Imperial College London
Alternate

Professor Chris Braddock

Faculty of Natural Sciences, Department of Chemistry

Professor of Organic Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 5772c.braddock

 
 
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Location

 

601EMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Bahou:2020:10.1021/acs.orglett.0c00935,
author = {Bahou, K and Braddock, D and Meyer, A and Savage, GP},
doi = {10.1021/acs.orglett.0c00935},
journal = {Organic Letters},
pages = {3176--3179},
title = {Relay cross metathesis for the iterative construction of terpenoids and synthesis of a diterpene benzoate macrolide of biogenetic relevance to the bromophycolides},
url = {http://dx.doi.org/10.1021/acs.orglett.0c00935},
volume = {22},
year = {2020}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - We report a relay cross metathesis (ReXM) reaction for the construction of terpenoids in an iterative protocol. The protocol features the cross metathesis of a relay-actuated Δ6,7-functionalized C10-monoterpenoid alcohol with C10-monoterpenoid citral to form a C15-sesquiterpene. Subsequent functional group manipulation allows for the method to be repeated in an iterative fashion. The method is used for the synthesis of a diterpene-benzoate macrolide of biogenetic relevance to the bromophycolide family of natural products.
AU  - Bahou,K
AU  - Braddock,D
AU  - Meyer,A
AU  - Savage,GP
DO  - 10.1021/acs.orglett.0c00935
EP  - 3179
PY  - 2020///
SN  - 1523-7052
SP  - 3176
TI  - Relay cross metathesis for the iterative construction of terpenoids and synthesis of a diterpene benzoate macrolide of biogenetic relevance to the bromophycolides
T2  - Organic Letters
UR  - http://dx.doi.org/10.1021/acs.orglett.0c00935
UR  - http://hdl.handle.net/10044/1/79037
VL  - 22
ER  -
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