@article{Tong:2012,
author = {Tong, D and Trusler, JPM and Maitland, GC and Gibbins, J and Fennell, PS},
journal = {International Journal of Greenhouse Gas Control},
pages = {37--47},
title = {Solubility of carbon dioxide in aqueous solution of monoethanolamine or 2-amino-2-methyl-1-propanol: Experimental measurements and modelling},
volume = {6},
year = {2012}
}

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TY  - JOUR
AB  - Despite the importance of the accurate measurement of vapour–liquid equilibria (VLE) data, the reported values, even for well-studied systems such as MEA–H2O–CO2, are scattered. This work centres on the development of an experimental method to measure accurately the VLE of various aqueous amine systems. A static-analytic type of VLE apparatus has been constructed and employed to measure the VLE of CO2 in aqueous monoethanolamine and 2-amino-2-methyl-1-propanol. Gas chromatography was used to analyse the liquid phase compositions. The setup has been validated against literature data for 30 mass% MEA (monoethanolamine) at T = 313 and 393 K and was shown to be capable of generating reliable and repeatable data. New measurements for 30 mass% aqueous AMP (2-amino-2-methyl-1-propanol) solutions are also presented at temperatures between 313 and 393 K and a total pressure range of 23–983 kPa. A quasi-chemical model has been employed to interpret the experimental data for the MEA–H2O–CO2 and AMP–H2O–CO2 systems. The average absolute deviation (ΔAAD) between model prediction and experimental data is within 7%.
AU  - Tong,D
AU  - Trusler,JPM
AU  - Maitland,GC
AU  - Gibbins,J
AU  - Fennell,PS
EP  - 47
PY  - 2012///
SP  - 37
TI  - Solubility of carbon dioxide in aqueous solution of monoethanolamine or 2-amino-2-methyl-1-propanol: Experimental measurements and modelling
T2  - International Journal of Greenhouse Gas Control
VL  - 6
ER  - 

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