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@article{Scott:2015:10.1021/acscatal.5b01417,
author = {Scott, DJ and Simmons, TR and Lawrence, EJ and Wildgoose, GG and Fuchter, MJ and Ashley, AE},
doi = {10.1021/acscatal.5b01417},
journal = {ACS Catalysis},
pages = {5540--5544},
title = {Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation},
url = {http://dx.doi.org/10.1021/acscatal.5b01417},
volume = {5},
year = {2015}
}

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TY  - JOUR
AB  - Despite rapid advances in the field of metal-free, “frustrated Lewis pair” (FLP)-catalyzed hydrogenation, the need for strictly anhydrous reaction conditions has hampered wide-scale uptake of this methodology. Herein, we report that, despite the generally perceived moisture sensitivity of FLPs, 1,4-dioxane solutions of B(C6F5)3 actually show appreciable moisture tolerance and can catalyze hydrogenation of a range of weakly basic substrates without the need for rigorously inert conditions. In particular, reactions can be performed directly in commercially available nonanhydrous solvents without subsequent drying or use of internal desiccants.
AU  - Scott,DJ
AU  - Simmons,TR
AU  - Lawrence,EJ
AU  - Wildgoose,GG
AU  - Fuchter,MJ
AU  - Ashley,AE
DO  - 10.1021/acscatal.5b01417
EP  - 5544
PY  - 2015///
SN  - 2155-5435
SP  - 5540
TI  - Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation
T2  - ACS Catalysis
UR  - http://dx.doi.org/10.1021/acscatal.5b01417
UR  - http://hdl.handle.net/10044/1/33837
VL  - 5
ER  -

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