@article{Nguyen:2015:10.1039/c5dt02104a,
author = {Nguyen, BN and Adrio, LA and Albrecht, T and White, AJP and Newton, MA and Nachtegaal, M and Figueroa, SJA and Hii, KKM},
doi = {10.1039/c5dt02104a},
journal = {Dalton Transactions},
pages = {16586--16591},
title = {Electronic structures of cyclometalated palladium complexes in the higher oxidation states},
url = {http://dx.doi.org/10.1039/c5dt02104a},
volume = {44},
year = {2015}
}

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TY  - JOUR
AB  - The electronic and redox properties of a series of cyclometalated Pd complexes with oxidation states of +2, +3 and +4 were examined using a range of currently available spectroscopic and electrochemical techniques. Changes in metal–ligand bond lengths were established by X-ray crystallography and correctly predicted by DFT calculations, from which the frontier orbitals and partial atomic charges can be obtained. X-ray absorption spectroscopy (XAS) revealed interesting XANES features that suggest a synergistic relationship between metal–ligand interactions. The electrochemical study of the Pd(II) dimer was found to contain two sequential oxidative potentials indicative of a weak metal–metal interaction.
AU  - Nguyen,BN
AU  - Adrio,LA
AU  - Albrecht,T
AU  - White,AJP
AU  - Newton,MA
AU  - Nachtegaal,M
AU  - Figueroa,SJA
AU  - Hii,KKM
DO  - 10.1039/c5dt02104a
EP  - 16591
PY  - 2015///
SN  - 1477-9226
SP  - 16586
TI  - Electronic structures of cyclometalated palladium complexes in the higher oxidation states
T2  - Dalton Transactions
UR  - http://dx.doi.org/10.1039/c5dt02104a
UR  - http://hdl.handle.net/10044/1/41204
VL  - 44
ER  - 

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