Imperial College London
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Dr Andrew Cairns

Faculty of Engineering, Department of Materials

Lecturer in Materials Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 9528a.cairns Website

 
 
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Location

 

107Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Boström:2020:10.1039/d0dt02036b,
author = {Boström, HLB and Cairns, AB and Liu, L and Lazor, P and Collings, IE},
doi = {10.1039/d0dt02036b},
journal = {Dalton Transactions: an international journal of inorganic chemistry},
pages = {12940--12944},
title = {Spin crossover in the Prussian blue analogue FePt(CN)6 induced by pressure or X-ray irradiation.},
url = {http://dx.doi.org/10.1039/d0dt02036b},
volume = {49},
year = {2020}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The spin state of the Prussian blue analogue FeIIPtIV(CN)6 is investigated in response to temperature, pressure, and X-ray irradiation. While cooling to 10 K maintains the high-spin state of FeII, compression at ambient temperature induces a first-order spin-crossover (SCO) transition with a small hysteresis loop (p↑ = 0.8 GPa, p↓ = 0.6 GPa). In addition, the high-spin to low-spin transition can be initiated at lower pressure through increased X-ray irradiation. Our study highlights a cooperative SCO with moderate pressure in a porous Prussian blue analogue.
AU  - Boström,HLB
AU  - Cairns,AB
AU  - Liu,L
AU  - Lazor,P
AU  - Collings,IE
DO  - 10.1039/d0dt02036b
EP  - 12944
PY  - 2020///
SN  - 1477-9226
SP  - 12940
TI  - Spin crossover in the Prussian blue analogue FePt(CN)6 induced by pressure or X-ray irradiation.
T2  - Dalton Transactions: an international journal of inorganic chemistry
UR  - http://dx.doi.org/10.1039/d0dt02036b
UR  - https://www.ncbi.nlm.nih.gov/pubmed/32662482
UR  - https://pubs.rsc.org/en/content/articlelanding/2020/DT/D0DT02036B#!divAbstract
UR  - http://hdl.handle.net/10044/1/82654
VL  - 49
ER  -
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