Citation

BibTex format

@article{Murray:2017:10.1002/anie.201700977,
author = {Murray, JI and Floden, NJ and Bauer, A and Fessner, ND and Dunklemann, DL and Bob-Egbe, O and Rzepa, HS and Burgi, T and Richardson, J and Spivey, AC},
doi = {10.1002/anie.201700977},
journal = {Angewandte Chemie International Edition},
pages = {5760--5764},
title = {Kinetic resolution of 2-substituted indolines by N-sulfonylation using an atropisomeric 4-DMAP-N-oxide organocatalyst},
url = {http://dx.doi.org/10.1002/anie.201700977},
volume = {56},
year = {2017}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - The first catalytic kinetic resolution by N-sulfonylation is described. 2-Substituted indolines are resolved (s=2.6–19) using an atropisomeric 4-dimethylaminopyridine-N-oxide (4-DMAP-N-oxide) organocatalyst. Use of 2-isopropyl-4-nitrophenylsulfonyl chloride is critical to the stereodiscrimination and enables facile deprotection of the sulfonamide products with thioglycolic acid. A qualitative model that accounts for the stereodiscrimination is proposed.
AU - Murray,JI
AU - Floden,NJ
AU - Bauer,A
AU - Fessner,ND
AU - Dunklemann,DL
AU - Bob-Egbe,O
AU - Rzepa,HS
AU - Burgi,T
AU - Richardson,J
AU - Spivey,AC
DO - 10.1002/anie.201700977
EP - 5764
PY - 2017///
SN - 1433-7851
SP - 5760
TI - Kinetic resolution of 2-substituted indolines by N-sulfonylation using an atropisomeric 4-DMAP-N-oxide organocatalyst
T2 - Angewandte Chemie International Edition
UR - http://dx.doi.org/10.1002/anie.201700977
UR - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000400755800017&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR - http://hdl.handle.net/10044/1/49050
VL - 56
ER -