Publications

Journal article

Hu S, Cao X, Reddyhoff T, Puhan D, Huang W, Shi X, Peng Z, Dini Det al., 2019,

Three-dimensional printed surfaces inspired by bi-Gaussian stratified plateaus

, ACS Applied Materials and Interfaces, Vol: 11, Pages: 20528-20534, ISSN: 1944-8244

Wettability of artificial surfaces is attracting increasing attention for its relevant technological applications. Functional performance is often achieved by mimicking the topographical structures found in natural flora and fauna; however, surface attributes inspired by geological landscapes have so far escaped attention. We reproduced a stratified morphology of plateaus with a bi-Gaussian height distribution using a three-dimensional direct laser lithography. The plateau-inspired artificial surface exhibits a hydrophobic behavior even if fabricated from a hydrophilic material, giving rise to a new wetting mechanism that divides the well-known macroscopic Wenzel and Cassie states into four substates. We have also successfully applied the plateau-inspired structure to droplet manipulation.

Journal article

Ebrahimi M, Balint D, Sutton A, Dini Det al., 2019,

A discrete crack dynamics model of toughening in brittle polycrystalline material by crack deflection

, Engineering Fracture Mechanics, Vol: 214, Pages: 95-111, ISSN: 0013-7944

This paper focuses on the study of the effect of the interfacial strength of grain boundaries and elliptical inclusions on crack path deflection. The method is developed to channel a crack into a toughening configuration (arrays of elliptical holes and inclusions are considered) in order to obtain the optimised microstructure required to enhance fracture toughness through different mechanisms. The proposed technique is shown to reproduce experimental crack propagation paths in various configurations and is capable of capturing the effect of that variation of the GB and the inclusion interfacial strength; it provides a powerful tool to understand the interplay between microstructural features and improve materials performance.

Journal article

Rosenkranz A, Costa HL, Profito F, Gachot C, Medina S, Dini Det al., 2019,

Influence of surface texturing on hydrodynamic friction in plane converging bearings - An experimental and numerical approach

, Tribology International, Vol: 134, Pages: 190-204, ISSN: 0301-679X

The frictional behaviour of plane converging bearings was experimentally and numerically studied for four texture geometries fabricated by ultra-short pulse laser texturing (single pocket, line-, cross- and dot-like texture) and convergence ratios under full-film lubrication in the presence of thick oil films (up to 100 μm). Regarding the experiments, small variations in the spread of results between different textures and a general improvement over the untextured reference can be observed. Numerical simulations help to clarify the expected variations and conditions under which these occur. For high convergences, the simulations demonstrated that textures are beneficial for friction reduction, regardless of load and relative texture's position. For low convergences, a significant friction reduction occurs for textures being located at the bearing's inlet.

Journal article

Dawczyk J, Morgan N, Russo J, Spikes Het al., 2019,

Film thickness and friction of ZDDP tribofilms

, Tribology Letters, Vol: 67, ISSN: 1023-8883

Tribofilm formation by several zinc dialkyl- and diaryldithiophosphate (ZDDP) solutions in thin film rolling-sliding conditions has been investigated. A primary, a secondary alkyl and a mixed alkyl ZDDP show similar rates of film formation and generate films typically 150 nm thick. Another secondary ZDDP forms a tribofilm much faster and the film is partially lost after extended rubbing. An aryl ZDDP forms a tribofilm much more slowly. The films all have a pad-like structure, characterised by flat pad regions separated by deep valleys. Three different techniques have been used to analyse the thickness and morphology of the tribofilms: spacer layer imaging (SLIM), scanning white light interferometry (SWLI) of the gold-coated film and contact mode atomic force microscopy (AFM). The SLIM method measures considerably thicker films than the other two techniques, probably because of lack of full conformity of a glass disc loaded against the rough tribofilm. No evidence of a highly viscous layer on top of the solid tribofilm is seen. SWLI and contact mode AFM measure similar film thicknesses. The importance of coating the tribofilm with a reflective layer prior to using SWLI is confirmed. As noted in previous work, the formation of a ZDDP tribofilm is accompanied by a marked shift in the Stribeck friction curve towards higher entrainment speed. For a given ZDDP this shift is found to correlate with the measured tribofilm roughness, proving that it results from the influence of this roughness on fluid entrainment in the inlet.

Journal article

Geng Z, Puhan D, Reddyhoff T, 2019,

Using acoustic emission to characterize friction and wear in dry sliding steel contacts

, Tribology International, Vol: 134, Pages: 394-407, ISSN: 0301-679X

© 2019 Acoustic emission (AE) was recorded during tribological tests on 52,100 steel specimens under different loads. AE signals were transformed to the frequency domain using a Fast Fourier Transform and parameters such as power, RMS amplitude, mean frequency, and energy were analyzed and compared with friction coefficient and wear volume measurements. Results show that certain acoustic frequencies reflect friction while others reflect wear. If frequencies are chosen optimally, AE and friction signals are highly correlated (Pearson coefficients >0.8). SEM and Raman analysis reveal how plastic deformation and oxide formation affect friction, wear and AE simultaneously. AE recordings contains more information than conventional friction and wear volume measurements and are more sensitive to changes in mechanism. This all demonstrates AE's potential as a tool to monitor tribological behavior.

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Journal article

Sufian A, Knight C, O'Sullivan C, Van Wachem B, Dini Det al., 2019,

Ability of a pore network model to predict fluid flow and drag in saturated granular materials

, Computers and Geotechnics, Vol: 110, Pages: 344-366, ISSN: 0266-352X

The local flow field and seepage induced drag obtained from Pore Network Models (PNM) is compared to Immersed Boundary Method (IBM) simulations, for a range of linear graded and bimodal samples. PNM were generated using a weighted Delaunay Tessellation (DT), along with the Modified Delaunay Tessellation (MDT) which considers the merging of tetrahedral Delaunay cells. Two local conductivity models are compared in simulating fluid flow in the PNM. The local pressure field was very accurately captured, while the local flux (flow rate) exhibited more scatter and sensitivity to the choice of the local conductance model. PNM based on the MDT clearly provided a better correlation with the IBM. There was close similarity in the network shortest paths, indicating that the PNM captures dominant flow channels. Comparison of streamline profiles demonstrated that local pressure drops coincided with the pore constrictions. A rigorous validation was undertaken for the drag force calculated from the PNM by comparing with analytical solutions for ordered array of spheres. This method was subsequently applied to all samples, and the calculated force was compared with the IBM data. Linear graded samples were able to calculate the force with reasonable accuracy, while the bimodal samples exhibited slightly more scatter.

Journal article

Rycerz P, Kadiric A, 2019,

The influence of slide–roll ratio on the extent of micropitting damage in rolling–sliding contacts pertinent to gear applications

, Tribology Letters, Vol: 67, Pages: 1-20, ISSN: 1023-8883

Micropitting is a type of surface damage that occurs in rolling–sliding contacts operating under thin oil film, mixed lubrication conditions, such as those formed between meshing gear teeth. Like the more widely studied pitting damage, micropitting is caused by the general mechanism of rolling contact fatigue but, in contrast to pitting, it manifests itself through the formation of micropits on the local, roughness asperity level. Despite the fact that micropitting is increasingly becoming a major mode of gear failure, the relevant mechanisms are poorly understood and there are currently no established design criteria to assess the risk of micropitting occurrence in gears or other applications. This paper provides new understanding of the tribological mechanisms that drive the occurrence of micropitting damage and serves to inform the ongoing discussions on suitable design criteria in relation to the influence of contact slide–roll ratio (SRR) on micropitting. A triple-disc rolling contact fatigue rig is used to experimentally study the influence of the magnitude and direction of SRR on the progression of micropitting damage in samples made of case-carburised gear steel. The test conditions are closely controlled to isolate the influence of the variable of interest. In particular, any variation in bulk heating at different SRRs is eliminated so that tests are conducted at the same film thickness for all SRRs. The results show that increasing the magnitude of SRR increases the level of micropitting damage and that negative SRRs (i.e. the component where damage is being accumulated is slower) produce more micropitting than the equivalent positive SRRs. Measurements of elastohydrodynamic film thickness show that in the absence of bulk heating, increasing SRR does not cause a reduction in EHL film thickness and therefore this cannot be the reason for the increased micropitting at higher SRRs. Instead, we show that the main mechanism by which increase in SRR

Journal article

Vladescu S-C, Fowell M, Mattsson L, Reddyhoff Tet al., 2019,

The effects of laser surface texture applied to internal combustion engine journal bearing shells - An experimental study

, TRIBOLOGY INTERNATIONAL, Vol: 134, Pages: 317-327, ISSN: 0301-679X

Journal article

Peng B, Spikes H, Kadiric A, 2019,

The development and application of a scuffing test based on contra-rotation

, Tribology Letters, Vol: 67, ISSN: 1023-8883

Scuffing is a surface failure mode that occurs in sliding–rolling contacts subjected to high loads and high sliding speeds, such as those in gears and cam-followers. Owing to its sudden onset, rapid progression and dependence on both fluid and boundary lubricant films, scuffing is difficult to study in a repeatable manner. This paper describes further development of a recently proposed scuffing test method based on contra-rotation, its extension to higher loads using a new experimental set-up and its application to study the onset of scuffing with a selection of model and fully-formulated oils. The method employs two surfaces moving in opposite directions under rolling–sliding conditions, with a fixed load and step-wise increasing sliding speed. By decoupling the entrainment and sliding speeds, the method allows the effects of lubricant formulation on scuffing performance to be isolated from the influence of viscosity. The approach achieves high sliding speeds in parallel with low entrainment speeds, while minimising the undesirable effects of surface wear and frictional heating. The proposed test is relatively fast and economical, with total test time of about 30 min including specimen cleaning and set-up. Results show that the newly implemented modifications have improved the repeatability of the test method, so that the number of repeat tests required for reliable oil ranking results is minimal. Tests with model and fully-formulated oils show that the onset of scuffing is characterised by a sharp and unrecoverable increase in friction and accompanied by the destruction of any boundary films. All tests show that the relationship load × speedn = constant holds at scuffing, with the exact value of the exponent n being dependent on the oil formulation. Additivised oils were shown to have enhanced scuffing resistance, which arises from their ability to postpone the uncontrollable rise in friction to higher sliding speeds. Finally, the critical maximu

Journal article

Restrepo SE, van Eijk MCP, Ewen JP, 2019,

Behaviour of n-alkanes confined between iron oxide surfaces at high pressure and shear rate: A nonequilibrium molecular dynamics study

, Tribology International, Vol: 137, Pages: 420-432, ISSN: 0301-679X

The behaviour of n-alkanes confined and sheared between iron oxide surfaces has been studied using nonequilibrium molecular dynamics simulations. The molecular extension, orientation, film structure, flow, and friction have been investigated for a range of n-alkane chain lengths under conditions representative of the elastohydrodynamic lubrication regime. At high pressure, the molecules show strong layering and long-range order, suggesting solid-like films. Conversely, high shear rates result in less elongated, layered, and ordered molecules; indicating more liquid-like films. Although Couette flow is usually observed for short n-alkanes, the flow is often non-linear for long n-alkanes. The friction coefficient increases logarithmically with shear rate, but the slope decreases with increasing pressure such that it becomes insensitive to shear rate for long n-alkanes.

Journal article

Heyes D, Smith ER, Dini D, 2019,

Shear stress relaxation and diffusion in simple liquids by molecular dynamics simulations: Analytic expressions and paths to viscosity

, The Journal of Chemical Physics, Vol: 150, ISSN: 0021-9606

The results are reported of an equilibrium molecular dynamics simulation study of the shear viscosity, η, and self-diffusion coefficient, D, of the Lennard-Jones liquid using the Green-Kubo (GK) method. Semiempirical analytic expressions for both GK time correlation functions were fitted to the simulation data and used to derive analytic expressions for the time dependent diffusion coefficient and shear viscosity, and also the correlation function frequency transforms. In the case of the shear viscosity for a state point near the triple point, a sech function was found to fit the correlation function significantly better than a gaussian in the ballistic short time regime. A reformulation of the shear GK formula in terms of a time series of time integrals (“viscuits”) and contributions to the viscosity from components based on the initial stress (“visclets”) enable the GK expressions to be recast in terms of probability distributions which could be used in coarse grained stochastic models of nanoscale flow. The visclet treatment shows that stress relaxation is statistically independent of the initial stress for equilibrium and metastable liquids, suggesting that shear stress relaxation in liquids is diffusion controlled. By contrast, the velocity autocorrelation function is sensitive to the initial velocity. Weak oscillations and a plateau at intermediate times originate to a greater extent from the high velocity tail of the Maxwell-Boltzmann velocity distribution. Simple approximate analytic expressions for the mean square displacement and the self Van Hove correlation function are also derived.

Journal article

Wu P-J, Masouleh MI, Paterson C, Dini D, Török P, Overby DR, Kabakova IVet al., 2019,

Detection of proteoglycan loss from articular cartilage using Brillouin microscopy, with applications to osteoarthritis

, Biomedical Optics Express, Vol: 10, Pages: 2457-2466, ISSN: 2156-7085

The degeneration of articular cartilage (AC) occurs in osteoarthritis (OA), which is a leading cause of pain and disability in middle-aged and older people. The early disease-related changes in cartilage extra-cellular matrix (ECM) start with depletion of proteoglycan (PG), leading to an increase in tissue hydration and permeability. These early compositional changes are small (<10%) and hence difficult to register with conventional non-invasive imaging technologies (magnetic resonance and ultrasound imaging). Here we apply Brillouin microscopy for detecting changes in the mechanical properties and composition of porcine AC. OA-like degradation is mimicked by enzymatic tissue digestion, and we compare Brillouin microscopy measurements against histological staining of PG depletion over varying digestion times and enzyme concentrations. The non-destructive nature of Brillouin imaging technology opens new avenues for creating minimally invasive arthroscopic devices for OA diagnostics and therapeutic monitoring.

Journal article

Geng Z, Shi G, Shao T, Liu Y, Duan D, Reddyhoff Tet al., 2019,

Tribological behavior of patterned TiAlN coatings at elevated temperatures

, SURFACE & COATINGS TECHNOLOGY, Vol: 364, Pages: 99-114, ISSN: 0257-8972

Journal article

Hu S, Vladescu S-C, Puhan D, Huang W, Shi X, Peng Zet al., 2019,

Bi-Gaussian stratified theory to understand wettability on rough topographies

, Surface and Coatings Technology, ISSN: 0257-8972

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Journal article

Hu S, Reddyhoff T, Puhan D, Vladescu S-C, Huang W, Shi X, Dini D, Peng Zet al., 2019,

Bi-Gaussian stratified wetting model on rough surfaces

, Langmuir, Vol: 35, Pages: 5967-5974, ISSN: 0743-7463

Wetting mechanisms on rough surfaces were understood from either a monolayer or a multiscale perspective. However, it has recently been shown that the bi-Gaussian stratified nature of real surfaces should be accounted for when modeling mechanisms of lubrication, sealing, contact, friction, acoustic emission, and manufacture. In this work, a model combining Wenzel and Cassie theories was put forward to predict the static contact angle of a droplet on a bi-Gaussian stratified surface. The model was initially applied to numerically simulated surfaces and subsequently demonstrated on hydrophilic steel and hydrophobic self-assembled monolayer specimens with preset bi-Gaussian stratified topographies. In the Wenzel state, both the upper and the lower surface components are fully wetted. In the Cassie state, the upper component is still completely wetted, while the lower component serves as gas traps and reservoirs. By this model, wetting evolution was assessed, and the existence of different wetting states and potential state transitions was predicted.

Journal article

Ewen J, Gao H, Mueser M, Dini Det al., 2019,

Shear heating, flow, and friction of confined molecular fluids at high pressure

, Physical Chemistry Chemical Physics, Vol: 21, Pages: 5813-5823, ISSN: 1463-9076

Understanding the molecular-scale behavior of fluids confined and sheared between solid surfaces is important for many applications, particularly tribology where this often governs the macroscopic frictional response. In this study, nonequilibrium molecular dynamics simulations are performed to investigate the effects of fluid and surface properties on the spatially resolved temperature and flow profiles, as well as friction. The severe pressure and shear rate conditions studied are representative of the elastohydrodynamic lubrication regime. In agreement with tribology experiments, flexible lubricant molecules give low friction, which increases linearly with logarithmic shear rate, while bulky traction fluids show higher friction, but a weaker shear rate dependence. Compared to lubricants, traction fluids show more significant shear heating and stronger shear localization. Models developed for macroscopic systems can be used to describe both the spatially resolved temperature profile shape and the mean film temperature rise. The thermal conductivity of the fluids increases with pressure and is significantly higher for lubricants compared to traction fluids, in agreement with experimental results. In a subset of simulations, the efficiency of the thermostat in one of the surfaces is reduced to represent surfaces with lower thermal conductivity. For these unsymmetrical systems, the flow and the temperature profiles become strongly asymmetric and some thermal slip can occur at the solid-fluid interface, despite the absence of velocity slip. The larger temperature rises and steeper velocity gradients in these cases lead to large reductions in friction, particularly at high pressure and shear rate.

Journal article

Fatti G, Righi MC, Dini D, Ciniero Aet al., 2019,

First-principles insights into the structural and electronic properties of polytetrafluoroethylene in its high-pressure phase (form III)

, Journal of Physical Chemistry C, Vol: 123, Pages: 6250-6255, ISSN: 1932-7447

Polytetrafluoroethylene (PTFE), commercially known as Teflon, is one the most effective insulating polymers for a wide range of applications because of its peculiar electronic, mechanical, and thermal properties. Several studies have attempted to elucidate the structural and electronic properties of PTFE; however, some important aspects of its structural and electronic characteristics are still under debate. To shed light on these fundamental features, we have employed a first-principles approach to optimize the two coexisting PTFE structures (monoclinic and orthorhombic) at high pressure by using the characteristic zigzag planar chain configuration. Our electronic analysis of the optimized structures shows charge transfer from carbons to fluorines, supporting the PTFE electronegative character. In addition, band structure calculations show that the band gap is estimated to be around 5 eV, which correlates with previous studies. Moreover, the analysis of the valence and conduction states reveals an intrachain and an interchain character of the charge distribution, suggesting additional insights into the PTFE electronic properties.

Journal article

Stevenson H, Jaggard M, Akhbari P, Vaghela U, Gupte C, Cann Pet al., 2019,

The role of denatured synovial fluid proteins in the lubrication of artificial joints

, Biotribology, Vol: 17, Pages: 49-63, ISSN: 2352-5738

CoCrMo ball-on-flat wear tests were carried out with 25 wt% bovine calf serum (25BCS) and human synovial fluid (HSF) to investigate artificial joint lubricating mechanisms. Post-test the wear scar on the disc was measured and surface deposits in and around the rubbed region were analysed by Micro InfraRed Reflection Absorption Spectroscopy (Micro-IRRAS). In most tests the HSF samples gave higher wear than the 25BCS solution; in some cases, up to 77%. After rinsing a similar pattern of surface deposits was observed in and around the wear scar for both the model and HSF. Micro-IRRAS showed the deposits were primarily denatured proteins with an increased β-sheet content. In some cases, trans-alkyl chain/carbonyl components were also present and these were assigned to lipids. Thioflavin T fluorescent imaging also indicated aggregated non-native β-sheet fibrils were present in the deposits and their presence was associated with lower wear. The formation of insoluble, denatured protein films is thought to be the primary lubrication mechanism contributing to surface protection during rubbing. From this and earlier work we suggest inlet shear induces denaturing of proteins resulting in the formation of non-native β-sheet aggregates. This material is entrained into the contact region where it forms the lubricating film. Patient synovial fluid chemistry appears to influence wear, at least in the bench test, and thus could contributes to increased risk of failure, or success, with metal-metal hips. Finally using 25BCS as a reference screening fluid gives an overly optimistic view of wear in these systems.

Journal article

Limbert G, Masen MA, Pond D, Graham HK, Sherratt MJ, Jobanputra R, McBride Aet al., 2019,

Biotribology of the ageing skin—Why we should care

, Biotribology, Vol: 17, Pages: 75-90, ISSN: 2352-5738

Ageing of populations has emerged as one of the most pressing societal, economic and healthcare challenges currently facing most nations across the globe. The ageing process itself results in degradation of physiological functions and biophysical properties of organs and tissues, and more particularly those of the skin. Moreover, in both developed and emerging economies, population ageing parallels concerning increases in lifestyle-associated conditions such as Type 2 diabetes, obesity and skin cancers. When considered together, these demographic trends call for even greater urgency to find clinical and engineering solutions for the numerous age-related deficits in skin function.From a tribological perspective, detrimental alterations of skin biophysical properties with age have fundamental consequences on how one interacts with the body's inner and outer environments. This stems from the fact that, besides being the largest organ of the human body, and also nearly covering its entirety, the skin is a multifunctional interface which mediates these interactions.The aim of this paper is to present a focused review to discuss some of the consequences of skin ageing from the viewpoint of biotribology, and their implications on health, well-being and human activities. Current and future research questions/challenges associated with biotribology of the ageing skin are outlined. They provide the background and motivation for identifying future lines of research that could be taken up by the biotribology and biophysics communities.

Journal article

Yu M, Arana C, Evangelou S, Dini Det al., 2019,

Quarter-car experimental study for series active variable geometry suspension

, IEEE Transactions on Control Systems Technology, Vol: 27, Pages: 743-759, ISSN: 1063-6536

In this paper, the recently introduced series active variable geometry suspension (SAVGS) for road vehicles is experimentally studied. A realistic quarter-car test rig equipped with double-wishbone suspension is designed and built to mimic an actual grand tourer real axle, with a single-link variant of the SAVGS and a road excitation mechanism implemented. A linear equivalent modeling method is adopted to synthesize an H-infinity control scheme for the SAVGS, with the geometric nonlinearity compensated. Simulations with a theoretical nonlinear quarter-car indicate the SAVGS potential to enhance suspension performance, in terms of ride comfort and road holding. Practical features in the test rig are further considered and included in the nonlinear model to compensate the difference between the theoretical and testing behaviors. Experiments with a sinusoidal road, a smoothed bump and hole, and a random road are performed to evaluate the SAVGS practical feasibility and performance improvement, the accuracy of the model, and the robustness of the control schemes. Compared with the conventional passive suspension, ride comfort improvements of up to 41% without any deterioration of the suspension deflection are demonstrated, while the SAVGS actuator power is kept very low, at levels below 500 W.

Journal article

Vladescu S-C, Putignano C, Marx N, Keppens T, Reddyhoff T, Dini Det al., 2019,

The percolation of liquid through a compliant seal - an experimental and theoretical study

, Journal of Fluids Engineering, Vol: 141, Pages: 031101-031101, ISSN: 0098-2202

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Journal article

Manieri F, Stadler K, Morales-Espejel GE, Kadiric Aet al., 2019,

The origins of white etching cracks and their significance to rolling bearing failures

, International Journal of Fatigue, Vol: 120, Pages: 107-133, ISSN: 0142-1123

Presence of white etching cracks has been widely associated with early failures of rolling bearings in a number of applications, with wind turbine gearbox bearings being the most frequently cited and practically significant example. Despite the recent research efforts, there is yet no universal agreement on the mechanisms of formation of these cracks and little direct evidence of their significance to bearing reliability. In an attempt to address this, this paper proposes a new theory on the origins and significance of white etching cracks. The paper provides systematic experimental evidence in support of this theory through rolling contact fatigue tests performed with AISI 52100 bearing steel specimens on a triple-disc machine over a wide range of contact conditions. The test results show that white etching cracks can be formed with base oils as well as commercially formulated transmission and engine oils. WECs were generated under slide-roll-ratios ranging from 0.05 to 0.3, under positive and negative sliding, different contact pressures and specific film thicknesses ranging from 0.1 to 0.7. No white etching areas were ever observed without the associate crack being present, and it was also shown that white etching areas themselves can be produced in a pure rubbing contact of bearing steels under both lubricated and unlubricated conditions. These results provide direct evidence that the steel transformations that exhibit themselves as white etching areas are formed through rubbing of the existing crack faces, and that the chemical composition of the lubricant and the magnitude and direction of sliding are not the primary driver of WEC formation, in contrast to literature. Instead, the results presented here show that WECs are formed through the action of a specific stress history in time via the following mechanism: (i) Short-lived high contact stresses, which can be caused by a number of factors, act in the initial stages of the component life to initiate early f

Journal article

Reddyhoff T, Schmidt A, Spikes H, 2019,

Thermal conductivity and flash temperature

, Tribology Letters, Vol: 67, Pages: 22-22, ISSN: 1023-8883

The thermal conductivity is a key property in determining the friction-induced temperature rise on the surface of sliding components. In this study, a Frequency Domain Thermoreflectance (FDTR) method is used to measure the thermal conductivity of a range of tribological materials (AISI 52100 bearing steel, silicon nitride, sapphire, tungsten carbide and zirconia). The FDTR technique is validated by comparing measurements of pure germanium and silicon with well-known values, showing discrepancies of less than 3%. For most of the tribological materials studied, the thermal conductivity values measured are reasonably consistent with values found in the literature. However the measured thermal conductivity of AISI 52100 steel (21 W/mK) is less than half the value cited in the literature (46 W/mK). Further bulk thermal conductivity measurements show that this discrepancy arises from a reduction in thermal conductivity of AISI 52100 due to through-hardening. The thermal conductivity value generally cited and used in the literature represents that of soft, annealed alloy, but through-hardened AISI 52100, which is generally employed in rolling bearings and for lubricant testing, appears to have a much lower thermal conductivity. This difference has a large effect on estimates of flash temperature and example calculations show that it increases the resulting surface temperatures by 30 to 50%. The revised value of thermal conductivity of bearing steel also has implications concerning heat transfer in transmissions.

Journal article

Hu S, Reddyhoff T, Wen J, Huang W, Shi X, Dini D, Peng Zet al., 2019,

Characterization and simulation of bi-Gaussian surfaces induced by material transfer and additive processes

, Tribology International, ISSN: 0301-679X

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Journal article

Porte E, Cann P, Masen M, 2019,

Fluid load support does not explain tribological performance of PVA hydrogels

, Journal of the Mechanical Behavior of Biomedical Materials, Vol: 90, Pages: 284-294, ISSN: 1751-6161

The application of hydrogels as articular cartilage (AC) repair or replacement materials is limited by poor tribological behaviour, as it does not match that of native AC. In cartilage, the pressurisation of the interstitial fluid is thought to be crucial for the low friction as the load is shared between the solid and liquid phase of the material. This fluid load support theory is also often applied to hydrogels. However, this theory has not been validated as no experimental evidence directly relates the pressurisation of the interstitial fluid to the frictional response of hydrogels. This lack of understanding about the governing tribological mechanisms in hydrogels limits their optimised design. Therefore, this paper aims to provide a direct measure for fluid load support in hydrogels under physiologically relevant sliding conditions. A photoelastic method was developed to simultaneously measure the load on the solid phase of the hydrogel and its friction coefficient and thus directly relate friction and fluid load support. The results showed a clear distinction in frictional behaviour between the different test conditions, but results from photoelastic images and stress-relaxation experiments indicated that fluid load support is an unlikely explanation for the frictional response of the hydrogels. A more appropriate explanation, we hypothesized, is a non-replenished lubricant mechanism. This work has important implications for the tribology of cartilage and hydrogels as it shows that the existing theories do not adequately describe the tribological behaviour of hydrogels. The developed insights can be used to optimise the tribological performance of hydrogels as articular cartilage implants.

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Citations: 18

Journal article

Puhan D, Nevshupa R, Wong J, Reddyhoff Tet al., 2019,

Transient aspects of plasma luminescence induced by triboelectrification of polymers

, Tribology International, Vol: 130, Pages: 366-377, ISSN: 0301-679X

Transient electric gas discharges that occur around sliding interfaces during contact electrification of polymers were studied at millisecond timescales and with micrometre resolution. Deduced vibrational temperatures indicate cold plasma resulting from positive corona discharge. At millisecond timescales, previously unseen rapid discharge events are observed, and modelling suggests that these result from streamer development, triggered by electron emission from the polymer surface. Those which occur over a period of several seconds are shown to be caused by competition between charge generation and the formation of polymer films. The findings explain the interplay between charging and plasma generation and their dependence on wear processes.

Journal article

Dzepina B, Balint D, Dini D, 2019,

A phase field model of pressure-assisted sintering

, Journal of the European Ceramic Society, Vol: 39, Pages: 173-182, ISSN: 0955-2219

The incorporation of an efficient contact mechanics algorithm into a phase field sintering model is presented. Contact stresses on the surface of arbitrarily shaped interacting bodies are evaluated and built into the model as an elastic strain energy field. Energy relaxation through deformation is achieved by diffusive fluxes along stress gradients and rigid body motion of the deforming particles maintain contact between the particles. The proposed model is suitable for diffusion deformation mechanisms occurring at stresses below the yield strength of a defect-free material; this includes Nabarro-Herring creep, Coble creep and pressure-solution. The effect of applied pressure on the high pressure-high temperature (HPHT) liquid phase sintering of diamond particles was investigated. Changes in neck size, particle coordination and contact flattening were observed. Densification rates due to the externally applied loads were found to be in good agreement with a new theory which implicitly incorporates the effect of applied external pressure.

Journal article

Jeffreys S, di Mare L, Liu X, Morgan N, Wong Jet al., 2019,

Elastohydrodynamic lubricant flow with nanoparticle tracking

, RSC Advances, Vol: 9, Pages: 1441-1450, ISSN: 2046-2069

Lubricants operating in elastohydrodynamic (EHD) contacts exhibit local variations in rheological properties when the contact pressure rises. Direct evidence of this behaviour has only been obtained by examining through-thickness velocity profiles U(z) of lubricants in a contact using luminescence-based imaging velocimetry. In the present study, nanoparticles (NPs) are added to polybutene (PB) as tracers to investigate the effect of pressure on the flow of PB in an EHD contact. By tracking NPs in the contact, particle velocity distributions f(U) under various pressures are obtained and found to be pressure dependent. Results show quantitatively that f(U) and U(z) are correlated and thus confirm that U(z) of PB changes from Couette flow to partial plug flow above a critical pressure. This confirmation highlights the complexity of lubricant rheology in a high pressure contact.

Journal article

Ma S, Scaraggi M, Yan C, Wang X, Gorb S, Dini D, Zhou Fet al., 2019,

Bio-inspired 3D printed locomotion devices based on anisotropic friction

, Small, Vol: 15, Pages: 1802931-1802931, ISSN: 1613-6810

Anisotropic friction plays a key role in natural systems, particularly for realizing the purpose of locomotion and strong attachment for the survival of organisms. Of particular interest, here, is the observation that friction anisotropy is promoted numerous times by nature, for example, by wild wheat awn for its targeted and successful seed anchorage and dispersal. Such feature is, however, not fully exploited in man‐made systems, such as microbots, due to technical limitations and lack of full understanding of the mechanisms. To unravel the complex dynamics occurring in the sliding interaction between anisotropic microstructured surfaces, the friction induced by asymmetric plant microstructures is first systematically investigated. Inspired by this, anisotropic polymer microactuators with three‐dimensional (3D) printed microrelieves are then prepared. By varying geometric parameters, the capability of microactuators to generate strong friction anisotropy and controllable motion in remotely stretched cylindrical tubes is investigated. Advanced theoretical models are proposed to understand and predict the dynamic behavior of these synthetic systems and to shed light on the parameters and mechanisms governing their behavior. Finally, a microbot prototype is developed and cargo transportation functions are successfully realized. This research provides both in‐depth understanding of anisotropic friction in nature and new avenues for developing intelligent actuators and microbots.

Journal article

Jean-Fulcrand A, Masen MA, Bremner T, Wong JSSet al., 2019,

Effect of temperature on tribological performance of polyetheretherketone-polybenzimidazole blend

, Tribology International, Vol: 129, Pages: 5-15, ISSN: 0301-679X

Polyetheretherketone (PEEK) is one of the most commonly used High Performance Polymers (HPP) although its high temperature performance is poor. In this study, polybenzimidazole (PBI), a HPP with one of the highest glass transition temperatures currently available, is blended to PEEK to form a 50:50 blend (TU60). Tribological performance of the blend (TU60) was investigated by rubbing it against steel at temperatures up to 280 °C. Results obtained are compared to those from neat PEEK and neat PBI. All three polymers were thermally stable during the duration of tests. However chemical analyses on polymeric transfer layers on steel surfaces and polymer debris suggest polymer degradation. The degradation observed is shear-assisted, possibly promoted by shear heating. Indeed the estimated interfacial temperature based on Jaeger model was above the melting point of PEEK in some cases. TU60 outperforms PEEK in all test conditions and PBI at 280 °C. TU60 formed transfer layers on steel similar to that of PEEK. When contact temperature is closed to the melting point of PEEK, PEEK in the TU60 creates a low strength transfer layer which acts as an interfacial lubricant. This reduces friction which in turn reduces PBI degradation in TU60 at high temperature. This work provides a strategy for creating interfacial layers to improve polymer tribological performance while maintaining the integrity of the polymer.

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Citations: 25

Conference paper

Spagnoli A, Terzano M, Dini D, 2019,

Mixed-mode crack propagation during needle penetration for surgical interventions

, 25th International Conference on Fracture and Structural Integrity, Publisher: ELSEVIER SCIENCE BV, Pages: 775-780, ISSN: 2452-3216

Journal article

Dench J, di Mare L, Morgan N, Wong Jet al., 2018,

Comparing the molecular and global rheology of a fluid under high pressures

, Physical Chemistry Chemical Physics, Vol: 20, Pages: 30267-30280, ISSN: 1463-9076

The viscosity of liquids is a strong function of pressure. While viscosity is relatively easy to measure at low pressure, high-pressure rheology presents significant experimental challenges. As a result, rheological models are often used to extrapolate viscosity from low pressure measurements to higher pressures. Techniques to obtain data over a wide range of pressures and shear rates, as well as understanding the validity and limitations of methods to fill the gaps in the available data, are therefore of crucial practical and theoretical importance. This work examines the viscosity of polyalphaolefin (PAO) by combining average global area averaged measurements at high pressure and local molecular viscosity measurements at moderate pressures. Viscosities spanning five orders of magnitude are examined at pressures up to 720 MPa. High pressure results were obtained with friction measurements where the fluid is sheared between two surfaces in a loaded point contact. The local molecular microviscosity at medium and low pressures was measured by applying a technique based on fluorescence anisotropy, which probes the rotational motion of dye molecules in a nanoscale film under shear. Both sets of measurements are taken in the same configuration, an elastohydrodynamic (EHD) contact. This is the first set of quantitative local viscosity measurements that have been verified against both friction and high pressure rheometry measurements. Commonly used rheological models were compared to experimental results. Our work shows that fluorescence anisotropy and friction measurements can be used to determine the viscosity of liquids over a wide range of conditions from a single experimental setup. The results obtained match results from low- and high-pressure rheometry for PAO. The importance of correcting friction data for pressure non-uniformity, temperature and shear thinning is also highlighted.

Journal article

Tan Z, Dini D, Rodriguez y Baena F, Forte Aet al., 2018,

Composite hydrogel: A high fidelity soft tissue mimic for surgery

, Materials and Design, Vol: 160, Pages: 886-894, ISSN: 0264-1275

Accurate tissue phantoms are difficult to design due to the complex non-linear viscoelastic properties of real soft tissues. A composite hydrogel, resulting from a mix of poly(vinyl) alcohol and phytagel, is able to reproduce the viscoelastic responses of different soft tissues due to its compositional tunability. The aim of this work is to demonstrate the flexibility of the composite hydrogel in mimicking the interactions between surgical tools and various soft tissues, such as brain, lung and liver. Therefore compressive stiffness, insertion forces and frictional forces were used as matching criteria to determine the hydrogel compositions for each soft tissue. A full map of the behaviour of the synthetic material is provided for these three characteristics and the compositions found to best match the mechanical response of brain, lung and liver are reported. The optimised hydrogel samples are then tested and shown to mimic the behaviour of the three tissues with unprecedented fidelity. The effect of each hydrogel constituent on the compressive stiffness, needle insertion and frictional forces is also detailed in this work to explain their individual contributions and synergistic effects. This study opens important opportunities for the realisation of surgical planning and training devices and tools for in-vitro tissue testing.

Journal article

Vladescu SC, Marx N, Fernández L, Barceló F, Spikes HAet al., 2018,

Hydrodynamic friction of viscosity-modified oils in a journal bearing machine

, Tribology Letters, Vol: 66, ISSN: 1023-8883

The friction properties of a range of viscosity modifier-containing oils in an engine bearing have been studied in the hydrodynamic regime using a combined experimental and modelling approach. The viscometric properties of these oils were previously measured and single equations derived to describe how their viscosities vary with temperature and shear rate (Marx et al. Tribol Lett 66:92, 2018). A journal bearing machine has been used to measure the friction properties of the test oils at various oil supply temperatures, while simultaneously measuring bearing temperature using an embedded thermocouple. This shows the importance of taking account of thermal response in journal bearings since the operating oil film temperature is often considerably higher than the oil supply temperature. For Newtonian oils, friction coefficient measurements made over a wide range of speeds, loads and oil supply temperatures collapse onto a single Stribeck curve when the viscosity used in determining the Stribeck number is based on an effective oil film temperature. Journal bearing machine measurements on VM-containing oils show that these give lower friction than a Newtonian reference oil. A thermo-hydrodynamic model incorporating shear thinning has been used to explore further the frictional properties of the VM-containing oils. These confirm the findings of the journal bearing experiments and show that two key factors determine the friction of the engine bearing; (i) the low shear rate viscosity of the oil at the effective bearing temperature and (ii) the extent to which the blend shear thins at the high shear rate present in the bearing.

Journal article

Ewen J, Heyes D, Dini D, 2018,

Advances in nonequilibrium molecular dynamics simulations of lubricants and additives

, Friction, Vol: 6, Pages: 349-386, ISSN: 2223-7704

Nonequilibrium molecular dynamics (NEMD) simulations have provided unique insights into the nanoscale behaviour of lubricants under shear. This review discusses the early history of NEMD and its progression from a tool to corroborate theories of the liquid state, to an instrument that can directly evaluate important fluid properties, towards a potential design tool in tribology. The key methodological advances which have allowed this evolution are also highlighted. This is followed by a summary of bulk and confined NEMD simulations of liquid lubricants and lubricant additives, as they have progressed from simple atomic fluids to ever more complex, realistic molecules. The future outlook of NEMD in tribology, including the inclusion of chemical reactivity for additives, and coupling to continuum methods for large systems, is also briefly discussed.

Journal article

Dawczyk J, Ware E, Ardakani M, Russo J, Spikes Het al., 2018,

Use of FIB to study ZDDP tribofilms

, Tribology Letters, Vol: 66, Pages: 155-155, ISSN: 1023-8883

Focussed ion beam milling (FIB) followed by TEM has been used to study ZDDP tribofilms on rubbed steel surfaces. It has been found that the impact of high energy platinum and gallium ions during FIB causes significant morphological and structural changes to the uppermost 30–50 nm of a ZDDP tribofilm. This can be prevented by the low energy deposition of a quite thick gold layer prior to installation of the sample in the FIB facility. This problem, and its solution, have been quite widely reported in the non-tribology literature but have not previously been highlighted in the application of FIB to study tribological surfaces. It has also been found, using this gold pre-deposition method, that the bulk of the ZDDP tribofilm studied has a polycrystalline structure.

Journal article

Kontou A, Southby M, Morgan N, Spikes HAet al., 2018,

Influence of dispersant and ZDDP on soot wear

, Tribology Letters, Vol: 66, Pages: 1-15, ISSN: 1023-8883

Diesel engines and gasoline direct injection (GDI) engines both produce soot due to incomplete combustion of the fuel and some enters the lubricant where it accumulates between drain intervals, promoting wear of rubbing engine components. Currently the most favoured mechanism for this wear is that the anti-wear additives present in engine oils, primarily zinc dialkyldithiophosphates (ZDDPs), react very rapidly with rubbing surfaces to form relatively soft reaction products. These are easily abraded by soot, resulting in a corrosive-abrasive wear mechanism. This study has explored the impact of engine oil dispersant additives on this type of wear using combinations of dispersant, ZDDP and carbon black, a soot surrogate. It has been found that both the concentration and type of dispersant are critical in influencing wear. With most dispersants studied, wear becomes very high over an intermediate dispersant concentration range of ca 0.1–0.4 wt% N, with both lower and higher dispersant levels showing much less wear. However a few dispersants appear able to suppress high wear by ZDDP and carbon black over the whole concentration range. A series of experiments have been carried out to determine the origin of this behaviour and it is believed that high levels of dispersant, and, for a few dispersants, all concentration levels, protect the iron sulphide tribofilm initially formed by ZDDP from abrasion by carbon black.

Journal article

Tajabadi-Ebrahimi M, Dini D, Balint DS, Sutton AP, Ozbayraktar Set al., 2018,

Discrete crack dynamics: a planar model of crack propagation and crack-inclusion interactions in brittle materials

, International Journal of Solids and Structures, Vol: 152-153, Pages: 12-27, ISSN: 0020-7683

The Multipole Method (MPM) is used to simulate the many-body self-consistentproblem of interacting elliptical micro-cracks and inclusions in single crystals. Acriterion is employed to determine the crack propagation path based on the stressdistribution; the evolution of individual micro-cracks and their interactions withexisting cracks and inclusions is then predicted using what we coin the DiscreteCrack Dynamics (DCD) method. DCD is fast (semi-analytical) and particularlysuitable for the simulation of evolving low-speed crack networks in brittle orquasi-brittle materials. The method is validated against finite element analysispredictions and previously published experimental data.

Journal article

Verschueren J, Gurrutxaga-Lerma B, Balint D, Sutton A, Dini Det al., 2018,

Instabilities of high speed dislocations

, Physical Review Letters, Vol: 121, ISSN: 0031-9007

Despite numerous theoretical models and simulation results, a clear physical picture of dislocations traveling at velocities comparable to the speed of sound in the medium remains elusive. Using two complementary atomistic methods to model uniformly moving screw dislocations, lattice dynamics and molecular dynamics, the existence of mechanical instabilities in the system is shown. These instabilities are found at material-dependent velocities far below the speed of sound. We show that these are the onset of an atomistic kinematic generation mechanism, which ultimately results in an avalanche of further dislocations. This homogeneous nucleation mechanism, observed but never fully explained before, is relevant in moderate and high strain rate phenomena including adiabatic shear banding, dynamic fracture, and shock loading. In principle, these mechanical instabilities do not prevent supersonic motion of dislocations.

Journal article

Hartinger M, Reddyhoff T, 2018,

CFD modeling compared to temperature and friction measurements of an EHL line contact

, Tribology International, Vol: 126, Pages: 144-152, ISSN: 0301-679X

In this paper, predictions from CFD modeling are compared against measurements of surface temperatures and friction for an EHL line contact lubricated with the fluid Santotrac 50. Two slide-to-roll-ratios (SRR), 50% and 100%, and entrainment velocities ranging from 0.211 to 1.13 m/s are considered. Very good agreement is shown for the 50% SRR cases, with only a 3% deviation in friction coefficient values. At 100% SRR, the deviation in friction increases to 3–7% which is attributed to deficiencies in the modeling approach with regard to shear-thinning. The temperature profiles agree reasonably well at 50% SRR and show larger deviations at 100% SRR. For all cases, the formation of a shear-band in the center of the fluid film is predicted. This is very pronounced for 100% SRR, although likely to be over-estimated by this CFD-approach. The data presented here serve as a basis from which further refinements in the modeling and measurements shown can be made.

Journal article

Yu M, Arana C, Evangelou S, Dini D, Cleaver Get al., 2018,

Parallel active link suspension: a quarter-car experimental study

, IEEE-ASME Transactions on Mechatronics, Vol: 23, Pages: 2066-2077, ISSN: 1083-4435

In this paper, a novel electro-mechanical active suspension for cars, the Parallel Active Link Suspension (PALS), is proposed and then experimentally studied. PALS involves the introduction of a rotary-actuator-driven rocker-pushrod mechanism in parallel with the conventional passive suspension assembly, to exert an additional controlled force between the chassis and the wheel. The PALS geometric arrangement is designed and optimized to maximize the rocker torque propagation onto the tire load increment. A quarter car test rig with double wishbone suspension is utilized for the PALS physical implementation. Based on a linear equivalent model of the PALS quarter car, a conservative and an aggressive robust H∞ control schemes are synthesized separately to improve the ride comfort and the road holding, with different levels of control effort allowed in each of the control schemes. Simulations with a theoretical nonlinear model of the PALS quarter car are performed to evaluate the potential in suspension performance enhancement and power demand in the rocker actuator. Experiments with a harmonic road, a smoothed bump and hole, and swept frequency are conducted with the quarter car test rig to validate the practical feasibility of the novel PALS, the ride comfort enhancement, as well as the accuracy of the theoretical model and of a further nonlinear model in which practical features existing in the test rig are identified and included.

Journal article

Campen S, Smith B, Wong J, 2018,

Deposition of asphaltene from destabilized dispersions in heptane-toluene

, Energy and Fuels, Vol: 32, Pages: 9159-9171, ISSN: 0887-0624

Deposition of carbonaceous materials, such as asphaltene, is a major problem in petroleum production. During production, changing environmental conditions destabilize asphaltene, resulting in dispersions that are out of equilibrium, where asphaltene is aggregating or flocculating. Key to developing the most effective strategies for tackling this problem is a fundamental understanding of asphaltene deposition behavior. A quartz crystal microbalance with dissipation monitoring (QCM-D) is used to study asphaltene deposition from destabilized dispersions generated by in-line mixing of asphaltene in toluene (a solvent) with n-heptane (a precipitant). The effects of heptane:toluene ratio and destabilization time are investigated. At high heptane:toluene ratio, the rate of asphaltene aggregation is faster, and large flocs form by the time the flowing liquid reaches the QCM cell. In this case, the rate of deposition decreases with deposition time. At low heptane:toluene ratio, the rate of asphaltene aggregation is slower; hence large flocs do not form before the flowing liquid reaches the QCM cell, and deposition of smaller aggregates occurs. Here, the deposition rate is constant with time. The deposited mass is greatest before the formation of large flocs and at short destabilization times, where the particle distribution is furthest from equilibrium. Destabilized small particles existing immediately after a destabilization event pose a greater deposition problem than the flocs that subsequently form. This may be a contributing factor in the existence of deposition “hotspots” at certain locations in the production pipeline. Pushing destabilized dispersions to their new equilibrium distributions as quickly as possible may be a preventative strategy to combat deposition. The dissipation–frequency relationship monitored by QCM-D is sensitive to the nature of deposited asphaltene films and may be used as a diagnostic tool.

Journal article

Gattinoni C, Ewen JP, Dini D, 2018,

Adsorption of Surfactants on α-Fe<sub>2</sub>O<sub>3</sub>(0001): A Density Functional Theory Study

, JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 122, Pages: 20817-20826, ISSN: 1932-7447

Journal article

Marx N, Fernández L, Barceló F, Spikes HAet al., 2018,

Shear thinning and hydrodynamic friction of viscosity modifier-containingoils. Part I: shear thinning behaviour

, Tribology Letters, Vol: 66, Pages: 92-92, ISSN: 1023-8883

Viscosity versus shear rate curves have been measured up to 107 s−1 for a range of VM solutions and fully formulated oils of known composition at several temperatures. This shows large differences in the shear thinning tendencies of different engine oil VMs. It has been found that viscosity versus shear rate data at different temperatures can be collapsed onto a single master curve using time–temperature superposition based on a shear rate shift factor. This enables shear thinning equations to be derived that are able to predict the viscosity of a given oil at any shear rate and temperature within the range originally tested. One of the tested lubricants does not show this time temperature superposition collapse. This fluid also exhibits extremely high viscosity index and shear thins more easily at high than at low temperature, unlike all the other solutions tested. This unusual response may originate from the presence on the VM molecules of two structurally and chemically different components. In a companion paper, the master shear thinning curves obtained in this paper are used to explore how VMs impact film thickness and friction in a steadily loaded, isothermal journal bearing [1].

Journal article

Vakis A, Yastrebov V, Scheibert J, Nicola L, Dini D, Minfray C, Almqvist A, Paggi M, Lee S, Limbert G, Molinari JF, Anciaux G, Aghababaei R, Echeverri Restrepo S, Papangelo A, Cammarata A, Nicolini P, Putignano C, Carbone G, Stupkiewicz S, Lengiewicz J, Costagliola G, Bosia F, Guarino R, Pugno NM, Müser MH, Ciavarella Met al., 2018,

Modeling and simulation in tribology across scales: An overview

, Tribology International, Vol: 125, Pages: 169-199, ISSN: 0301-679X

This review summarizes recent advances in the area of tribology based on the outcome of a Lorentz Center workshop surveying various physical, chemical and mechanical phenomena across scales. Among the main themes discussed were those of rough surface representations, the breakdown of continuum theories at the nano- and micro-scales, as well as multiscale and multiphysics aspects for analytical and computational models relevant to applications spanning a variety of sectors, from automotive to biotribology and nanotechnology. Significant effort is still required to account for complementary nonlinear effects of plasticity, adhesion, friction, wear, lubrication and surface chemistry in tribological models. For each topic, we propose some research directions.

Journal article

Shen L, Denner F, Morgan N, Van Wachem B, Dini Det al., 2018,

Capillary waves with surface viscosity

, Journal of Fluid Mechanics, Vol: 847, Pages: 644-663, ISSN: 0022-1120

Experiments over the last 50 years have suggested a tentative correlation between the surface (shear) viscosity and the stability of a foam or emulsion. We examine this link theoretically using small-amplitude capillary waves in the presence of a surfactant solution of dilute concentrations where the associated Marangoni and surface viscosity effects are modelled via the Boussinesq-Scriven formulation. The resulting integro-differential initial value problem is solved analyticallyand surface viscosity is found to contribute an overall damping effect on the amplitude of the capillary wave with varying degrees depending on the lengthscale of the system.Numerically, we find the critical damping wavelength to increase for increasing surface concentration but the rate of increase remains different for both the surface viscosity and the Marangoni effect.

Journal article

Reddyhoff T, Underwood R, Sayles R, Spikes Het al., 2018,

Temperature measurement of debris particles in EHL contacts

, Surface Topography: Metrology and Properties, Vol: 6, ISSN: 2051-672X

Dents caused by entrained debris are now the main cause of fatigue failure in rolling element bearings. It is therefore important to be able to understand and predict the deformation behaviour of particles in elastohydrodynamic contacts. This paper describes a new method to study debris entrainment. This uses a sensitive infrared microscope to map the temperature of a contact between a steel ball and coated sapphire disc as lubricant dispersed with bearing dust is entrained. Full-field thermal maps were acquired at a sufficient rate to monitor the deformation of a single particle on its journey through the contact.Under the low-speed, high-sliding conditions studied, the temperature rise increases from when the particle is trapped by the inlet to reach a peak near the contact centre, where shearing is a maximum. Under these conditions, temperature rises are typically of the order of 10 °C, which is significantly lower than has been predicted theoretically. Even lower temperature rises were observed under pure rolling conditions, since minimal shearing occurs.Experimental results are also compared with existing models used to predict particle behaviour. Measured radiation distributions confirm qualitatively the ductile particle deformation mechanisms originally proposed by Hamer et al.

Journal article

Marx N, Fernández L, Barceló F, Spikes HAet al., 2018,

Shear Thinning and Hydrodynamic Friction of Viscosity Modifier-ContainingOils. Part II: Impact of Shear Thinning on Journal BearingFriction

, Tribology Letters, Vol: 66, Pages: 91-91, ISSN: 1023-8883

Journal article

Kanca Y, Milner P, Dini D, Amis Aet al., 2018,

Tribological evaluation of biomedical polycarbonate urethanes against articular cartilage

, Journal of the Mechanical Behavior of Biomedical Materials, Vol: 82, Pages: 394-402, ISSN: 1751-6161

This research investigated the in-vitro wear and friction performance of polycarbonate urethane (PCU) 80A as they interact with articular cartilage, using a customised multidirectional pin-on-plate tester. Condyles were articulated against PCU 80A discs (Bionate® I and Bionate® II) (configuration 1) and the results arising from these tests were compared to those recorded during the sliding of PCU pins against cartilage plates (configuration 2). Configuration 1 produced steadily increasing coefficient of friction (COF) (up to 0.64 ± 0.05) and had the same trend as the cartilage–on–stainless steel articulation (positive control). When synovial fluid rather than bovine calf serum was used as lubricant, average COF significantly decreased from 0.50 ± 0.02–0.38 ± 0.06 for condyle–on–Bionate® I (80AI) and from 0.41 ± 0.02–0.24 ± 0.04 for condyle–on–Bionate® II (80AII) test configurations (p < 0.05). After 15 h testing, the cartilage–on–cartilage articulation (negative control) tests showed no cartilage degeneration. However, different levels of cartilage volume loss were found on the condyles from the positive control (12.5 ± 4.2 mm3) and the PCUs (20.1 ± 3.6 mm3 for 80 AI and 19.0 ± 2.3 mm3 for 80AII) (p > 0.05). A good correlation (R2 =0.84) was found between the levels of average COF and the volume of cartilage lost during testing; increasing wear was found at higher levels of COF. Configuration 2 showed low and constant COF values (0.04 ± 0.01), which were closer to the negative control (0.03 ± 0.01) and significantly lower than configuration 1 (p < 0.05). The investigation showed that PCU is a good candidate for use in hemiarthroplasty components, where only one of the two articulating surfaces is replaced, as long as the synthetic material is implanted in a region where migrating cartilage contact is achieved. Bio

Journal article

Stevenson H, Parkes M, Austin L, Jaggard M, Akhbri P, Vaghela U, Williams H, Gupte C, Cann PMet al., 2018,

The development of a small-scale wear test for CoCrMo specimens with human synovial fluid

, Biotribology, Vol: 14, Pages: 1-10, ISSN: 2352-5738

A new test was developed to measure friction and wear of hip implant materials under reciprocating sliding conditions. The method requires a very small amount of lubricant (<3 ml) which allows testing of human synovial fluid. Friction and wear of Cobalt Chromium Molybdenum (CoCrMo) material pairs were measured for a range of model and human synovial fluid samples. The initial development of the test assessed the effect of fluid volume and bovine calf serum (BCS) concentration on friction and wear. In a second series of tests human synovial fluid (HSF) was used. The wear scar size (depth and volume) on the disc was dependent on protein content and reduced significantly for increasing BCS concentration. The results showed that fluid volumes of <1.5 ml were affected by evaporative loss effectively increasing the protein concentration resulting in anomalously lower wear. At the end of the test thick deposits were observed in and around the wear scars on the disc and ball; these were analysed by Infrared Reflection-Absorption Spectroscopy. The deposits were composed primarily of denatured proteins and similar IR spectra were obtained from the BCS and HSF tests. The analysis confirmed the importance of SF proteins in determining wear of CoCrMo couples.

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