Publications
110 results found
Craig D, Spreadbury SRJ, White AJP, 2020, Synthesis and hetero-diels–alder reactions of enantiomerically pure dihydro-1H-azepines, Chemical Communications, Vol: 56, Pages: 9803-9806, ISSN: 1359-7345
Thermolysis of enantiomerically pure 3-substituted 7,7-dihalo-2-azabicyclo[4.1.0]heptanes in the presence of K2CO3 gives in good yields 2-alkyl-6-halo-1-tosyl-2,3-dihydro-1H-azepines. These undergo highly stereoselective [4+2] cycloaddition reactions with heterodienophiles and arylation/alkenylation under Suzuki conditions.
Craig D, Goldberg FW, Pett RW, et al., 2013, Aziridine-based Concise Synthesis of (±)-Alstonerine, Chemical Communications, Vol: 49, Pages: 9275-9277, ISSN: 1359-7345
A concise synthesis of the macroline-related alkaloid (±)-alstonerine 1 is reported. Key steps are regioselective and stereospecific aziridine ring-opening using a sulfone-stabilised carbanion, Me3Al-meditaed O → N-transacylation–elimination, intramolecular Michael reaction, and one-pot reduction–dehydration–Pictet–Spengler cyclisation.
Craig D, 2013, Creating Complexity, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, Vol: 9, Pages: 1881-1882, ISSN: 1860-5397
Partridge S, Craig D, Lucas A, 2011, Toward the total synthesis of 1a,25-dihydroxylumisterol, 242nd National Meeting of the American-Chemical-Society (ACS), Publisher: AMER CHEMICAL SOC, ISSN: 0065-7727
Camp JE, Craig D, Funai K, et al., 2011, Decarboxylative Claisen rearrangement reactions: synthesis and reactivity of alkylidene-substituted indolines, ORGANIC & BIOMOLECULAR CHEMISTRY, Vol: 9, Pages: 7904-7912, ISSN: 1477-0520
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- Citations: 16
Craig D, Funai K, Gore SJ, et al., 2011, Transannular Claisen rearrangement reactions for the synthesis of vinylcyclobutanes: formal synthesis of (+/-)-grandisol, ORGANIC & BIOMOLECULAR CHEMISTRY, Vol: 9, Pages: 8000-8002, ISSN: 1477-0520
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- Citations: 9
Craig D, Harvey JW, O'Brien AG, et al., 2011, Claisen rearrangements of equilibrating allylic azides, ORGANIC & BIOMOLECULAR CHEMISTRY, Vol: 9, Pages: 7057-7061, ISSN: 1477-0520
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- Citations: 26
Chahal JK, Craig D, Smethurst CA, et al., 2011, Facile Diels-Alder dimerisation of a vinyloxepin synthesised using intramolecular ene-yne metathesis, ARKIVOC, Pages: 127-139, ISSN: 1551-7004
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- Citations: 3
Craig D, Harvey JW, O'Brien AG, et al., 2010, Exopericyclic stereocontrol in Johnson-Claisen rearrangements of allylic sulfides, CHEMICAL COMMUNICATIONS, Vol: 46, Pages: 6932-6934, ISSN: 1359-7345
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- Citations: 6
Craig D, Lu P, Mathie T, et al., 2010, Directed addition of sulfur-stabilised carbanions to 1,2,3-trisubstituted aziridines, Tetrahedron, Vol: 66, Pages: 6376-6382, ISSN: 0040-4020
Thioether and sulfone-stabilised carbanions possessing varying functional groups enter into highly regioselective, stereospecific ring-opening reactions with vinyl- and hydroxymethyl-substituted aziridines. Some derivatisation reactions of the adducts are reported.
Craig D, Lu P, White AJP, 2010, Highly diastereoselective allylation reactions of dilithiated 4-(phenylsulfonyl)-cyclopent-2-enol, TETRAHEDRON LETTERS, Vol: 51, Pages: 99-101, ISSN: 0040-4039
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- Citations: 1
Craig D, Gore SJ, Lansdell MI, et al., 2010, Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes, CHEMICAL COMMUNICATIONS, Vol: 46, Pages: 4991-4993, ISSN: 1359-7345
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- Citations: 16
Camp JE, Craig D, 2009, Reactivity of dearomatised furans synthesised via the decarboxylative Claisen rearrangement, TETRAHEDRON LETTERS, Vol: 50, Pages: 3503-3508, ISSN: 0040-4039
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- Citations: 15
Carballares S, Craig D, Hyland CJT, et al., 2009, Highly regioselective ring-opening of trisubstituted aziridines by sulfur-stabilised carbanions, CHEMICAL COMMUNICATIONS, Pages: 451-453, ISSN: 1359-7345
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- Citations: 8
Ley SV, Abad-Somovilla A, Anderson JC, et al., 2008, The Synthesis of Azadirachtin: A Potent Insect Antifeedant, CHEMISTRY-A EUROPEAN JOURNAL, Vol: 14, Pages: 10683-10704, ISSN: 0947-6539
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- Citations: 49
Craig D, Paina F, Smith SC, 2008, Double decarboxylative Claisen rearrangement reactions: microwave-assisted de novo synthesis of pyridines, CHEMICAL COMMUNICATIONS, Pages: 3408-3410, ISSN: 1359-7345
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- Citations: 20
Craig D, Slavov NK, 2008, A quantitative structure-reactivity relationship in decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters, CHEMICAL COMMUNICATIONS, Pages: 6054-6056, ISSN: 1359-7345
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- Citations: 11
Berry MB, Craig D, Jones PS, et al., 2007, The enantiospecific synthesis of (+)-monomorine I using a 5-endo-trig cyclisation strategy, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, Vol: 3, ISSN: 1860-5397
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- Citations: 8
Craig D, Lansdell MI, Lewis SE, 2007, Highly regioselective decarboxylative Claisen rearrangement reactions of diallyl 2-sulfonylmalonates, TETRAHEDRON LETTERS, Vol: 48, Pages: 7861-7864, ISSN: 0040-4039
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- Citations: 11
Caldwell JJ, Craig D, 2007, Sulfone-mediated total synthesis of (+/-)-lepadiformine, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Vol: 46, Pages: 2631-2634, ISSN: 1433-7851
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- Citations: 52
Caldwell JJ, Craig D, East SP, 2007, Application of a 5-endo-trig cyclisation in the total synthesis of (+)-preussin, ARKIVOC, Pages: 67-90, ISSN: 1551-7004
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- Citations: 13
Craig D, King NP, Mountford DM, 2007, Silyl-modified Bellus-Claisen rearrangement, CHEMICAL COMMUNICATIONS, Pages: 1077-1079, ISSN: 1359-7345
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- Citations: 16
Craig D, Hyland CJT, Ward SE, 2006, Stereoselective synthesis of (-)-trachelanthamidine via palladium-catalysed intramolecular allylation, SYNLETT, Pages: 2142-2144, ISSN: 0936-5214
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- Citations: 19
Craig D, Henry GD, 2006, Total synthesis of the cytotoxic guaipyridine sesquiterpene alkaloid (+)-cananodine, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Vol: 2006, Pages: 3558-3561, ISSN: 1434-193X
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- Citations: 26
Bourgeois D, Craig D, Grellepois F, et al., 2006, A [3,3]-sigmatropic process catalysed by acetate. The decarboxylative Claisen rearrangement, TETRAHEDRON, Vol: 62, Pages: 483-495, ISSN: 0040-4020
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- Citations: 19
Craig D, King NP, Kley JT, et al., 2005, Heteroaromatic decarboxylative claisen rearrangement reactions, SYNTHESIS-STUTTGART, Pages: 3279-3282, ISSN: 0039-7881
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- Citations: 10
Craig D, Grellepois F, White AJP, 2005, Asymmetric decarboxylative Claisen rearrangement reactions of sulfoximine-substituted allylic tosylacetic esters, JOURNAL OF ORGANIC CHEMISTRY, Vol: 70, Pages: 6827-6832, ISSN: 0022-3263
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- Citations: 40
Cox P, Craig D, Ioannidis S, et al., 2005, 4-(phenylsulfonyl)-4-lithiocyclopentene as a nucleophilic 2-pentene-1,5-dial synthetic equivalent. An aziridine-based synthetic approach to (-)-alstonerine, TETRAHEDRON LETTERS, Vol: 46, Pages: 4687-4690, ISSN: 0040-4039
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- Citations: 16
Bonfanti JF, Craig D, 2005, Synthesis of substituted dihydrobenzothiopyrans and dihydrobenzopyrans by cation-mediated cyclisation reactions, TETRAHEDRON LETTERS, Vol: 46, Pages: 3719-3723, ISSN: 0040-4039
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- Citations: 5
Craig D, Henry GD, 2005, Sulfone-mediated synthesis of polysubstituted pyridines, TETRAHEDRON LETTERS, Vol: 46, Pages: 2559-2562, ISSN: 0040-4039
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- Citations: 28
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