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@article{Sapsford:2019:10.1016/j.ica.2019.01.022,
author = {Sapsford, JS and Gates, SJ and Doyle, LR and Taylor, RA and Diez-Gonzalez, S and Ashley, AE},
doi = {10.1016/j.ica.2019.01.022},
journal = {Inorganica Chimica Acta},
pages = {201--207},
title = {Cp*Fe(Me2PCH2CH2PMe2)(CHO): Hydride shuttle reactivity of a thermally stable formyl complex},
url = {http://dx.doi.org/10.1016/j.ica.2019.01.022},
volume = {488},
year = {2019}
}

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TY  - JOUR
AB  - [CpFe(Me2PCH2CH2PMe2)(CO)]+ [BArF24]− has been synthesised and characterised using single crystal X-ray diffraction, NMR and IR spectroscopies. Reduction of the CO ligand using Na[Et3BH] produces the corresponding neutral formyl complex CpFe(Me2PCH2CH2PMe2)(CHO), that is very thermally stable, and which is attributed to the electron-releasing properties of the spectator ligands. This compound is a potent hydride donor which exists in equilibrium with [Et3BH]−, Et3B, and the structural isomer (η4-C5Me5H)CpFe(Me2PCH2CH2PMe2)(CO), resulting from reversible hydride migration to the Cp ligand.
AU  - Sapsford,JS
AU  - Gates,SJ
AU  - Doyle,LR
AU  - Taylor,RA
AU  - Diez-Gonzalez,S
AU  - Ashley,AE
DO  - 10.1016/j.ica.2019.01.022
EP  - 207
PY  - 2019///
SN  - 0020-1693
SP  - 201
TI  - CpFe(Me2PCH2CH2PMe2)(CHO): Hydride shuttle reactivity of a thermally stable formyl complex
T2  - Inorganica Chimica Acta
UR  - http://dx.doi.org/10.1016/j.ica.2019.01.022
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000458696800023&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - http://hdl.handle.net/10044/1/67863
VL  - 488
ER  -

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