the Directive was introduced and what it is trying to deliver, and to place progress with its implementation into context. It further investigates reasons that might have limited the effectiveness of the Directive and contributed to the limited delivery and delays in water quality improvements. Findings reveal that different interpretations on the Directive’s objectives and exemptions left unresolved since its negotiation, ambiguity and compromises observed by its Common Implementation Strategy and lack of real support for the policy shift required have all been barriers to the harmonised transposition of the IRBM paradigm, the key to delivering good ecological status. The 2019 WFD review offers a unique opportunity to realign the implementation of the Directive to its initial aspirations and goals.
Burgman MA, Tennant M, Voulvoulis N, et al., 2018, Facilitating the transition to sustainable green chemistry, Current Opinion in Green and Sustainable Chemistry, Vol: 13, Pages: 130-136, ISSN: 2452-2236
Sustainable green chemistry depends on technically feasible, cost-effective and socially acceptable decisions by regulators, industry and the wider community. The discipline needs to embrace a new suite of tools and train proponents in their use. We propose a set of tools that will bridge the gap between technical feasibility and efficiency on one hand, and social preferences and values on the other. We argue that they are indispensable in the next generation of regulators and chemistry industry proponents.
Zafeiridou M, Hopkinson NS, Voulvoulis N, 2018, Cigarette Smoking: An assessment of tobacco's global environmental footprint across its entire supply chain., Environmental Science and Technology, Vol: 52, Pages: 8087-8094, ISSN: 0013-936X
While the health effects of cigarette smoking are well recognised and documented, the environmental impacts of tobacco are less appreciated and often overlooked. Here we evaluate tobacco's global footprint across its entire supply chain, looking at resources needs, wastes and emissions of the full cradle-to-grave life cycle of cigarettes. The cultivation of 32.4 Mt of green tobacco used for the production of 6.48 Mt of dry tobacco in the six trillion cigarettes manufactured worldwide in 2014, were shown to contribute almost 84 Mt CO2 eq emissions to climate change - approximately 0.2% of the global total, 490,000 tonnes 1,4 dichlorobenzene eq to ecosystem ecotoxicity levels, over 22 billion m3 and 21 Mt oil eq to water and fossil fuel depletion respectively. A typical cigarette was shown to have a water footprint of 3.7 litres, a climate change contribution of 14 g CO2 eq, and a fossil fuel depletion contribution of 3.5 g oil eq. Tobacco competes with essential commodities for resources and places significant pressures on the health of our planet and its most vulnerable inhabitants. Increased awareness as well as better monitoring and assessment of the environmental issues associated with tobacco should support the current efforts to reduce global tobacco use as an important element of sustainable development.
Giakoumis T, Voulvoulis N, 2018, Progress with monitoring and assessment in the wfd implementation in five european river basins: Significant differences but similar problems, European Journal of Environmental Sciences, Vol: 8, Pages: 44-50, ISSN: 1805-0174
The river basin approach of the Water Framework Directive (WFD) and the introduction of ecological status represent a shift in the assessment and management of freshwater systems from discipline-specific to more holistic, catchment-based principles. At the core of the WFD’s approach are catchments as highly interconnected systems. Despite strict timetables, progress towards achieving the WFD objectives has been slow, with deterioration in some cases not being halted. In this paper, looking at evidence from five European basins (Adige, Anglian, Ebro, Evrotas and Sava) we identify some of the key implementation challenges faced by each catchment during the development and implementation of the 1st River Basin Management Plans (RBMPs) of 2009. Despite significant differences in socio-ecological conditions, geographic coverage and starting points in the implementation between these river basins, findings highlight some similar key issues. The lack of a common systemic understanding of each river basin and detailed monitoring data to capture pressure-status interactions in order to anticipate how the system will react to interventions; as well as compliance driven implementation efforts were underlying problems in all five study areas. While some improvements to address these problems can be seen in the 2nd River Basin Management Planning Cycle (2015–2016), our findings demonstrate that a more effective approach is to question the deviation of the whole implementation from the directive’s systemic nature and therefore improve the adaptive, collaborative, participatory and interdisciplinary nature of the implementation efforts.
Facchini E, Iacovidou E, Gronow J, et al., 2018, Food flows in the United Kingdom: the potential of surplus food redistribution to reduce waste, Journal of the Air and Waste Management Association, Vol: 68, Pages: 887-899, ISSN: 2162-2906
The increasing amount of food waste generated as a direct consequence of its excessive production, mismanagement, and wasteful behaviors represents a real challenge in promoting resource efficiency. In the United Kingdom (UK), the lack of robust mass flow data hinders the ability both to understand and address food waste challenges and to devise long-term sustainable prevention strategies. In recognition of these challenges, this paper seeks to (i) provide insights into the UK's annual estimates of food mass flows, including imports, exports, distribution, consumption, surplus food production, and final disposal; and (ii) scrutinize the uptake and redistribution of surplus food as a potential food waste prevention strategy. Evidence collected from several enterprises and community-led initiatives in the UK, and London specifically, supports that there is an increasing potential of making a shift towards food redistribution and reuse. Further analysis has shown that the outreach of food redistribution initiatives in the UK is currently limited, possibly because redistribution efforts remain largely fragmented and independent from each other. It is concluded that a national commitment could be instrumental in encouraging the roll-out of this practice, and governmental support through fiscal incentives could lead to the development of a larger and coherent surplus food redistribution system, ultimately enabling food waste prevention and recovery of food's multidimensional value. IMPLICATIONS: This paper deals with the topical issue of the increasing amount of food waste generated as a direct consequence of excessive production, mismanagement, and wasteful behavior, representing a real challenge in achieving sustainability and resource efficiency. Currently, only a small fraction of food is redistributed back into the system. Yet, a considerable fraction of food waste generated is edible; thus, better planning, storage, and coordination amongst the different stakeholder
Voulvoulis N, 2018, Water reuse from a circular economy perspective and potential risks from an unregulated approach, Current Opinion in Environmental Science & Health, Vol: 2, Pages: 32-45, ISSN: 2468-5844
Considerations including water scarcity in arid and semi-arid regions, water security concerns in areas where water demand exceeds water availability, and rigorous and costly requirements to remove nutrients and emerging contaminants from effluent discharge to surface waters have driven water reuse as an alternate water supply in some parts of the world. However, the potential of reusing treated wastewater has not yet been exploited in many areas. A transition to a circular economy could create significant synergies for the wide adoption of water reuse as an alternate water supply. This paper therefore examines opportunities and risks with the transition to such an economy. Findings show that although many of the barriers water reuse is facing, ranging from public perception to pricing and regulatory challenges, could be addressed more effectively through a wider circular economy perspective, care must be taken with regulating and monitoring levels of contaminants in the recycled water according to its use. A review of existing reuse schemes and regulations across the world, found variation, demonstrating the need for assessing benefits and risks on a case by case basis. Recycling and reuse are central to a circular economy approach and offer a strategy to improve water supply by managing wastewater better. Such strategy should also ensure the safety of water reuse, and therefore apply water quality standards appropriate to the specific use, but also ensure adequate and reliable operation of water reuse systems and appropriate regulatory enforcement.
Manap N, Voulvoulis N, 2016, Data analysis for environmental impact of dredging, Journal of Cleaner Production, Vol: 137, Pages: 394-404, ISSN: 0959-6526
The aim of this paper is twofold; first is to identify the environmental impact of dredging related to water and sediment quality; and second is to identify the main factors determining the environmental impact of dredging. The method of this research is data analysis using historical dredging data from three dredging projects performed from 2006 to 2008 at two connected rivers in Perak, Malaysia. The indices measured to identify the impact include: total suspended solids, dissolved oxygen, chemical oxygen demand, biochemical oxygen demand, pH, total organic content, iron, zinc, manganese, copper, chromium, mercury, arsenic, and lead. The factors are then identified through determination of relationships between concentration levels in sediment and water and identification of patterns of impact in the water and caged fish during dredging activities. The results of the analysis show that dredging performed in these rivers has an impact on the environment. The impact includes an increase in levels of most of the monitored indices, including dissolved oxygen and metal concentrations in highly contaminated areas. The main factors associated with the environmental impacts of dredging are the contamination level of the sediment and the contamination level of the neighbouring area, aspects that are the main scientific value added by this paper. This paper draws conclusions regarding the importance of two analyses prior to commencement of dredging: sediment quality analysis and analysis of contamination level in the neighbouring area prior to dredging. The results of this paper could help to better anticipate the environmental impact of dredging and allow for suitable mitigation measures to be identified, especially for developing countries such as Malaysia.
Voulvoulis N, Arpon KD, Giakoumis T, 2016, The EU Water Framework Directive: From great expectations to problems with implementation, Science of the Total Environment, Vol: 575, Pages: 358-366, ISSN: 0048-9697
The Water Framework Directive 2000/60/EC (WFD) is widely accepted as the most substantial and ambitious piece of European environmental legislation to date. It has been referred to as a once in a generation opportunity to restore Europe's waters and a potential template for future environmental regulations. However, fifteen years since it was adopted, and with many problems and delays in its implementation, the WFD has not delivered its main objectives of non-deterioration of water status and the achievement of good status for all EU waters. Putting aside the daunting technical and organisational challenges of its implementation, this paper aims to shed light on why the great expectations that came with the WFD have not yet been fully realised. It reviews how the Directive has been interpreted, focusing on its intentions and how they were applied. The findings reveal the absence of the paradigm shift towards the systems (integrated) thinking that the WFD was grounded on, as a fundamental problem with its implementation. This is also evident in cases where the Directive has been criticised as a policy tool or when implementation efforts were reviewed, indicating misunderstandings even of its core principles. This inherent departure from the Directive's systemic intention and methodological approach needs further investigation, as it could be the reason behind many of its problems and delays. Unless current implementation efforts are reviewed or revised in light of this, enabling the paradigm shift required to ensure a more sustainable and holistic approach to water management, the fading aspirations of the initial great expectations that came with the Directive could disappear for good.
Kirkman R, Voulvoulis N, 2016, The role of public communication in decision making for waste management infrastructure, Environmental Management, Vol: 203, Pages: 640-647, ISSN: 1432-1009
Modern waste management provision seeks to meet challenging objectives and strategies while reflecting community aspirations and ensuring cost-effective compliance with statutory obligations. Its social acceptability, which affects both what systems (infrastructure) can be put in place and to what extent their implementation will be successful, is a multi-dimensional phenomenon, often not well understood. In light of the growing evidence that decisions to build new infrastructure are often contested by the public, there is a clear need to understand the role of scientific evidence in public perception, particularly as environmental infrastructure delivery is often objected to by the public on environmental grounds. In this paper the need for waste management infrastructure is reviewed, and the way its delivery in the UK has evolved is used as an example of the role of public perception in the planning and delivery of waste facilities. Findings demonstrate the vital role of public communication in waste management infrastructure delivery. Public perception must be taken into account early in the decision making process, with the public informed and engaged from the start. There is a pressing need for people not simply to accept but to understand and appreciate the need for infrastructure, the nature of infrastructure investments and development, the costs and the benefits involved, and the technological aspects. Scientific evidence and literacy have a critical role to play, facilitating public engagement in a process that empowers people, allowing them to define and handle challenges and influence decisions that will impact their lives. Problem ownership, and an increased probability of any solutions proposed being selected and implemented successfully are potential benefits of such approach.
Stanley E, Plant J, Voulvoulis N, 2016, Environmental chemical exposures and breast cancer, AIMS Environmental Science, Vol: 3, Pages: 96-114, ISSN: 2372-0352
As a hormone-sensitive condition with no single identifiable cause, breast cancer is a major health problem. It is characterized by a wide range of contributing factors and exposures occurring in different combinations and strengths across a lifetime that may be amplified during periods of enhanced developmental susceptibility and impacted by reproductive patterns and behaviours. The vast majority of cases are oestrogen-receptor positive and occur in women with no family history of the disease suggesting that modifiable risk factors are involved. A substantial body of evidence now links oestrogen-positive breast cancer with environmental exposures. Synthetic chemicals capable of oestrogen mimicry are characteristic of industrial development and have been individually and extensively assessed as risk factors for oestrogen-sensitive cancers. Existing breast cancer risk assessment tools do not take such factors into account. In the absence of consensus on causation and in order to better understand the problem of escalating incidence globally, an expanded, integrated approach broadening the inquiry into individual susceptibility breast cancer is proposed. Applying systems thinking to existing data on oestrogen-modulating environmental exposures and other oestrogenic factors characteristic of Westernisation and their interactions in the exposure, encompassing social, behavioural, environmental, hormonal and genetic factors, can assist in understanding cancer risks and the pursuit of prevention strategies. A new conceptual framework based on a broader understanding of the “system” that underlies the development of breast cancer over a period of many years, incorporating the factors known to contribute to breast cancer risk, could provide a new platform from which government and regulators can promulgate enhanced and more effective prevention strategies.
Voulvoulis N, Barceló D, Verlicchi P, 2016, Pharmaceutical residues in sewage treatment works and their fate in the receiving environment
© The Royal Society of Chemistry 2016. Pharmaceuticals are increasingly used in large amounts in human (and veterinary) medicine around the world. They reach the aquatic environment mainly through sewage treatment systems and can reach mg l×1 levels. The continual input of pharmaceuticals to the aquatic environment, via sewage, can also impart a persistent quality to compounds that otherwise possess no inherent environmental stability. While the literature contains increasing numbers of studies detailing fate, effects and behaviour in the environment, the subject is still not fully understood for all the different therapeutic classes. The toxicological significance for non-target (especially aquatic) organisms is poorly understood. The use/release of antibiotics and natural/synthetic steroids to the environment has generated most of the concern to date, but a plethora of other drugs are increasingly attracting attention, as their biological activity alone may support ecotoxicity assessments of those compounds with high production volumes (or toxicity), especially in view of the increasing importance of freshwater resources. Pharmaceuticals display a variety of removal efficiencies during wastewater treatment and their fate and behaviour are not determined by their physicochemical properties alone. Despite the fact that many drugs have high sorption potentials, partitioning to the solid phase was determined to be an unlikely removal pathway for the majority of compounds. The partitioning behaviour of these compounds both in sewage treatment and the aquatic environment is likely to be dictated by a number of physicochemical parameters. Findings also indicate that the costs of using tertiary treatment options (mainly based on drinking water treatment) to remove drugs from wastewater effluent are likely to be prohibitively expensive, and potentially undesirable, due sustainability implications. While adjusting existing treatment parameters may increase the re
Voulvoulis N, 2015, The potential of water reuse as a management option for water security under the ecosystem services approach, DESALINATION AND WATER TREATMENT, Vol: 53, Pages: 3263-3271, ISSN: 1944-3994
Jorquera CO, Oates CJ, Plant JA, et al., 2015, Regional hydrogeochemical mapping in Central Chile: natural and anthropogenic sources of elements and compounds, GEOCHEMISTRY-EXPLORATION ENVIRONMENT ANALYSIS, Vol: 15, Pages: 72-96, ISSN: 1467-7873
Voulvoulis N, Georges K, 2015, Industrial and agricultural sources and pathways of aquatic pollution, Impact of Water Pollution on Human Health and Environmental Sustainability, Pages: 29-54, ISBN: 9781466695597
© 2016 by IGI Global. All rights reserved. This chapter provides an introduction to the topic of aquatic pollution and looks at the major sources and pathways of pollutants to the environment from agriculture and industry. The section on agricultural pollution focuses on the use of fertilizers and pesticides. Industrial pollution covers a large topic and so three groups of pollutants are examined to provide an overview of the key issues faced within this sector.
Collins A, Voulvoulis N, 2014, Ecological assessments of surface water bodies at the river basin level: a case study from England, ENVIRONMENTAL MONITORING AND ASSESSMENT, Vol: 186, Pages: 8649-8665, ISSN: 0167-6369
Manap N, Voulvoulis N, 2014, Risk-based decision-making framework for the selection of sediment dredging option, SCIENCE OF THE TOTAL ENVIRONMENT, Vol: 496, Pages: 607-623, ISSN: 0048-9697
Al Aukidy M, Verlicchi P, Voulvoulis N, 2014, A framework for the assessment of the environmental risk posed by pharmaceuticals originating from hospital effluents, Science of the Total Environment, Vol: 493, Pages: 54-64, ISSN: 0048-9697
The consumption of pharmaceuticals is increasing in both hospitals and households. After administration, many compounds enter the water cycle as parent compounds or their metabolites via excretion. Conventional municipal wastewater treatment plants are unable to efficiently remove all the different compounds found in sewage and, consequently, treated effluents are one of the main sources of persistent micropollutants in the environment. Hospital patients are administered relatively high quantities of drugs and therefore hospital wastewaters can consistently contribute to treatment plant influent loads, with the magnitude of environmental risk posed by pharmaceuticals originating from hospital effluents largely unknown. This study has therefore developed a framework to enable authorities responsible for hospital management and environmental health to evaluate such risk, considering site-specific information such as the contribution of human population and hospital sizes, wastewater treatment removal efficiency, and potential dilution in the receiving water body. The framework was applied to three case studies, that are representative of frequent situations in many countries, and findings demonstrated that the degree of risk posed by any compound was site-specific and depended on a combination of several factors: compound concentration and toxicity, compound removal efficiency in the wastewater treatment plant and dilution factor. Ofloxacin, 17α-ethinylestradiol, erythromycin and sulfamethoxazole were identified as compounds of concern and might require management in order to reduce risk.
Navarro-Ortega A, Acuna V, Bellin A, et al., 2014, Managing the effects of multiple stressors on aquatic ecosystems under water scarcity. The GLOBAQUA project, Science of the Total Environment, Vol: 503-504, Pages: 3-9, ISSN: 0048-9697
Water scarcity is a serious environmental problem in many European regions, and will likely increase in the near future as a consequence of increased abstraction and climate change. Water scarcity exacerbates the effects of multiple stressors, and thus results in decreased water quality. It impacts river ecosystems, threatens the services they provide, and it will force managers and policy-makers to change their current practices. The EU-FP7 project GLOBAQUA aims at identifying the prevalence, interaction and linkages between stressors, and to assess their effects on the chemical and ecological status of freshwater ecosystems in order to improve water management practice and policies. GLOBAQUA assembles a multidisciplinary team of 21 European plus 2 non-European scientific institutions, as well as water authorities and river basin managers. The project includes experts in hydrology, chemistry, biology, geomorphology, modelling, socio-economics, governance science, knowledge brokerage, and policy advocacy. GLOBAQUA studies six river basins (Ebro, Adige, Sava, Evrotas, Anglian and Souss Massa) affected by water scarcity, and aims to answer the following questions: how does water scarcity interact with other existing stressors in the study river basins? How will these interactions change according to the different scenarios of future global change? Which will be the foreseeable consequences for river ecosystems? How will these in turn affect the services the ecosystems provide? How should management and policies be adapted to minimise the ecological, economic and societal consequences? These questions will be approached by combining data-mining, field- and laboratory-based research, and modelling. Here, we outline the general structure of the project and the activities to be conducted within the fourteen work-packages of GLOBAQUA.
Singh K, Oates C, Plant J, et al., 2014, Undisclosed chemicals - implications for risk assessment: A case study from the mining industry, Environment International, Vol: 68, Pages: 1-15, ISSN: 0160-4120
Many of the chemicals used in industry can be hazardous to human health and the environment, and some formu-lations can have undisclosed ingredients and hazards, increasing the uncertainty of the risks posed by their use. Theneed for a better understanding of the extent of undisclosedinformation in chemicals arose from collecting data onthe hazards and exposures of chemicals used in typical mining operations (copper, platinum and coal). Four maincategories of undisclosed chemicals were defined (incomplete disclosure; chemicals with unspecific identities; rel-ative quantities of ingredients not stated; and trade secret ingredients) by reviewing material safety data sheet(MSDS) omissions in previous studies. A significant number of chemicals (20% of 957 different chemicals) acrossthe three sites had a range of undisclosed information, with majority of the chemicals (39%) having unspecificiden-tities. The majority of undisclosed information was found in commercially available motor oils followed by cleaningproducts and mechanical maintenance products, as opposed to reagents critical to the main mining processes. Allthree types of chemicals had trade secrets, unspecific chemical identities and incomplete disclosures. These typesof undisclosed information pose a hindrance to a full understanding of the hazards, which is made worse whencombined with additional MSDS omissions such as acute toxicity endpoints (LD50) and/or acute aquatic toxicityendpoints (LC50), as well as inadequate hazard classifications of ingredients. The communication of the hazard in-formation in the MSDSs varied according to the chemical type, the manufacturer and the regulations governing theMSDSs. Undisclosed information can undermine occupational health protection, compromise the safety of workersin industry, hinder risk assessment procedures and cause uncertainty about future health. It comes down to theduty of care that industries have towards their employees. With a wide range of chemicals incr
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