Imperial College London

Prof. David Chadwick

Faculty of EngineeringDepartment of Chemical Engineering

Professor
 
 
 
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Contact

 

+44 (0)20 7594 5579d.chadwick

 
 
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Location

 

235Roderic Hill BuildingSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Khawaji:2021:10.1016/j.cattod.2020.05.012,
author = {Khawaji, M and Graça, I and Ware, E and Chadwick, D},
doi = {10.1016/j.cattod.2020.05.012},
journal = {Catalysis Today},
pages = {257--264},
title = {Catalytic oxidation of glucose over highly stable AuxPdy NPs immobilised on ceria nanorods},
url = {http://dx.doi.org/10.1016/j.cattod.2020.05.012},
volume = {365},
year = {2021}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - The catalytic performance of AuxPdy nanoparticles prepared by colloidal synthesis and immobilised on ceria nanorods (Ce-NR) in the selective oxidation of glucose has been studied under initially basic and relatively mild conditions. Activity was found to be strongly dependent on the bimetallic composition with Au-rich catalysts being more active in glucose oxidation. Catalyst recycling revealed negligible deactivation or metal loss from leaching, and continuing high selectivity to gluconic acid (≥97.7%). Defects on the Ce-NR surface appear to serve as anchoring sites for Au-Pd NPs giving rise to small and very stable NPs.
AU - Khawaji,M
AU - Graça,I
AU - Ware,E
AU - Chadwick,D
DO - 10.1016/j.cattod.2020.05.012
EP - 264
PY - 2021///
SN - 0920-5861
SP - 257
TI - Catalytic oxidation of glucose over highly stable AuxPdy NPs immobilised on ceria nanorods
T2 - Catalysis Today
UR - http://dx.doi.org/10.1016/j.cattod.2020.05.012
UR - https://www.sciencedirect.com/science/article/pii/S0920586120302911?via%3Dihub
UR - http://hdl.handle.net/10044/1/82851
VL - 365
ER -