Imperial College London
Alternate

Professor Paul D. Lickiss

Faculty of Natural Sciences, Department of Chemistry

Senior Research Investigator
 
 
 
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Contact

 

+44 (0)20 7594 5761p.lickiss Website

 
 
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Location

 

601DMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Davies:2019:10.1016/j.poly.2018.09.050,
author = {Davies, RP and Delmas, L and Horton, P and White, A and Coles, S and Lickiss, P},
doi = {10.1016/j.poly.2018.09.050},
journal = {Polyhedron},
pages = {25--32},
title = {Studies on the structural diversity of MOFs containing octahedral siloxane-backboned connectors},
url = {http://dx.doi.org/10.1016/j.poly.2018.09.050},
volume = {157},
year = {2019}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Four metal–organic frameworks containing hexatopic connectors have been prepared and structurally characterised: [Cd3(L)(DMA)2(H2O)2] (IMP-28), [Ce2(L)(DMF)2(H2O)2] (IMP-29), [Y2(L)(DMF)2(H2O)2] (IMP-30), and [Zn2(L-H2)(4,4′-bipy)2] (IMP-31). All the MOFs have been constructed using the hybrid inorganic–organic siloxane linker hexakis(4-carboxyphenyl)disiloxane (L-H6). In each case, discrete metal-based nodes are cross-linked by the octahedrally disposed connector to afford 3D polymeric structures. The underlying nets in these MOFs have been evaluated through deconstruction of their crystal structures and subsequent topological analysis. Examples of MOFs built from hexatopic linkers, and especially those with octahedral predispositions such as in L, remain scarce and the topologies ascribed to some of these MOFs are unique.
AU  - Davies,RP
AU  - Delmas,L
AU  - Horton,P
AU  - White,A
AU  - Coles,S
AU  - Lickiss,P
DO  - 10.1016/j.poly.2018.09.050
EP  - 32
PY  - 2019///
SN  - 0277-5387
SP  - 25
TI  - Studies on the structural diversity of MOFs containing octahedral siloxane-backboned connectors
T2  - Polyhedron
UR  - http://dx.doi.org/10.1016/j.poly.2018.09.050
UR  - http://hdl.handle.net/10044/1/64977
VL  - 157
ER  -
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