TY - JOUR AB - Deconvolution of the role of off-cycle species from the desired catalytic cycle leads to an optimized protocol for the prolinate-catalyzed amination of aldehydes. The scope of complex reaction networks will be greatly broadened by understanding ancillary rate processes that influence the productive catalytic pathway. AU - Hein,JE AU - Armstrong,A AU - Blackmond,DG DO - 10.1021/ol201639z EP - 4303 PY - 2011/// SP - 4300 TI - Kinetic profiling of prolinate-catalyzed α-amination of aldehydes. T2 - Org Lett UR - http://dx.doi.org/10.1021/ol201639z UR - https://www.ncbi.nlm.nih.gov/pubmed/21761822 VL - 13 ER -