Imperial College London
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ProfessorBaptisteGault

Faculty of Engineering, Department of Materials

Professor of Atomic-Scale Characterization
 
 
 
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Contact

 

b.gault

 
 
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Location

 

Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Rivas:2020:10.1371/journal.pone.0227920,
author = {Rivas, NA and Babayigit, A and Conings, B and Schwarz, T and Sturm, A and Manjon, AG and Cojocaru-Miredin, O and Gault, B and Renner, FU},
doi = {10.1371/journal.pone.0227920},
journal = {PLoS One},
pages = {1--14},
title = {Cryo-focused ion beam preparation of perovskite based solar cells for atom probe tomography},
url = {http://dx.doi.org/10.1371/journal.pone.0227920},
volume = {15},
year = {2020}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Focused-ion beam lift-out and annular milling is the most common method used for obtaining site specific specimens for atom probe tomography (APT) experiments and transmission electron microscopy. However, one of the main limitations of this technique comes from the structural damage as well as chemical degradation caused by the beam of high-energy ions. These aspects are especially critical in highly-sensitive specimens. In this regard, ion beam milling under cryogenic conditions has been an established technique for damage mitigation. Here, we implement a cryo-focused ion beam approach to prepare specimens for APT measurements from a quadruple cation perovskite-based solar cell device with 19.7% efficiency. As opposed to room temperature FIB milling we found that cryo-milling considerably improved APT results in terms of yield and composition measurement, i.e. halide loss, both related to less defects within the APT specimen. Based on our approach we discuss the prospects of reliable atom probe measurements of perovskite based solar cell materials. An insight into the field evaporation behavior of the organic-inorganic molecules that compose the perovskite material is also given with the aim of expanding the applicability of APT experiments towards nano-characterization of complex organo-metal materials.
AU  - Rivas,NA
AU  - Babayigit,A
AU  - Conings,B
AU  - Schwarz,T
AU  - Sturm,A
AU  - Manjon,AG
AU  - Cojocaru-Miredin,O
AU  - Gault,B
AU  - Renner,FU
DO  - 10.1371/journal.pone.0227920
EP  - 14
PY  - 2020///
SN  - 1932-6203
SP  - 1
TI  - Cryo-focused ion beam preparation of perovskite based solar cells for atom probe tomography
T2  - PLoS One
UR  - http://dx.doi.org/10.1371/journal.pone.0227920
UR  - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000513141500001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb
UR  - https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0227920
UR  - http://hdl.handle.net/10044/1/104340
VL  - 15
ER  -
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