@article{Mcculloch:2012:10.1021/ar200208g,
author = {Mcculloch, I and Ashraf, RS and Biniek, L and Bronstein, H and Combe, C and Donaghey, JE and James, DI and Nielsen, CB and Schroeder, BC and Zhang, W},
doi = {10.1021/ar200208g},
journal = {ACCOUNTS OF CHEMICAL RESEARCH},
pages = {714--722},
title = {Design of Semiconducting Indacenodithiophene Polymers for High Performance Transistors and Solar Cells},
url = {http://dx.doi.org/10.1021/ar200208g},
volume = {45},
year = {2012}
}

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TY  - JOUR
AB  - The prospect of using low cost, high throughput material deposition processes to fabricate organic circuitry and solar cells continues to drive research towards improving the performance of the semiconducting materials utilized in these devices. Conjugated aromatic polymers have emerged as a leading candidate semiconductor material class, due to their combination of their amenability to processing and reasonable electrical and optical performance. Challenges remain, however, to further improve the charge carrier mobility of the polymers for transistor applications and the power conversion efficiency for solar cells. This optimization requires a clear understanding of the relationship between molecular structure and both electronic properties and thin film morphology.In this Account, we describe an optimization process for a series of semiconducting polymers based on an electron rich indacenodithiophene aromatic backbone skeleton. We demonstrate the effect of bridging atoms, alkyl chain functionalization, and co-repeating units on the morphology, molecular orbital energy levels, charge carrier mobility, and solar cell efficiencies. This conjugated unit is extremely versatile with a coplanar aromatic ring structure, and the electron density can be manipulated by the choice of bridging group between the rings. The functionality of the bridging group also plays an important role in the polymer solubility, and out of plane aliphatic chains present in both the carbon and silicon bridge promote solubility. This particular polymer conformation, however, typically suppresses long range organization and crystallinity, which had been shown to strongly influence charge transport. In many cases, polymers exhibited both high solubility and excellent charge transport properties, even where there was no observable evidence of polymer crystallinity. The optical bandgap of the polymers can be tuned by the combination of the donating power of the bridging unit and the electron withdra
AU  - Mcculloch,I
AU  - Ashraf,RS
AU  - Biniek,L
AU  - Bronstein,H
AU  - Combe,C
AU  - Donaghey,JE
AU  - James,DI
AU  - Nielsen,CB
AU  - Schroeder,BC
AU  - Zhang,W
DO  - 10.1021/ar200208g
EP  - 722
PY  - 2012///
SN  - 0001-4842
SP  - 714
TI  - Design of Semiconducting Indacenodithiophene Polymers for High Performance Transistors and Solar Cells
T2  - ACCOUNTS OF CHEMICAL RESEARCH
UR  - http://dx.doi.org/10.1021/ar200208g
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=000303965300004&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
VL  - 45
ER  - 

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