@article{Labanti:2021:10.1021/acsnano.1c01345,
author = {Labanti, C and Sung, MJ and Luke, J and Kwon, S and Kumar, R and Hong, J and Kim, J and Bakulin, AA and Kwon, S-K and Kim, Y-H and Kim, J-S},
doi = {10.1021/acsnano.1c01345},
journal = {ACS Nano},
pages = {7700--7712},
title = {Selenium-substituted non-fullerene acceptors: a route to superior Operational stability for organic bulk heterojunction solar cells.},
url = {http://dx.doi.org/10.1021/acsnano.1c01345},
volume = {15},
year = {2021}
}

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TY  - JOUR
AB  - Non-fullerene acceptors (NFAs) for organic solar cells (OSCs) have significantly developed over the past five years with continuous improvements in efficiency now over 18%. However, a key challenge still remains in order to fully realize their commercialization potential: the need to extend device lifetime and to control degradation mechanisms. Herein, we investigate the effect of two different molecular engineering routes on the widely utilized ITIC NFA, to tune its optoelectronic properties and interactions with the donor polymer in photoactive blends. Heavier selenium (Se) atoms substitute sulfur (S) atoms in the NFA core in either outer or inner positions, and methyl chains are attached to the end groups. By investigating the effects of these structural modifications on the long-term operational stability of bulk-heterojunction OSC devices, we identify outer selenation as a powerful strategy to significantly increase device lifetime compared to ITIC. Combining outer selenation and methylation results in an impressive 95% of the initial OSC efficiency being retained after 450 h under operating conditions, with an exceptionally long projected half-lifetime of 5600 h compared to 400 h for ITIC. We find that the heavier and larger Se atoms at outer-core positions rigidify the molecular structure to form highly crystalline films with low conformational energetic disorder. It further enhances charge delocalization over the molecule, promoting strong intermolecular interactions among acceptor molecules. Upon methylation, this strong intermolecular interaction stabilizes acceptor domains in blends to be resilient to light-induced morphological changes, thereby leading to superior device stability. Our results highlight the crucial role of NFA molecular structure for OSC operational stability and provide important NFA design rules via heteroatom position and end-group control.
AU  - Labanti,C
AU  - Sung,MJ
AU  - Luke,J
AU  - Kwon,S
AU  - Kumar,R
AU  - Hong,J
AU  - Kim,J
AU  - Bakulin,AA
AU  - Kwon,S-K
AU  - Kim,Y-H
AU  - Kim,J-S
DO  - 10.1021/acsnano.1c01345
EP  - 7712
PY  - 2021///
SN  - 1936-0851
SP  - 7700
TI  - Selenium-substituted non-fullerene acceptors: a route to superior Operational stability for organic bulk heterojunction solar cells.
T2  - ACS Nano
UR  - http://dx.doi.org/10.1021/acsnano.1c01345
UR  - https://www.ncbi.nlm.nih.gov/pubmed/33769786
UR  - https://pubs.acs.org/doi/10.1021/acsnano.1c01345
UR  - http://hdl.handle.net/10044/1/88127
VL  - 15
ER  - 

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