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Journal articleKirchartz T, Nelson J, 2014,
Device Modelling of Organic Bulk Heterojunction Solar Cells
, MULTISCALE MODELLING OF ORGANIC AND HYBRID PHOTOVOLTAICS, Vol: 352, Pages: 279-324, ISSN: 0340-1022 -
Journal articleVaissier V, Mosconi E, Moia D, et al., 2014,
Effect of Molecular Fluctuations on Hole Diffusion within Dye Monolayers
, CHEMISTRY OF MATERIALS, Vol: 26, Pages: 4731-4740, ISSN: 0897-4756- Author Web Link
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- Citations: 21
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Book chapterEkins-Daukes NJ, Nelson J, 2014,
Quantum Well Solar Cells
, Clean Electricity from Photovoltaics, Editors: Green, Archer, Publisher: Imperial College Press, ISBN: 9781848167674The second edition of Clean Electricity from Photovoltaics, first published in 2001, provides an updated account of the underlying science, technology and market prospects for photovoltaics.
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Journal articleDattani R, Bannock JH, Fei Z, et al., 2014,
A general mechanism for controlling thin film structures in all-conjugated block copolymer: fullerene blends
, JOURNAL OF MATERIALS CHEMISTRY A, Vol: 2, Pages: 14711-14719, ISSN: 2050-7488 -
Journal articleMartinez L, Higuchi S, MacLachlan AJ, et al., 2014,
Improved electronic coupling in hybrid organic-inorganic nanocomposites employing thiol-functionalized P3HT and bismuth sulfide nanocrystals
, Nanoscale, Vol: 6, Pages: 10018-10026, ISSN: 2040-3372In this study, we employ a thiol-functionalized polymer (P3HT-SH) as a leverage to tailor the nanomorphology and electronic coupling in polymer–nanocrystal composites for hybrid solar cells. The presence of the thiol functional group allows for a highly crystalline semiconducting polymer film at low thiol content and allows for improved nanomorphologies in hybrid organic–inorganic systems when employing non-toxic bismuth sulfide nanocrystals. The exciton dissociation efficiency and carrier dynamics at this hybrid heterojunction are investigated through photoluminescence quenching and transient absorption spectroscopy measurements, revealing a larger degree of polaron formation when P3HT-SH is employed, suggesting an increased electronic interaction between the metal chalcogenide nanocrystals and the thiol-functionalized P3HT. The fabricated photovoltaic devices show 15% higher power conversion efficiencies as a result of the improved nanomorphology and better charge transfer mechanism together with the higher open circuit voltages arising from the deeper energy levels of P3HT-SH.
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Journal articleXu W, Zhang X, Hu Q, et al., 2014,
Fluorene-based cathode interlayer polymers for high performance solution processed organic optoelectronic devices
, ORGANIC ELECTRONICS, Vol: 15, Pages: 1244-1253, ISSN: 1566-1199- Author Web Link
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- Citations: 35
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Journal articleEmmott CJM, Ekins-Daukes NJ, Nelson J, 2014,
Dynamic carbon mitigation analysis: the role of thin-film photovoltaics
, ENERGY & ENVIRONMENTAL SCIENCE, Vol: 7, Pages: 1810-1818, ISSN: 1754-5692- Author Web Link
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- Citations: 15
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Journal articleMacKenzie RCI, Goeritz A, Greedy S, et al., 2014,
Theory of Stark spectroscopy transients from thin film organic semiconducting devices
, PHYSICAL REVIEW B, Vol: 89, ISSN: 2469-9950- Author Web Link
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- Citations: 12
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Journal articleFew S, Frost JM, Kirkpatrick J, et al., 2014,
Influence of Chemical Structure on the Charge Transfer State Spectrum of a Polymer:Fullerene Complex
, JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 118, Pages: 8253-8261, ISSN: 1932-7447- Author Web Link
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- Citations: 60
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Journal articleMacLachlan AJ, O'Mahony FTF, Sudlow AL, et al., 2014,
Solution- Processed Mesoscopic Bi2S3: Polymer Photoactive Layers
, CHEMPHYSCHEM, Vol: 15, Pages: 1019-1023, ISSN: 1439-4235- Author Web Link
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- Citations: 30
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Journal articleDeledalle F, Shakya Tuladhar P, Nelson J, et al., 2014,
Understanding the Apparent Charge Density Dependence of Mobility and Lifetime in Organic Bulk Heterojunction Solar Cells
, The Journal of Physical Chemistry C, Vol: 118, Pages: 8837-8842, ISSN: 1932-7447 -
Journal articleAbramavicius V, Vithanage DA, Devizis A, et al., 2014,
Carrier motion in as-spun and annealed P3HT:PCBM blends revealed by ultrafast optical electric field probing and Monte Carlo simulations
, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol: 16, Pages: 2686-2692, ISSN: 1463-9076 -
Journal articleGuilbert AAY, Frost JM, Agostinelli T, et al., 2014,
Influence of Bridging Atom and Side Chains on the Structure and Crystallinity of Cyclopentadithiophene-Benzothiadiazole Polymers
, CHEMISTRY OF MATERIALS, Vol: 26, Pages: 1226-1233, ISSN: 0897-4756- Author Web Link
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- Citations: 46
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Journal articleMoia D, Vaissier V, Lopez-Duarte I, et al., 2014,
The reorganization energy of intermolecular hole hopping between dyes anchored to surfaces
, CHEMICAL SCIENCE, Vol: 5, Pages: 281-290, ISSN: 2041-6520- Author Web Link
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- Citations: 59
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Journal articleHodgkiss J, Conboy G, Hutchings G, et al., 2014,
Organic photovoltaics and energy: general discussion
, FARADAY DISCUSSIONS, Vol: 174, Pages: 341-355, ISSN: 1359-6640- Author Web Link
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- Citations: 1
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Journal articleFrost JM, Kirkpatrick J, Kirchartz T, et al., 2014,
Parameter free calculation of the subgap density of states in poly(3-hexylthiophene)
, FARADAY DISCUSSIONS, Vol: 174, Pages: 255-266, ISSN: 1359-6640- Author Web Link
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- Citations: 28
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Journal articleKoch FPV, Rivnay J, Foster S, et al., 2013,
The impact of molecular weight on microstructure and charge transport in semicrystalline polymer Semiconductors poly(3-hexylthiophene), a model study
, PROGRESS IN POLYMER SCIENCE, Vol: 38, Pages: 1978-1989, ISSN: 0079-6700- Author Web Link
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- Citations: 238
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Journal articleDibb GFA, Muth M-A, Kirchartz T, et al., 2013,
Influence of doping on charge carrier collection in normal and inverted geometry polymer: fullerene solar cells
, SCIENTIFIC REPORTS, Vol: 3, ISSN: 2045-2322- Author Web Link
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- Citations: 64
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Journal articleBronstein H, Hurhangee M, Fregoso EC, et al., 2013,
Isostructural, Deeper Highest Occupied Molecular Orbital Analogues of Poly(3-hexylthiophene) for High-Open Circuit Voltage Organic Solar Cells
, CHEMISTRY OF MATERIALS, Vol: 25, Pages: 4239-4249, ISSN: 0897-4756- Author Web Link
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- Citations: 53
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Journal articleRyan JW, Kirchartz T, Viterisi A, et al., 2013,
Understanding the Effect of Donor Layer Thickness and a MoO<sub>3</sub> Hole Transport Layer on the Open-Circuit Voltage in Squaraine/C<sub>60</sub> Bilayer Solar Cells
, JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 117, Pages: 19866-19874, ISSN: 1932-7447- Author Web Link
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- Citations: 24
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Journal articleBruno A, Reynolds LX, Dyer-Snaith C, et al., 2013,
Determining the Exciton Diffusion Length in a Polyfluorene from Ultrafast Fluorescence Measurements of Polymer/Fullerene Blend Films
, JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 117, Pages: 19832-19838, ISSN: 1932-7447- Author Web Link
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- Citations: 45
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Journal articleHawks SA, Deledalle F, Yao J, et al., 2013,
Relating Recombination, Density of States, and Device Performance in an Efficient Polymer: Fullerene Organic Solar Cell Blend
, ADVANCED ENERGY MATERIALS, Vol: 3, Pages: 1201-1209, ISSN: 1614-6832- Author Web Link
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- Citations: 93
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Journal articleJames DT, Frost JM, Wade J, et al., 2013,
Controlling Microstructure of Pentacene Derivatives by Solution Processing: Impact of Structural Anisotropy on Optoelectronic Properties
, ACS NANO, Vol: 7, Pages: 7983-7991, ISSN: 1936-0851- Author Web Link
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- Citations: 84
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Journal articleNelson J, Emmott CJM, 2013,
Can solar power deliver?
, PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, Vol: 371, ISSN: 1364-503X- Author Web Link
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- Citations: 7
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Journal articleMeager I, Ashraf RS, Mollinger S, et al., 2013,
Photocurrent Enhancement from Diketopyrrolopyrrole Polymer Solar Cells through Alkyl-Chain Branching Point Manipulation
, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol: 135, Pages: 11537-11540, ISSN: 0002-7863- Author Web Link
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- Citations: 254
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Journal articleMeager I, Ashraf RS, Mollinger S, et al., 2013,
Photocurrent enhancement from diketopyrrolopyrrole polymer solar cells through alkyl-chain branching point manipulation.
, J Am Chem Soc, Vol: 135, Pages: 11537-11540Systematically moving the alkyl-chain branching position away from the polymer backbone afforded two new thieno[3,2-b]thiophene-diketopyrrolopyrrole (DPPTT-T) polymers. When used as donor materials in polymer:fullerene solar cells, efficiencies exceeding 7% were achieved without the use of processing additives. The effect of the position of the alkyl-chain branching point on the thin-film morphology was investigated using X-ray scattering techniques and the effects on the photovoltaic and charge-transport properties were also studied. For both solar cell and transistor devices, moving the branching point further from the backbone was beneficial. This is the first time that this effect has been shown to improve solar cell performance. Strong evidence is presented for changes in microstructure across the series, which is most likely the cause for the photocurrent enhancement.
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Journal articleVithanage DA, Devizis A, Abramavicius V, et al., 2013,
Visualizing charge separation in bulk heterojunction organic solar cells
, NATURE COMMUNICATIONS, Vol: 4, ISSN: 2041-1723- Author Web Link
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- Citations: 150
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Conference paperDurrant JR, Nelson J, Klug DR, 2013,
Functionalising nanocrystalline TiO<sub>2</sub> films:: dye sensitised solar cells and optical biosensors
, Materials Congress 2000, Publisher: TAYLOR & FRANCIS LTD, Pages: 1345-1348, ISSN: 0267-0836- Author Web Link
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- Citations: 16
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Journal articleKirchartz T, Deledalle F, Tuladhar PS, et al., 2013,
On the Differences between Dark and Light Ideality Factor in Polymer:Fullerene Solar Cells
, JOURNAL OF PHYSICAL CHEMISTRY LETTERS, Vol: 4, Pages: 2371-2376, ISSN: 1948-7185- Author Web Link
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- Citations: 213
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Journal articleMacKenzie RCI, Shuttle CG, Dibb GF, et al., 2013,
Interpreting the Density of States Extracted from Organic Solar Cells Using Transient Photocurrent Measurements
, JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 117, Pages: 12407-12414, ISSN: 1932-7447- Author Web Link
- Cite
- Citations: 55
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Contact
Jenny Nelson
Professor of Physics
1007, Huxley Building
South Kensington, London, SW7 2AZ