Imperial College London
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Professor David W. McComb

Faculty of Engineering, Department of Materials

Adjunct Professor
 
 
 
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Contact

 

+44 (0)20 7594 6750d.mccomb Website

 
 
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Location

 

Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Londo:2020:10.1021/acs.jpcc.0c03736,
author = {Londo, S and Biswas, S and Husek, J and Pinchuk, IV and Newburger, MJ and Boyadzhiev, A and Trout, AH and McComb, DW and Kawakami, R and Baker, LR},
doi = {10.1021/acs.jpcc.0c03736},
journal = {Journal of Physical Chemistry C},
pages = {11368--11375},
title = {Ultrafast Spin Crossover in a Room-Temperature Ferrimagnet: Element-Specific Spin Dynamics in Photoexcited Cobalt Ferrite},
url = {http://dx.doi.org/10.1021/acs.jpcc.0c03736},
volume = {124},
year = {2020}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Transition metal complexes capable of photoinduced spin crossover have been widely investigated because of their potential to enable ultrafast optical control of information processing. However, any real application of photoswitchable molecules requires that spin crossover be paired with additional functionality such as long-range magnetic order. Important advances combining these functions are notably reported for a number of bimetallic Prussian Blue analogues; however, to date, PBA-based magnetic photoswitches can only operate below 150 K due to loss of magnetic order. In contrast, cobalt ferrite is a ferrimagnetic semiconductor with a Curie temperature of 790 K and extremely favorable magnetic properties by comparison to state-of-the-art PBAs. The mixed valence electronic structure of cobalt ferrite is reminiscent of cobalt-iron PBA, which is a well-known photoswitch. To investigate the potential for photoswitching in this material, we employ transient XUV spectroscopy to probe charge and spin dynamics with element-specific resolution on the femtosecond time scale. Results show that 400 nm light excites a metal-to-metal charge transfer transition, which drives the crossover of high-spin Co2+ to low-spin Co3+ with a time constant of 405 ± 29 fs and an internal quantum efficiency of unity. This result establishes the existence of efficient photoswitching in a new class of robust ferrimagnetic spinel ferrites.
AU  - Londo,S
AU  - Biswas,S
AU  - Husek,J
AU  - Pinchuk,IV
AU  - Newburger,MJ
AU  - Boyadzhiev,A
AU  - Trout,AH
AU  - McComb,DW
AU  - Kawakami,R
AU  - Baker,LR
DO  - 10.1021/acs.jpcc.0c03736
EP  - 11375
PY  - 2020///
SN  - 1932-7447
SP  - 11368
TI  - Ultrafast Spin Crossover in a Room-Temperature Ferrimagnet: Element-Specific Spin Dynamics in Photoexcited Cobalt Ferrite
T2  - Journal of Physical Chemistry C
UR  - http://dx.doi.org/10.1021/acs.jpcc.0c03736
VL  - 124
ER  -
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