Imperial College London
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DrAndyAshley

Faculty of Natural Sciences, Department of Chemistry

Honorary Lecturer
 
 
 
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Contact

 

+44 (0)20 7594 5810a.ashley Website

 
 
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Location

 

601LMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Piascik:2017:10.1039/C7CC04188H,
author = {Piascik, AD and Crawford, AD and Hill, PJ and Doyle, LR and Green, JC and Ashley, AE},
doi = {10.1039/C7CC04188H},
journal = {Chemical Communications (London)},
pages = {7657--7660},
title = {Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2)platform: structural and electronic models for an elusive firstintermediate in N2 fixation},
url = {http://dx.doi.org/10.1039/C7CC04188H},
volume = {53},
year = {2017}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The first cationic Fe silyldiazenido complexes, [Fe(PP)2(NN–SiMe3)]+[BArF4]− (PP = dmpe/depe), have been synthesised and thoroughly characterised. Computational studies show the compounds to be useful structural and electronic surrogates for the more elusive [Fe(PP)2(NN–H)]+, which are postulated intermediates in the H+/e− mediated fixation of N2 by Fe(PP)2(N2) species.
AU  - Piascik,AD
AU  - Crawford,AD
AU  - Hill,PJ
AU  - Doyle,LR
AU  - Green,JC
AU  - Ashley,AE
DO  - 10.1039/C7CC04188H
EP  - 7660
PY  - 2017///
SN  - 0009-241X
SP  - 7657
TI  - Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2)platform: structural and electronic models for an elusive firstintermediate in N2 fixation
T2  - Chemical Communications (London)
UR  - http://dx.doi.org/10.1039/C7CC04188H
UR  - http://hdl.handle.net/10044/1/49435
VL  - 53
ER  -
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