Citation

BibTex format

@article{Murray:2017:10.1002/ange.201700977,
author = {Murray, JI and Flodén, NJ and Bauer, A and Fessner, ND and Dunklemann, DL and Bob-Egbe, O and Rzepa, HS and Bürgi, T and Richardson, J and Spivey, AC},
doi = {10.1002/ange.201700977},
journal = {Angewandte Chemie},
pages = {5854--5858},
title = {Kinetic Resolution of 2-Substituted Indolines by N -Sulfonylation using an Atropisomeric 4-DMAP- N -oxide Organocatalyst},
url = {http://dx.doi.org/10.1002/ange.201700977},
volume = {129},
year = {2017}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - The first catalytic kinetic resolution by Nsulfonylation is described. 2Substituted indolines are resolved (s=2.6–19) using an atropisomeric 4dimethylaminopyridineNoxide (4DMAPNoxide) organocatalyst. Use of 2isopropyl4nitrophenylsulfonyl chloride is critical to the stereodiscrimination and enables facile deprotection of the sulfonamide products with thioglycolic acid. A qualitative model that accounts for the stereodiscrimination is proposed.
AU - Murray,JI
AU - Flodén,NJ
AU - Bauer,A
AU - Fessner,ND
AU - Dunklemann,DL
AU - Bob-Egbe,O
AU - Rzepa,HS
AU - Bürgi,T
AU - Richardson,J
AU - Spivey,AC
DO - 10.1002/ange.201700977
EP - 5858
PY - 2017///
SN - 0044-8249
SP - 5854
TI - Kinetic Resolution of 2-Substituted Indolines by N -Sulfonylation using an Atropisomeric 4-DMAP- N -oxide Organocatalyst
T2 - Angewandte Chemie
UR - http://dx.doi.org/10.1002/ange.201700977
UR - http://hdl.handle.net/10044/1/64867
VL - 129
ER -