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• Journal article
  Zhong WY, Toumi R, Haigh JD, 1996,

  Climate forcing by stratospheric ozone depletion calculated from observed temperature trends

  , GEOPHYSICAL RESEARCH LETTERS, Vol: 23, Pages: 3183-3186, ISSN: 0094-8276
  • Author Web Link
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  • Citations: 17
• Journal article
  Bekki S, Pyle JA, Zhong W, Toumi R, Haigh JD, Pyle DMet al., 1996,

  The role of microphysical and chemical processes in prolonging the climate forcing of the Toba eruption

  , GEOPHYSICAL RESEARCH LETTERS, Vol: 23, Pages: 2669-2672, ISSN: 0094-8276
  • Author Web Link
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  • Citations: 77
• Journal article
  Houston PL, Suits AG, Toumi R, 1996,

  Isotopic enrichment of heavy ozone in the stratosphere

  , JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, Vol: 101, Pages: 18829-18834, ISSN: 2169-897X
  • Author Web Link
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  • Citations: 11
• Journal article
  Zhong WY, Haigh JD, Toumi R, Bekki Set al., 1996,

  Infrared heating rates in the stratosphere due to volcanic sulphur dioxide

  , QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, Vol: 122, Pages: 1459-1466, ISSN: 0035-9009
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  • Citations: 5
• Journal article
  Toumi R, Haigh JD, Law KS, 1996,

  A tropospheric ozone-lightning climate feedback

  , GEOPHYSICAL RESEARCH LETTERS, Vol: 23, Pages: 1037-1040, ISSN: 0094-8276
  • Author Web Link
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  • Citations: 38
• Journal article
  Lary DJ, Chipperfield MP, Toumi R, Lenton Tet al., 1996,

  Heterogeneous atmospheric bromine chemistry

  , JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, Vol: 101, Pages: 1489-1504, ISSN: 2169-897X
  • Author Web Link
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  • Citations: 108
• Journal article
  Toumi R, Houston PL, Wodtke AM, 1996,

  Reactive O-2(v>=26) as a source of stratospheric O-3

  , JOURNAL OF CHEMICAL PHYSICS, Vol: 104, Pages: 775-776, ISSN: 0021-9606
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  • Citations: 41
• Journal article
  Sinha A, Toumi R, 1996,

  A comparison of climate forcings due to chlorofluorocarbons and carbon monoxide

  , GEOPHYSICAL RESEARCH LETTERS, Vol: 23, Pages: 65-68, ISSN: 0094-8276
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  • Citations: 6
• Journal article
  TOUMI R, BEKKI S, LAW K, 1995,

  CLIMATE AND CCN - REPLY

  , NATURE, Vol: 375, Pages: 111-111, ISSN: 0028-0836
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  • Citations: 2
• Journal article
  LARY DJ, CHIPPERFIELD MP, TOUMI R, 1995,

  THE POTENTIAL IMPACT OF THE REACTION OH+CLO-]HCL+O-2 ON POLAR OZONE PHOTOCHEMISTRY

  , JOURNAL OF ATMOSPHERIC CHEMISTRY, Vol: 21, Pages: 61-79, ISSN: 0167-7764
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  • Citations: 30
• Journal article
  NESBITT FL, MONKS PS, PAYNE WA, STIEF LJ, TOUMI Ret al., 1995,

  THE REACTION O(3P)+HOBR - TEMPERATURE-DEPENDENCE OF THE RATE-CONSTANT AND IMPORTANCE OF THE REACTION AS AN HOBR STRATOSPHERIC LOSS PROCESS

  , GEOPHYSICAL RESEARCH LETTERS, Vol: 22, Pages: 827-830, ISSN: 0094-8276
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  • Citations: 9
• Journal article
  TOUMI R, BEKKI S, LAW KS, 1994,

  INDIRECT INFLUENCE OF OZONE DEPLETION ON CLIMATE FORCING BY CLOUDS

  , NATURE, Vol: 372, Pages: 348-351, ISSN: 0028-0836
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  • Citations: 34
• Journal article
  Miller RL, Suits AG, Houston PL, Toumi R, Mack JA, Wodtke AMet al., 1994,

  The "ozone deficit" problem: O2(X, v ≥ 26) + Q(3P) from 226-nm ozone photodissociation

  , Science, Vol: 265, Pages: 1831-1838, ISSN: 0036-8075

  Highly vibrationally excited O<inf>2</inf>(X ³Σ<inf>g</inf>^-, v ≥26) has been observed from the photodissociation of ozone (O<inf>3</inf>), and the quantum yield for this reaction has been determined for excitation at 226 nanometers. This observation may help to address the "ozone deficit" problem, or why the previously predicted stratospheric O<inf>3</inf> concentration is less than that observed. Recent kinetic studies have suggested that O<inf>2</inf>(X ³Σ<inf>g</inf>^-, v ≥ 26) can react rapidly with O<inf>2</inf> to form O<inf>3</inf> + O and have led to speculation that, if produced in the photodissociation of O<inf>3</inf>, this species might be involved in resolving the discrepancy. The sequence O<inf>3</inf> + hν → O<inf>2</inf>(X³Σ<inf>g</inf>^-, v ≥ 26) + O; O<inf>2</inf>(X³Σ<inf>g</inf>^-, v ≥ 26) + O<inf>2</inf> → O<inf>3</inf> + O (where hν is a photon) would be an autocatalytic mechanism for production of odd oxygen. A two-dimensional atmospheric model has been used to evaluate the importance of this new mechanism. The new mechanism can completely account for the tropical O<inf>3</inf> deficit at an altitude of 43 kilometers, but it does not completely account for the deficit at higher altitudes. The mechanism also provides for isotopic fractionation and may contribute to an explanation for the anomalously high concentration of heavy O<inf>3</inf> in the stratosphere.

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  • Citations: 174
• Journal article
  TOUMI R, BEKKI S, 1994,

  SENSITIVITY OF STRATOSPHERIC COMPOSITION TO OXYGEN ABSORPTION OF SOLAR-RADIATION (175-210 NM)

  , JOURNAL OF ATMOSPHERIC CHEMISTRY, Vol: 18, Pages: 57-73, ISSN: 0167-7764
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  • Citations: 4
• Journal article
  TOUMI R, BEKKI S, 1993,

  THE IMPORTANCE OF THE REACTIONS BETWEEN OH AND CLO FOR STRATOSPHERIC OZONE

  , GEOPHYSICAL RESEARCH LETTERS, Vol: 20, Pages: 2447-2450, ISSN: 0094-8276
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  • Citations: 28
• Journal article
  BEKKI S, TOUMI R, PYLE JA, 1993,

  ROLE OF SULFUR PHOTOCHEMISTRY IN TROPICAL OZONE CHANGES AFTER THE ERUPTION OF MOUNT PINATUBO

  , NATURE, Vol: 362, Pages: 331-333, ISSN: 0028-0836
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  • Citations: 44
• Journal article
  TOUMI R, BEKKI S, COX R, 1993,

  A MODEL STUDY OF ATMOS OBSERVATIONS AND THE HETEROGENEOUS LOSS OF N2O5 BY THE SULFATE AEROSOL LAYER

  , JOURNAL OF ATMOSPHERIC CHEMISTRY, Vol: 16, Pages: 135-144, ISSN: 0167-7764
  • Author Web Link
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  • Citations: 19
• Journal article
  BEKKI S, TOUMI R, PYLE JA, JONES AEet al., 1991,

  FUTURE AIRCRAFT AND GLOBAL OZONE

  , NATURE, Vol: 354, Pages: 193-194, ISSN: 0028-0836
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  • Citations: 20
• Journal article
  SPIRO M, TOUMI R, KANDIAH M, 1989,

  THE KINETICS AND MECHANISM OF CAFFEINE INFUSION FROM COFFEE - THE HINDRANCE FACTOR IN INTRA-BEAN DIFFUSION

  , JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Vol: 46, Pages: 349-356, ISSN: 0022-5142
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  • Citations: 30
• Thesis dissertation
  Liu F,

  Significance of metal-induced proteins in metal bioaccumulation in marine bivalves and pollution assessment

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