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BibTex format

@article{Pugh:2019:10.1021/acs.cgd.8b01567,
author = {Pugh, D and Ashworth, E and Robertson, K and Delmas, L and White, A and Horton, P and Tizzard, G and Coles, S and Lickiss, P and Davies, R},
doi = {10.1021/acs.cgd.8b01567},
journal = {Crystal Growth and Design},
pages = {487--497},
title = {Metal-organic frameworks constructed from group 1 metals (Li, Na) and silicon-centered linkers},
url = {http://dx.doi.org/10.1021/acs.cgd.8b01567},
volume = {19},
year = {2019}
}

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TY  - JOUR
AB  - A series of “light metal” metal–organic frameworks containing secondary building units (SBUs) based on Li+ and Na+ cations have been prepared using the silicon-centered linkers MexSi(p-C6H4CO2H)4-x (x = 2, 1, 0). The unipositive charge, small size, and oxophilic nature of the metal cations give rise to some unusual and unique SBUs, including a three-dimensional nodal structure built from sodium and oxygen ions when using the triacid linker (x = 1). The same linker with Li+ cations generated a chiral, helical SBU, formed from achiral starting materials. One-dimensional rod SBUs are observed for the diacid (x = 2) and tetra-acid (x = 0) linkers with both Li+ and Na+ cations, where the larger size of Na+ compared to Li+ leads to subtle differences in the constitution of the metal nodes.
AU  - Pugh,D
AU  - Ashworth,E
AU  - Robertson,K
AU  - Delmas,L
AU  - White,A
AU  - Horton,P
AU  - Tizzard,G
AU  - Coles,S
AU  - Lickiss,P
AU  - Davies,R
DO  - 10.1021/acs.cgd.8b01567
EP  - 497
PY  - 2019///
SN  - 1528-7483
SP  - 487
TI  - Metal-organic frameworks constructed from group 1 metals (Li, Na) and silicon-centered linkers
T2  - Crystal Growth and Design
UR  - http://dx.doi.org/10.1021/acs.cgd.8b01567
UR  - http://hdl.handle.net/10044/1/66658
VL  - 19
ER  -

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