Imperial College London

Emeritus ProfessorAndrewHolmes

Faculty of Natural SciencesDepartment of Chemistry

Distinguished Research Fellow
 
 
 
//

Contact

 

+44 (0)20 7594 9286andrew.holmes Website

 
 
//

Assistant

 

Ms Maria Tortelli +44 (0)20 7594 9286

 
//

Location

 

Molecular Sciences Research HubWhite City Campus

//

Summary

 

Publications

Citation

BibTex format

@article{Xiao:2014:10.1039/c4py00827h,
author = {Xiao, Z and Subbiah, J and Sun, K and Jones, DJ and Holmes, AB and Wong, WWH},
doi = {10.1039/c4py00827h},
journal = {Polymer Chemistry},
pages = {6710--6717},
title = {Synthesis and photovoltaic properties of thieno[3,2-b]thiophenyl substituted benzo[1,2-b:4,5-b′]dithiophene copolymers},
url = {http://dx.doi.org/10.1039/c4py00827h},
volume = {5},
year = {2014}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - A new benzo[1,2-b:4,5-b′]dithiophene (BDT) building block with 4,8-disubstitution using 2-(2-ethylhexyl)-3-hexylthieno[3,2-b]thiophene as the substituent has been designed and synthesized. The new building block has been copolymerized with benzothiadiazole (BT) and 5,6-difluorobenzothiadiazole (fBT) by Suzuki and Stille coupling polymerization to synthesize donor-acceptor conjugated polymers. The optical and electrochemical properties of the synthesized copolymers were studied. Bulk heterojunction solar cells were fabricated using the donor-acceptor copolymers in conjunction with PC71BM and exhibited up to 4.20% power conversion efficiency.
AU - Xiao,Z
AU - Subbiah,J
AU - Sun,K
AU - Jones,DJ
AU - Holmes,AB
AU - Wong,WWH
DO - 10.1039/c4py00827h
EP - 6717
PY - 2014///
SN - 1759-9954
SP - 6710
TI - Synthesis and photovoltaic properties of thieno[3,2-b]thiophenyl substituted benzo[1,2-b:4,5-b′]dithiophene copolymers
T2 - Polymer Chemistry
UR - http://dx.doi.org/10.1039/c4py00827h
VL - 5
ER -