Imperial College London
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ProfessorRogerWhatmore

Faculty of Engineering, Department of Materials

Visiting Professor
 
 
 
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Contact

 

r.whatmore

 
 
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Location

 

Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Crossley:2019:10.1103/physrevx.9.041002,
author = {Crossley, S and Nair, B and Whatmore, RW and Moya, X and Mathur, ND},
doi = {10.1103/physrevx.9.041002},
journal = {Physical Review X},
title = {Electrocaloric cooling cycles in lead scandium tantalate with true regeneration via field variation},
url = {http://dx.doi.org/10.1103/physrevx.9.041002},
volume = {9},
year = {2019}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - There is growing interest in heat pumps based on materials that show thermal changes when phase transitions are driven by changes of electric, magnetic, or stress field. Importantly, regeneration permits sinks and loads to be thermally separated by many times the changes of temperature that can arise in the materials themselves. However, performance and parameterization are compromised by net heat transfer between caloric working bodies and heat-transfer fluids. Here, we show that this net transfer can be avoided—resulting in true, balanced regeneration—if one varies the applied electric field while an electrocaloric (EC) working body dumps heat on traversing a passive fluid regenerator. Our EC working body is represented by bulk PbSc0.5Ta0.5O3 near its first-order ferroelectric phase transition, where we record directly measured adiabatic temperature changes of up to 2.2 K. Indirectly measured adiabatic temperature changes of similar magnitude are identified, unlike normal, from adiabatic measurements of polarization, at nearby measurement set temperatures, without assuming a constant heat capacity. The resulting high-resolution field-temperature-entropy maps of our material, and a small clamped companion sample, are used to construct cooling cycles that assume the use of an ideal passive regenerator in order to span ≤20  K. These cooling cycles possess well-defined coefficients of performance that are bounded by well-defined Carnot limits, resulting in large (>50%) well-defined efficiencies that are not unduly compromised by a small field hysteresis. Our approach permits the limiting performance of any caloric material in a passive regenerator to be established, optimized, and compared; provides a recipe for true regeneration in prototype cooling devices; and could be extended to balance active regeneration.
AU  - Crossley,S
AU  - Nair,B
AU  - Whatmore,RW
AU  - Moya,X
AU  - Mathur,ND
DO  - 10.1103/physrevx.9.041002
PY  - 2019///
SN  - 2160-3308
TI  - Electrocaloric cooling cycles in lead scandium tantalate with true regeneration via field variation
T2  - Physical Review X
UR  - http://dx.doi.org/10.1103/physrevx.9.041002
UR  - http://hdl.handle.net/10044/1/74412
VL  - 9
ER  -
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