TY - JOUR AB - Despite the ever-broadening applications of main-group ‘frustrated Lewis pair’ (FLP) chemistry to both new and established reactions, their typical intolerance of water, especially at elevated temperatures (>100 °C), represents a key barrier to their mainstream adoption. Herein we report that FLPs based on the Lewis acid iPr3SnOTf are moisture tolerant in the presence of moderately strong nitrogenous bases, even under high temperature regimes, allowing them to operate as simple and effective catalysts for the reductive amination of organic carbonyls, including for challenging bulky amine and carbonyl substrate partners. AU - Ashley,AE AU - Fuchter,MJ AU - Tighe,C AU - Allcock,N AU - Scott,D AU - Sapsford,J DO - 10.1002/adsc.201701418 EP - 1071 PY - 2018/// SN - 1615-4150 SP - 1066 TI - Direct reductive amination of carbonyl compounds catalyzed by a moisture tolerant Tin (IV) Lewis acid T2 - Advanced Synthesis and Catalysis UR - http://dx.doi.org/10.1002/adsc.201701418 UR - http://hdl.handle.net/10044/1/55349 VL - 360 ER -