Imperial College London

ProfessorChristosMarkides

Faculty of EngineeringDepartment of Chemical Engineering

Professor of Clean Energy Technologies
 
 
 
//

Contact

 

+44 (0)20 7594 1601c.markides Website

 
 
//

Location

 

404ACE ExtensionSouth Kensington Campus

//

Summary

 

Publications

Publication Type
Year
to

265 results found

Ibrahim D, Oyewunmi O, Haslam A, Markides Cet al., COMPUTER-AIDED WORKING FLUID DESIGN AND POWER SYSTEM OPTIMIZATION USING THE SAFT-γ MIE EQUATION OF STATE, 4th Thermal and Fluids Engineering Conference (TFEC)

Conference paper

Voulgaropoulos V, Aguiar GM, Matar OK, Bucci M, Markides CNet al., Temperature and velocity field measurements of pool boiling using two-colour laser-induced fluorescence, infrared thermometry and particle image velocimetry, 10th International Conference on Multiphase Flow

We study nucleate pool boiling in water at saturation temperature and ambient pressure under low heat fluxes. A combinationof high-speed and spatially-resolved diagnostic tools are developed and applied to provide detailed insight into the flow andheat transfer mechanisms during bubble life cycle. Two fluorescent dyes with non-overlapping spectra are seeded into thewater and are excited by a Nd:YLF laser sheet at 527 nm. A two-colour laser-induced fluorescence method is employedto individually track the fluorescence of each dye by connecting two cameras, equipped with separate optical filters, to abeamsplitter and a lens. Tracer particles are also introduced in the water to perform simultaneous particle image velocimetrymeasurements. Finally, synchronised high-speed infrared thermometry is conducted to acquire the surface temperature fieldover the heater. The links between the interfacial/bubble dynamics, flow and heat transfer are investigated. Superheated liquidfrom the thermal boundary layer adjacent to the heater is displaced upwards, due to the growth and departure of the bubbles.Two counteracting vortices form on each side of the bubbles during their departure and rise, which contribute to the scavengingand mixing of the bulk water, resulting in a trail of superheated liquid below them.

Conference paper

Charogiannis A, Denner F, Van Wachem B, Benoit S, Kalliadasis S, Markides Cet al., 2018, Experimental investigations of liquid falling films flowing under an inclined planar substrate, Physical Review Fluids, Vol: 3, ISSN: 2469-990X

We report on detailed and systematic experiments of thin liquid films flowing as a result of the action of gravity under an inverted planar substrate. A measurement technique based on planar laser-induced fluorescence (PLIF) was developed and applied to a range of such flows in order to provide detailed space- and time-resolved film-height information. Specifically, the experimental campaign spanned three inclination angles (β=−15∘, −30∘, and −45∘, in all cases negative with respect to the vertical), two water-glycerol solutions (with Kapitza numbers of Ka=13.1 and 330), and flow Reynolds numbers covering the range Re=0.6–193. The collection optics were arranged so as to interrogate a spanwise section of the flow extending about 40mm symmetrically on either side the centerline of the film span (80mm in total), at a distance 330 mm downstream of the flow inlet. A range of flow regimes, typically characterized by strong three dimensionality and pronounced rivulet formation, were observed depending on the imposed inlet flow conditions. In the lower liquid Kapitza number Ka(=13.1) flows and depending on the flow Re, the free surface of the film was populated by smooth rivulets or regular sequences of solitary pulses that traveled over the rivulets. In the higher liquid Ka(=330) flows, rivulets were observed typically above Re≈30, depending also on the inclination angle, and grew in amplitude until quasi-two-dimensional fronts developed intermittently that were associated with distinct thin-film regions of varying length and frequency. These regions are of particular interest as they are expected to affect strongly the heat and mass transfer capabilities of these flows. The occurrence of the fronts was more pronounced, with higher wave frequencies, in film flows at smaller negative inclinations for the same flow Re. The rivulet amplitude was found to increase at larger inclinations for the same Re and showed a nonmonotonic trend with in

Journal article

Riverola A, Mellor A, Alvarez DA, Llin LF, Guarracino I, Markides CN, Paul D, Chemisana D, Ekins-Daukes Net al., 2018, Experimental and theoretical study of the infrared emissivity of crystalline silicon solar cells, IEEE 44th Photovoltaic Specialist Conference (PVSC), Publisher: IEEE, Pages: 1339-1341, ISSN: 0160-8371

Conference paper

Charogiannis A, Markides CN, 2018, Spatiotemporally resolved heat transfer measurements in falling liquid-films by simultaneous application of planar laser-induced fluorescence (PLIF), particle tracking velocimetry (PTV) and infrared (IR) thermography, Experimental Thermal and Fluid Science, ISSN: 0894-1777

We present an optical technique that combines simultaneous planar laser-induced fluorescence (PLIF), particle tracking velocimetry (PTV) and infrared (IR) thermography for the space-and time-resolved measurement of the film-height, 2-D velocity and 2-D free-surface temperature in liquid films falling over an inclined, resistively-heated glass substrate. Using this information and knowledge of the wall temperature, local and instantaneous heat-transfer coefficients (HTCs) and Nusselt numbers, Nu, are also recovered along the waves of liquid films with Kapitza number, , and Prandtl number, . By employing this technique, falling-film flows are investigated with Reynolds numbers in the range , wave frequencies set to , 12 and 17 Hz, and a wall heat flux set to  W cm−2. Complementary data are also collected in equivalent (i.e., for the same mean-flow Re) flows with  W cm−2. Quality assurance experiments are performed that reveal deviations of up to 2-3% between PLIF/PTV-derived film heights, interfacial/bulk velocities and flow rates, and both analytical predictions and direct measurements of flat films over a range of conditions, while IR-based temperature measurements fall within 1 °C of thermocouple measurements. Highly localized film height, velocity, flow-rate and interface-temperature data are generated along the examined wave topologies by phase/wave locked averaging. The application of a heat flux ( W cm−2) results in a pronounced “thinning” of the investigated films (by 18%, on average), while the mean bulk velocities compensate by increasing by a similar extent to conserve the imposed flow rate. The axial-velocity profiles that are obtained in the heated cases are parabolic but “fuller” compared to equivalent isothermal flows, excluding any wave-regions where the interface slopes are high. As the Re is reduced, the heating applied at the wall penetrates through the film, resulting in a pronounced coupling between th

Journal article

Sacks RE, Markides C, 2018, Compressed air energy storage – a new heat-integration, liquid-compression approach, Energy Learning

Journal article

Mellor A, Alonso Alvarez D, Guarracino I, Ramos A, Riverola Lacasta A, Ferre Llin L, Murrell A, Paul D, Chemisana D, Markides C, Ekins-Daukes NJet al., 2018, Roadmap for the next-generation of hybrid photovoltaic-thermal solar energy collectors, Solar Energy, Vol: 174, Pages: 386-398, ISSN: 0038-092X

For hybrid photovoltaic-thermal collectors to become competitive with other types of solar energy converters, they must offer high performance at fluid outlet temperatures above 60 °C, as is required for space heating and domestic hot water provision, which together account for nearly 50% of heat demand. A roadmap is presented of the technological advances required to achieve this goal. Strategies for reducing convective, radiative and electrical losses at elevated temperature are discussed, and an experimental characterisation of a novel transparent low-emissivity coating for photovoltaic solar cells is presented. An experimentally-validated simulation formalism is used to project the performance of different combinations of loss-reduction strategies implemented together. Finally, a techno-economic analysis is performed to predict the price points at which the hybrid technologies along the roadmap become competitive with non-hybrid photovoltaic and solar thermal technologies. The most advanced hybrid technology along the roadmap employs an evacuated cavity, a transparent low-emissivity coating, and silicon heterojunction photovoltaic cells.

Journal article

Herrando M, Ramos A, Freeman J, Zabalza I, Markides CN, Herrando M, Ramos A, Freeman J, Zabalza I, Markides Cet al., 2018, Technoeconomic modelling and optimisation of solar combined heat and power systems based on flat-box PVT collectors for domestic applications, Energy Conversion and Management, Vol: 175, Pages: 67-85, ISSN: 0196-8904

We investigate solar combined heat and power (S-CHP) systems based on hybrid photovoltaic-thermal (PVT) collectors for the simultaneous provision of domestic hot water (DHW), space heating (SH) and power to single- family homes. The systems include PVT collectors with a polycarbonate flat-box structure design, a water storage tank, an auxiliary heater and a battery storage subsystem. A methodology is developed for modelling the en- ergetic and economic performance of such PVT-based S-CHP systems, which is used to optimally size and operate systems for covering the energy demands of single-family reference households at three selected locations: Athens (Greece), London (UK) and Zaragoza (Spain). The results show that optimised systems are capable of covering ∼65% of the annual household electricity demands in Athens, London and Zaragoza when employing 14.0, 17.0 and 12.4 m2 collector array areas respectively, while also covering a significant fraction of the thermal energy demands in Athens (∼60%) and Zaragoza (∼45%); even in London, almost 30% of the reference household’s thermal demand is covered by such a system. A corresponding economic analysis reveals that, despite the suitability of Athens’ weather conditions for implementing such solar-energy systems, the payback time (PBT) of the optimised S-CHP system in Athens is 15.6 years in contrast to the 11.6 years predicted for Zaragoza, due to the lower electricity prices in Greece. On the other hand, the high carbon emission factor of the electricity grid in Greece makes these systems particularly promising at this location. Specifically, the in- vestigated systems have the potential to displace 3.87, 1.65 and 1.54 tons of CO2 per year in Athens, London and Zaragoza, when substituting the conventional means for household energy provision (i.e. grid electricity and gas- fired boilers). Furthermore, it is demonstrated that the optimised systems outperform benchmark equivalent systems comprisin

Journal article

White M, Oyewunmi OA, Chatzopoulou M, Pantaleo AM, Haslam A, Markides Cet al., 2018, Computer-aided working-fluid design, thermodynamic optimisation and technoeconomic assessment of ORC systems for waste-heat recovery, Energy, Vol: 161, Pages: 1181-1198, ISSN: 0360-5442

The wider adoption of organic Rankine cycle (ORC) technology for power generation or cogeneration from renewable or recovered waste-heat in many applications can be facilitated by improved thermodynamic performance, but also reduced investment costs. In this context, it is suggested that the further development of ORC power systems should be guided by combined thermoeconomic assessments that can capture directly the trade-offs between performace and cost with the aim of proposing solutions with high resource-use efficiency and, importantly, improved economic viability. This paper couples, for the first time, the computer-aided molecular design (CAMD) of the ORC working-fluid based on the statistical associating fluid theory (SAFT)-γ Mie equation of state with thermodynamic modelling and optimisation, in addition to heat-exchanger sizing models, component cost correlations and thermoeconomic assessments. The resulting CAMD-ORC framework presents a novel and powerful approach with extended capabilities that allows the thermodynamic optimisation of the ORC system and working fluid to be performed in a single step, thus removing subjective and pre-emptive screening criteria that exist in conventional approaches, while also extending to include cost considerations relating to the resulting optimal systems. Following validation, the proposed framework is used to identify optimal cycles and working fluids over a wide range of conditions characterised by three different heat-source cases with temperatures of 150 °C, 250 °C and 350 °C, corresponding to small- to medium-scale applications. In each case, the optimal combination of ORC system design and working fluid is identified, and the corresponding capital costs are evaluated. It is found that fluids with low specific-investment costs (SIC) are different to those that maximise the power output. The fluids with the lowest SIC are isoheptane, 2-pentene and 2-heptene, with SICs of £5620, £2760 an

Journal article

Ramos A, Chatzopoulou MA, Freeman J, Markides Cet al., 2018, Optimisation of a high-efficiency solar-driven organic Rankine cycle for applications in the built environment, Applied Energy, Vol: 228, Pages: 755-765, ISSN: 0306-2619

Energy security, pollution and sustainability are major challenges presently facing the international community, in response to which increasing quantities of renewable energy are to be generated in the urban environment. Consequently, recent years have seen a strong increase in the uptake of solar technologies in the building sector. In this work, the potential of a solar combined heat and power (CHP) system based on an organic Rankine cycle (ORC) engine is investigated in a domestic setting. Unlike previous studies that focus on the optimisation of the ORC subsystem, this study performs a complete system optimisation considering both the design parameters of the solar collector array and the ORC engine simultaneously. Firstly, we present thermodynamic models of different collectors, including flat-plate and evacuated-tube designs, coupled to a non-recuperative sub-critical ORC architecture that delivers power and hot water by using thermal energy rejected from the engine. Optimisation of the complete system is first conducted, aimed at identifying operating conditions for which the power output is maximised. Then, hourly dynamic simulations of the optimised system configurations are performed to complete the system sizing. Results are presented of: (i) dynamic 3-D simulations of the solar collectors together with a thermal energy storage tank, and (ii) of an optimisation analysis to identify the most suitable working fluids for the ORC engine, in which the configuration and operational constraints of the collector array are considered. The best performing working fluids (R245fa and R1233zd) are then chosen for a whole-system annual simulation in a southern European climate. The system configuration combining an evacuated-tube collector array and an ORC engine is found to be best-suited for electricity prioritisation, delivering an electrical output of 3,605 kWh/year from a 60 m2 collector array. In addition, the system supplies 13,175 kWh/year in the form of domes

Journal article

Wang Y, Markides CN, Chachuat B, 2018, Optimization-based investigations of a thermofluidic engine for low-grade heat recovery, IFAC-PapersOnLine, Vol: 51, Pages: 690-695, ISSN: 2405-8963

This paper presents an analysis of the non-inertive-feedback thermofluidic engine (NIFTE) under cyclic steady-state conditions. The analysis is based on a nonlinear model of NIFTE that had previously been validated experimentally, and applies an optimization-based approach to detect the cyclic steady states (CSS). The stability of the CSS is furthermore determined by analyzing their monodromy matrix. It is found that NIFTE can exhibit multiple CSS for certain values of the design parameters, which may be either stable or unstable, a result that had not been reported before. Subsequently, a parametric study is conducted by varying key design parameters, revealing that higher efficiencies could be achieved by controlling the engine at different CSS, including unstable ones. Lastly, the paper investigates the trade-offs between efficiency and work output in NIFTE.

Journal article

McTigue JD, Markides C, White AJ, 2018, Performance response of packed-bed thermal storage to cycle duration perturbations, Journal of Energy Storage, Vol: 19, Pages: 379-392, ISSN: 2352-152X

Packed-bed thermal stores are integral components in numerous bulk electricity storage systems and may also be integrated into renewable generation and process heat systems. In such applications, the store may undergo charging and discharging periods of irregular durations. Previous work has typically concentrated on the initial charging cycles, or on steady-state cyclic operation. Understanding the impact of unpredictable charging periods on the storage behavior is necessary to improve design and operation. In this article, the influence of the cycle duration (or ‘partial-charge’ cycles) on the performance of such thermal stores is investigated. The response to perturbations is explained and provides a framework for understanding the response to realistic load cycles.The packed beds considered here have a rock filler material and air as the heat transfer fluid. The thermodynamic model is based on a modified form of the Schumann equations. Major sources of exergy loss are described, and the various irreversibility generating mechanisms are quantified.It is known that repeated charge-discharge cycles lead to steady-state behavior, which exhibits a trade-off between round-trip efficiency and stored exergy, and the underlying reasons for this are described. The steady state is then perturbed by cycles with a different duration. Short duration perturbations lead to a transient decrease in exergy losses, while longer perturbations increase it. The magnitude of the change in losses is related to the perturbation size and initial cycle period, but changes of 1–10 % are typical. The perturbations also affect the time to return to a steady-state, which may take up to 50 cycles. Segmenting the packed bed into layers reduces the effect of the perturbations, particularly short durations.Operational guidelines are developed, and it is found that packed beds are more resilient to changes in available energy if the store is not suddenly over-charged (i.e. longer

Journal article

Georgiou S, Aunedi M, Strbac G, Markides Cet al., 2018, Application of liquid-air and pumped-thermal electricity storage systems in low-carbon electricity systems, Heat Powered Cycles - HPC-2018

In this study, we considertwo medium-to large-scale electricity storage systems currently under development, namely ‘Liquid-Air Energy Storage’ (LAES) and ‘Pumped-Thermal Electricity Storage’ (PTES). Consistent thermodynamic models and costing methodologies for the twosystems are presented,with the objective of integrating the characteristics of these technologies intoa whole-electricity system assessment model,andassessingtheirsystem-levelvalue in different scenarios for power system decarbonisation.It is found that the value of storage variesgreatlydepending on the cumulative installed capacity of storage in the electrical system, withthe storage technologies providinggreater marginal benefits at low penetrations. Two carbon target scenarios showed similar results, with a limited effect of the carbon target on the system value of storage (althoughit is noted thatthis may change for even more ambitious carbon targets). On the other hand, the location and installed capacity of storage plants isfound to have a significantimpact on the system value and acceptable cost of thesetechnologies. The whole-system value of PTES was foundto be slightly higher than that of LAES, driven by a higher storage duration and efficiency,however, due to the higher power capital cost of PTES, this becomes less attractive for implementation at lower volumes than LAES.

Conference paper

Wang K, Herrando M, Pantaleo AM, Markides CNet al., 2018, Thermodynamic and economic assessments of a hybrid PVT-ORC combined heating and power system for swimming pools, Heat Powered Cycles Conference 2018

The thermodynamic and economicperformance of a solar combined heatand power(S-CHP) system based on an array of hybrid photovoltaic-thermal (PVT) collectorsandan organic Rankine cycle (ORC)engineis considered for the provision of heating and power to swimming poolfacilities. Priority is given to meeting the thermaldemand of the swimming pool,in order to ensure a comfortable condition for swimmers in colderweather conditions, while excessthermal output from the collectorsat highertemperatures is converted toelectricityby the ORC engine inwarmerweather conditions. The thermodynamic performance of this system and its dynamic characteristicsare analysed on the basis of a transient thermodynamic model. Various heat losses and gains are considered in accordance toenvironmental and user-relatedfactorsfor both indoor and outdoor swimming pools. A case study is then performed for the swimming pool atthe UniversitySportCentre (USC)of Bari, Italy. The results show thatemployinga zeotropic mixture of R245fa/R227ea (30/70%) as the ORC working fluidallows such an ORC systemto generate~50% more power than when usingpure R236eadue to the better temperature matchof the cycle tothe low-temperature hot-water heat sourcefrom the output of the PVT collectors.Apart from generatingelectricity, the ORC enginealso alleviatesPVT collectoroverheating,and reducesthe required size of the hot-water storage tank. With an installation of 2000 m2of PVT collectors, energetic analysesindicate that the proposedS-CHP systemcan cover 84-96% of the thermal demand of the swimming pool during the warm summer months and 61% of itsannually integratedtotal thermal demand. In addition, the system produces a combined (from thecollectors andORC engine) of 328 MWhofelectricityper year, corresponding to 36% of the total electricity demand of the USC, with ~4% coming from the ORC engine.Theanalysis suggestsa minimum payback time of 12.7yearswith anopt

Conference paper

Georgiou S, Shah N, Markides C, 2018, A thermo-economic analysis and comparison of pumped-thermal and liquid-air electricity storage systems, Applied Energy, Vol: 226, Pages: 1119-1133, ISSN: 0306-2619

Efficient and affordable electricitystorage systemshave a significant potential tosupport thegrowth and increasingpenetration of intermittent renewable-energy generationinto the gridfrom an energy system planning and management perspective,whiledifferencesin the demand and price ofpeak and off-peak electricity can make its storage of economicinterest. Technical (e.g.,roundtrip efficiency,energy andpower capacity)as well aseconomic (e.g.,capital, operating and maintenance costs)indicators are anticipatedto have a significantcombined impact on the competitiveness of anyelectricity storage technology or systemunder considerationand, ultimately, will cruciallydetermine their uptake and implementation.In this paper,we present thermo-economicmodels of two recentlyproposedmedium-to large-scale electricity storage systems, namely ‘Pumped-Thermal Electricity Storage’ (PTES) and ‘Liquid-Air Energy Storage’ (LAES), focusing on system efficiency and costs. The LAESthermodynamic model isvalidated against datafrom anoperationalpilot plant in the UK; no such equivalent PTES plant exists, although one is currently underconstruction. Ascommonwith most newly proposedtechnologies, the absenceof cost dataresults tothe economic analysis and comparisonbeinga significant challenge.Therefore, acosting effort for the two electricity storage systems that includes multiple costing approaches based on the module costing technique is presented,with the overriding aim of conducting a preliminary economic feasibility assessment and comparison of the two systems. Based on the results, it appears that PTES has the potential to achievehigher roundtrip efficiencies,althoughthis remains to be demonstrated. LAESperformance isfound to be significantly enhanced through the integration and utilisation of waste heat (and cold)streams.In terms of economicson the other hand,and at the

Journal article

Chatzopoulou MA, Markides C, 2018, Thermodynamic optimisation of a high-electrical efficiency integrated internal combustion engine – organic Rankine cycle combined heat and power system, Applied Energy, Vol: 226, Pages: 1229-1251, ISSN: 0306-2619

Organic Rankine cycle (ORC) engines are suitable for heat recovery from internal combustion engines (ICE) in combined heat and power (CHP) systems. However, trade-offs must be considered between ICE andORC engine performance in such integrated solutions. The ICE design and operational characteristics influence its own performance along withthe exhaust-gas conditions available as heat source to the ORC engine, impacting ORC design and performance, while the heat-recovery heat exchanger (ORC evaporator) will affect the ICE operation. In this paper, an integrated ICE-ORC CHP whole-system optimisation framework is presented. This differs from other efforts in that we develop and apply a fully-integrated ICE-ORC CHP optimisation framework, considering the design and operation of both the ICE and ORC enginessimultaneously within the combined system, to optimise the overall system performance. A dynamic ICE model is developed and validated, along with a steady-state model of subcritical recuperative ORC engines. Both naturally aspirated and turbocharged ICEs are considered, of two different sizes/capacities. Nine substances (covering low-GWP refrigerants and hydrocarbons) are investigated as potential ORC working fluids. The integrated ICE-ORC CHP system isoptimised for eithermaximum total power output, or minimum fuel consumption. Resultshighlight that by optimising the complete integrated ICE-ORC CHP system simultaneously, the total power output increases by up to 30% in comparison to a nominal system design. In the integrated CHP system,the ICE power output is slightly lower than that obtained for optimal standalone ICE application, as the exhaust-gas temperature increases to promote the bottoming ORC engine performance, whose power increasesby 7%. The ORC power output achieved accounts for up to 15% of the total power generated by the integrated system, increasing the system efficiency by up to 11%. When only power optimisation is performed, the

Journal article

White MT, Markides CN, Sayma AI, 2018, Working-Fluid Replacement in Supersonic Organic Rankine Cycle Turbines, JOURNAL OF ENGINEERING FOR GAS TURBINES AND POWER-TRANSACTIONS OF THE ASME, Vol: 140, ISSN: 0742-4795

Journal article

Pantaleo AM, de palma P, Fordham J, Oyewumni O, Markides CNet al., 2018, Integrating cogeneration and intermittent waste-heat recovery in food processing: Microturbines vs. ORC systems in the coffee roasting industry, Applied Energy, Vol: 225, Pages: 782-796, ISSN: 0306-2619

Coffee roasting is a highly energy intensive process wherein a large quantity of heat is discharged from the stack at medium-to-high temperatures. Much of the heat is released from the afterburner, which is required to remove volatile organic compounds and other pollutants from the flue gases. In this work, intermittent waste-heat recovery via thermal energy storage (TES) and organic Rankine cycles (ORCs) is compared to combined heat and power (CHP) based on micro gas-turbines (MGTs) for a coffee roasting plant. With regard to the former, a promising solution is proposed that involves recovering waste heat from the flue gas stream by partial hot-gas recycling at the rotating drum coffee roaster, and coupling this to a thermal store and an ORC engine for power generation. The two solutions (CHP + MGT prime mover vs. waste-heat recovery + ORC engine) are investigated based on mass and energy balances, and a cost assessment methodology is adopted to compare the profitability of three system configurations integrated into the selected roasting process. The case study involves a major Italian roasting plant with a 500 kg per hour coffee production capacity. Three options are investigated: (i) intermittent waste-heat recovery from the hot flue-gases with an ORC engine coupled to a TES system; (ii) regenerative topping MGT coupled to the existing modulating gas burner to generate hot air for the roasting process; and (iii) non-regenerative topping MGT with direct recovery of the turbine outlet air for the roasting process. The results show that the profitability of these investments is highly influenced by the natural gas and electricity prices and by the coffee roasting production capacity. The CHP solution via an MGT appears as a more profitable option than waste-heat recovery via an ORC engine primarily due to the intermittency of the heat-source availability and the high electricity cost relative to the cost of natural gas.

Journal article

Sorrentino A, Pantaleo AM, Markides C, Braccio G, Fanelli E, Camporeale Set al., Energy performance and profitability of biomass boilers in commercial sector: the case study of Sainsbury’s stores in the UK, 73rd Conference of the Italian Thermal Machines Engineering Association (ATI 2018), Publisher: Elsevier, ISSN: 1876-6102

Commercial buildings or shopping malls are characterized by large thermal and electrical energy consumptions with high variability of energy demand. Therefore, there is a large interest to explore novel renewable energy generation systems for these applications. A novel flexible configuration of biomass-fired CHP system with organic Rankine cycle(ORC) is here proposedand applied to the case study of Sainsbury’s supermarkets in the UK.The proposed configuration adoptsa molten salt (MS) circuitto transfer heat from the biomass furnace to the ORC plant. A thermal Energy Storage (TES) is proposedtoimprove the flexible operation of the plantand reduce the size of the biomass boiler. Molten salts have been preferredto thermal oil as they have no fire risks and low environmental impactand can be used as medium for a Two Tank TES with a “direct heating” scheme. The planthas beenanalysedusing real input data of biomass boiler installed, conversion efficiency and heat demand from the store. The model is informed by hourly energy costs and electricity feed in tariff in order to define optimal size and operation of the bottoming ORC for the specific case study of large commercial energy end userin the UK.The results show that the use of thermal storage in a biomass-fired ORC plant can improve the boiler efficiency and reduce the biomass consumption in thermal-load following operating mode and increase the investment profitability.

Conference paper

Pantaleo AM, Camporeale S, Sorrentino A, Miliozzi A, Shah N, Markides Cet al., 2018, Hybrid solar-biomass combined Brayton/organic Rankine-cycle plants integrated with thermal storage: Techno-economic feasibility in select Mediterranean areas, Renewable Energy, ISSN: 1879-0682

This paper presents a thermodynamic analysis and techno-economic assessment of a novel hybrid solar-biomass power-generation system configuration composed of an externally fired gas-turbine (EFGT) fuelled by biomass (wood chips) and a bottoming organic Rankine cycle (ORC) plant. The main novelty is related to the heat recovery from the exhaust gases of the EFGT via thermal energy storage (TES), and integration of heat from a parabolic-trough collectors (PTCs) field with molten salts as a heat-transfer fluid (HTF). The presence of a TES between the topping and bottoming cycles facilitates the flexible operation of the system, allows the system to compensate for solar energy input fluctuations, and increases capacity factor and dispatchability. A TES with two molten salt tanks (one cold at 200 °C and one hot at 370 °C) is chosen. The selected bottoming ORC is a superheated recuperative cycle suitable for heat conversion in the operating temperature range of the TES. The whole system is modelled by means of a Python-based software code, and three locations in the Mediterranean area are assumed in order to perform energy-yield analyses: Marseille in France, Priolo Gargallo in Italy and Rabat in Morocco. In each case, the thermal storage that minimizes the levelized cost of energy (LCE) is selected on the basis of the estimated solar radiation and CSP size. The results of the thermodynamic simulations, capital and operational costs assessments and subsidies (feed-in tariffs for biomass and solar electricity available in the Italian framework), allow estimating the global energy conversion efficiency and the investment profitability in the three locations. Sensitivity analyses of the biomass costs, size of PTCs, feed-in tariff and share of cogenerated heat delivered to the load are also performed. The results show that the high investment costs of the CSP section in the proposed size range and hybridization configuration allow investment profitability only in the

Journal article

Georgiou S, Acha S, Shah N, Markides C, Georgiou S, Acha S, Shah N, Markides Cet al., 2018, A generic tool for quantifying the energy requirements of glasshouse food production, Journal of Cleaner Production, Vol: 191, Pages: 384-399, ISSN: 0959-6526

Quantifying the use of resources in food production and its environmental impact is key to identifying distinctive measures which can be used to develop pathways towards low-carbon food systems. In this paper, a first-principle modelling approach is developed, referred to as gThermaR (Glasshouse-Thermal Requirements). gThermaR is a generic tool that focuses on the energy requirements of protected heated production, by integrating holistic energy, carbon, and cost modelling, food production, data analytics and visualization. The gThermaR tool employs historic data from weather stations, growing schedules and requirements specific to grower and product needs (e.g. set-point temperatures, heating periods, etc.) in order to quantify the heating and cooling requirements of glasshouse food production. In the present paper, a case study is reported that employs a database compiled for the UK. Another relevant feature of the tool is that it can quantify the effects that spatial and annual weather trends can have on these heating and cooling requirements. The main contribution of this work, therefore, concerns the development a tool that can provide a simple integrated approach for performing a wide range of analyses relevant to the thermal requirements of heated glasshouses. The tool is validated through collaborations with industrial partners and showcased in a case study of a heated glasshouse in the UK, offering the capacity to benchmark and compare different glasshouse types and food growth processes. Results from the case study indicate that a significant reduction in the heating requirement and, therefore, carbon footprint, of the facility can be achieved by improving key design and operational parameters. Results indicate savings in the peak daily and annual heating requirements of 44-50% and 51-57% respectively, depending on the region where the glasshouse is located. This improvement is also reflected in the carbon emissions and operating costs for the different en

Journal article

Wright SF, Charogiannis A, Voulgaropoulos V, Matar OK, Markides CNet al., 2018, Laser-based measurements of stratified liquid-liquid pipe flows interacting with jets in cross-flow, 19th International Symposium on the Application of Laser and Imaging Techniques to Fluid Mechanics

At low velocities, horizontal liquid-liquid flows uder go gravitation ally-induced stratification, which in many practical applications complicatessignificantly the direct measurement of the average properties of theflow. The extent of flow stratification, however, can be limited through in line mixing leading to the formation of liquid-liquid dispersions withmore homogenous properties. In this work, we focus on the use of‘active’ mixing methods using jets in cross flows (JICFs). In this paper,a dedicated experimental flow facility for the investigation of such flowsis presented, along with the accompanying laser-based optical measurement techniques and associated algorithms that have beendeveloped for this investigation. The facility allows simultaneous,space-and time-resolved phase and velocity information to be generatedvia plan ar laser-induced fluorescence (PLIF) and particle velocimetry(PIV/ PTV), with stereo-PIV used to provide information on the third (out-of-plane) velocity component. Preliminary experimental results arepresented which demonstrate the capabilities of this arrangementfor optically examining stratified liquid-liquid flows interacting withJICFs, leading to new insights into these complex flows. The key resultsinclude phenomena of jets interacting with the liquid-liquid inter face,recirculation zones that lead to further mixing, the presence of complexcompound droplets, droplet size distributions, and water concentrationprofiles.

Conference paper

Georgiou S, Shah N, Markides C, Potential for Carbon Savings from the Deployment of Liquid-Air and Pumped-Thermal Electricity Storage Systems, Offshore Energy and Storage 2018

Conference paper

Herrando M, Pantaleo AM, Wang K, Markides Cet al., Technoeconomic assessment of a PVT-based solar combined cooling heating and power (S-CCHP) system for the university campus of Bari, 13th Conference on Sustainable Development of Energy, Water and Environment Systems - SDEWES Conference, Publisher: SEDWES

In thiswork weanalyse the year-round technoeconomicperformance of a solar combined cooling, heating and power (S-CCHP)system that features polymeric flat-box PVT collectorscoupled via a thermal store to an absorptionchiller. The hourly space heating (SH), cooling and electricitydemands of the University Campus of Bari are used as inputs to amodeldeveloped in TRNSYS.Current electricity and gas prices are considered in order to estimate the annual cost savings which, together with the system’s investment cost, allow an estimation of itspayback time (PBT). The results are then compared to a PV systemthat matchesthe electricity demand of the Campus (including the electricity required to run the current HVAC system for air-conditioning).The results show that the main limiting factorfor the implementationof the S-CCHP systemis the roof-space availability in this application. Asystem with aninstalled power of 1.68MWpcan cover14% of the SH, 66% of the cooling and 17% oftheelectricaldemands of the Campus. The system’s PBTis estimated at 19.3years, which is 3 times higher than the PBTof a PV system of the same installed power, nevertheless,the proposed S-CCHPsystemhas the potential to displace 1,170tons CO2/year, or 50% more than theequivalentPV solution.

Conference paper

Chatzopoulou MA, Lecompte S, De Paepe M, Markides Cet al., Off-design operation of ORC engines with different heat exchanger architectures in waste heat recovery applications, ICAE2018 - 10th International Conference on Applied Energy, Publisher: Elsevier, ISSN: 1876-6102

Organic Rankine cycle(ORC)engines in waste-heat recovery applications experience variable heat-source conditions (i.e. temperature and mass flow ratevariations). Therefore maximisingthe ORC system performance under off-design conditions is of key importance, for the financial viability and wider adoption of these systems. In this paper,the off-design performance of an ORC engineis investigated, with screw expander andtwoheat exchanger (HEXs)architectures, while recovering heat from an internal combustion engine (ICE).Unlike previous studieswhere the ORC expanderand HEXsperformance is assumed fixed duringoff-design operation, in this work we consider the time-varying characteristics of the system components.Firstly, nominal system sizing results indicate that the screw expander isentropic efficiency exceeds 80%,whilethe plate HEXs (PHEXs) heat transferarea requirements are 50% lower,than the respective ones for double pipe (DPHEX) design. Next, the ORC engine operation is optimised at part-load (PL) ICE conditions.Although, the HEXs heat transfer coefficients decrease by 30% with part-load, the HEX effectiveness increasesby up to 20%, due to higher temperature difference across the working fluids.Findingsalso reveal that the PHEX performance is less sensitive to the off-design operation. Optimum off-design power output maps indicatethattheORC enginePL reduces to 72%, for ICE PL of 60%, while ORCengines with PHEXsgenerate slightlymore power,for the same heat source conditions. Overall, the modelling tool developed predictsthe ORC performance over an operating envelope and allows the selection of optimal designs and sizes of ORC HEXsand expanders.The findings can be used by ORC plant operators to optimise the ORC engine power output, given the varying heat source conditions observed on their site,and by ORC vendors to inform HEX andexpander design decisions.

Conference paper

van Kleef LMT, Oyewunmi OA, Harraz AA, Haslam AJ, Markides CNet al., 2018, Case studies in computer-aided molecular design (CAMD) of low- and medium-grade waste-heat recovery ORC systems, ECOS 2018 - 31st International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, Publisher: ECOS

Organic Rankine cycle (ORC) engines are suitable for theconversion oflow-grade heat into useful power. While numerous substances are available asORC working-fluid candidates, computer-aided molecular design (CAMD) techniques allow the rigorous selection of an optimal working fluid during system optimisation. The aim of this present study is to extend an existing CAMD-ORC framework [1,2] by incorporating, in addition to thermodynamic performance objectives, economic objectives when determining the optimal systemdesign, while maintaining the facility of selecting optimal working fluids. The SAFT-γ Mie equation of state is used to predictthethermodynamic properties of theworking fluids(here, hydrocarbons)that are relevant to the systems’economic appraisalsand critical/transport properties are estimated using empirical group-contribution methods. System investment costs are estimated with equipment cost correlations for the key system components, andthe stochastic NSGA-II solver is used for system optimisation. From a set of NLP optimisations, it is concluded that the optimal molecular size of the working fluid is linked to the heat-source temperature. The optimal specific investment cost (SIC) values were £10,120/kW and£4,040/kW when using heat-source inlet temperatures of 150°Cand250°C (representative of low-and medium-gradeheat) respectively, andthe corresponding optimal working fluids were propane, 2-butane and 2-heptene.

Conference paper

Simpson M, Pantaleo AM, De Palma P, Markides Cet al., 2018, Design and thermo-economic optimisation of small-scale bottoming ORC systems coupled to biomass CHP gasification cycles, ECOS 2018 - 31st International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems., Publisher: ECOS

Optimisation of a small-scale bottoming organic Rankine cycle (ORC) engine is carried out for a combined biomass-gasifier-CHP system, drawing heat from the syngas conditioning unit of the gasifier and the exhaust gas of the internal combustion(IC) engine. The optimisation considers different working fluids and selection of a positive-displacement expander. Single-and two-stage screw expanders and single-stage reciprocating-piston expanders are modelled in order to capture the variation in their performance at a range of design points.Double-pipe heat exchangers are employed for both evaporator and condenser, leading to a low-cost but bulky design.The system is optimised first for maximum electrical power output, and second for minimum specific investment cost(SIC). Cost correlations are used for each of the principal ORC components. The optimal design for minimum SIC is found to be a two-stage screw expander withethanol as the working fluid, which produces a 13.6% increase in the electrical power output relative to the system without an ORC.The investment attractiveness of the whole system with and without the bottoming ORC is assessed and the system is found tobe profitable for avoided electricity costs above 150 $/MWheland biomass costs of 50 $/t, with the ORC making the system more attractive in all cases studied.Discounted payback periods range from 12years at 150 $/MWhelto 3.5years at 250 $/MWhelforthe system with ORC.

Conference paper

Pantaleo AM, Camporeale S, Sorrentino A, Braccio G, Markides Cet al., 2018, Distributed heat and power generation: thermoeconomic analysis of Biomass-fired Rankine cycle systems with molten salts as heat transfer fluid, The 31st International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, Publisher: ECOS

Distributed cogeneration systems can be used to serve onsite energy demands in industrial and commercial buildings. In market segments with highly variable heat-demand patterns, the thermal plant is often composed of a boiler that is operated at part load in case of low thermal demands. To improve the plant flexibility and its overall energy efficiency, the biomass boiler can be coupled to a combined heat and power (CHP) generation system, as an alternative to a heat-only plant. In this work, three thermodynamic configurations are compared: (A) a biomass furnace that acts as a heat-source for a steam Rankine cycle (ST) plant coupled to an organic Rankine cycle (ORC) engine; (B) the same as Case A but without the bottoming ORC; and (C): the same as Case A but without the steam cycle. All configurations assume the cogeneration of heat and power to match onsite energy demands. The plant adopts a molten salt (MS) circuit to transfer heat from the biomass furnace to the power generation system. The energy analysis assumes a ternary MS mixture operating up to 450 °C and with minimum temperature of 200 °C. Two organic fluids (Pentafluoropropane R245fa and Toluene) are considered, based on the temperature of heat available to the ORC engine. In the combined cycle of Case A, R245fa is selected and the maximum cycle temperature is 130 °C, with a global electrical efficiency of 16.6%. In Case C, when only the ORC system is used with Toluene as the working fluid, the electrical efficiency is 18.8% at the higher turbine inlet temperature of 330 °C. Production of hot water for cogeneration at different temperature levels is also considered. Based on the results of the thermodynamic simulations, upfront and operational costs assessments, and feed-in tariffs for renewable electricity, energy efficiency and investment profitability are estimated.

Conference paper

Chatzopoulou MA, Sapin P, Markides C, Chatzopoulou MA, Sapin P, Markides Cet al., 2018, Optimisation of off-design internal combustion-organic Rankine engine combined cycles, ECOS 2018 - 31st International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, Publisher: ECOS

Organic Rankine cycle (ORC) enginesare an efficient means of convertinglow-to-medium renewable orwaste heat to useful power. In practicalapplications, ORC systemsexperience varying thermalinputprofile,due to the dynamic nature of realheat sources. Maximisingthe uptake of this technology requiresoptimisedORC designsand sizing tomaintain high efficiencyand power output,not only at full-load operation, but also under off-design conditions. Key for maintaining the efficient operationof the systemis the maximisation of heat extraction from the heat source, inthe ORC evaporator. In this paper, the off-design operation of an ICE-ORC combined heat and power (CHP) system is investigated, to optimise the ORC performance under varying ICE load conditions. First, the ORC enginethermodynamic design is optimised for the 100% load operation of the ICE. Alternative working fluids are investigated, including low ODP/GWP refrigerants and hydrocarbons. The ORC system is then sized using two different heat exchanger (HEX) architectures; tube-in-tube (DPHEX) and plate (PHEX) designs, at designconditions. The sizing results reveal that the PHEX area requirements are almost 50% lower than the respective ones for DPHEX, while recovering equivalent quantities of heat. Next, the ORC engine operation is optimised atpart-load ICE conditions, and the HEX heat transfer coefficients (HTCs) are predicted. Results indicate that: i) PHEX HTCs are up to 50% higher than DPHEX equivalents;ii)HTCsdecreaseat part load for both HEXs, but because the average temperaturedifferenceincreases, the overall HEX effectiveness improves; and iii) the ORC system with a PHEX evaporator has slightly higher power output thanthe DPHEX equivalent at off-design operation.Overall, the modelling tool developed here can predict ORC performance over an operating envelopeand allows the selection ofoptimal designsand si

Conference paper

Najjaran Kheirabadi A, Harraz AA, Freeman J, Mac Dowell N, Markides CNet al., 2018, Numerical and experimental investigations of diffusion absorption refrigeration systems for use with low temperature heat sources, ECOS 2018 - 31st International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, Publisher: ECOS

he diffusion absorption refrigeration (DAR) cycle is a technology of increasing interest thanks to its suitabilityfor providing cooling from a thermal energyinputin a range of applications. Itcan bedistinguished from other absorption refrigeration cycles by its employment of a thermally-driven bubble pump to circulate the working fluid, which gives it anability to operate entirely off-gridwithout an electricity input. In this work,we present results from an experimentalcampaign aimed atcharacterisingthe performance of aprototypeammonia-water-hydrogen DAR system with a nominal cooling capacity of 100 W,over a range of operating conditions, specifically with a view ofadaptingthe system for use in low-temperature applications. In the experiments, the heat input to the DAR generator is provided over a range of temperatures from175to215°Cby using electrical cartridge heaters. The system is charged to 22 bar, and the ammonia mass concentration of the working fluid mixture is 30%. The resulting coefficient of performance (COP) of the system is measured in the range 0.12to 0.26. A new methodology for the selection of optimal working-fluid mixtures using the state-of-the-art, statistical associating fluid theory (SAFT) approach implemented within the process modelling software gPROMS®is also presented. The experimental results will be used for futurevalidation of a thermodynamic model of the cycle. Finally,the performance of the system in a solar application is investigated, with a thermal inputprovided by an array of evacuated tube heat pipe solar collectors. The system pressure and condensation temperature are found to be key factors in determining the performance of solar-DAR systems.

Conference paper

This data is extracted from the Web of Science and reproduced under a licence from Thomson Reuters. You may not copy or re-distribute this data in whole or in part without the written consent of the Science business of Thomson Reuters.

Request URL: http://wlsprd.imperial.ac.uk:80/respub/WEB-INF/jsp/search-html.jsp Request URI: /respub/WEB-INF/jsp/search-html.jsp Query String: id=00345500&limit=30&person=true&page=2&respub-action=search.html