Imperial College London
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Dr Florian Glöcklhofer

Faculty of Natural Sciences, Department of Chemistry

Visiting Researcher
 
 
 
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Contact

 

f.glocklhofer Website

 
 
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Location

 

Molecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Glöcklhofer:2014:10.1107/s1600536814013762,
author = {Glöcklhofer, F and Fröhlich, J and Stöger, B and Weil, M},
doi = {10.1107/s1600536814013762},
journal = {Acta Crystallographica Section E Structure Reports Online},
pages = {39--42},
title = {Crystal structures of 2,5-diazido-1,4-phenylene diacetate and 2,5-diazido-1,4-phenylene dibutyrate},
url = {http://dx.doi.org/10.1107/s1600536814013762},
volume = {70},
year = {2014}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - <jats:p>The asymmetric units of the title compounds, C<jats:sub>10</jats:sub>H<jats:sub>8</jats:sub>N<jats:sub>6</jats:sub>O<jats:sub>4</jats:sub>, (I), and C<jats:sub>14</jats:sub>H<jats:sub>16</jats:sub>N<jats:sub>6</jats:sub>O<jats:sub>4</jats:sub>, (II), each contain half of the respective molecule which is completed by inversion symmetry. The two molecules differ in the ester moiety (acetate<jats:italic>versus</jats:italic>butyrate) and the crystal symmetry is different,<jats:italic>i.e.</jats:italic>triclinic for (I) and monoclinic for (II). The diazidophenylene moieties are essentially planar [maximum deviation of 0.0216(7)Å for (I) and 0.0330(14)Å for (II)], and the ester functionalities are almost perpendicular to these planes, making dihedral angles of 79.93(3)° for (I) and 79.42(6)° for (II). In the crystals of both (I) and (II), there are no significant intermolecular interactions present.</jats:p>
AU  - Glöcklhofer,F
AU  - Fröhlich,J
AU  - Stöger,B
AU  - Weil,M
DO  - 10.1107/s1600536814013762
EP  - 42
PY  - 2014///
SP  - 39
TI  - Crystal structures of 2,5-diazido-1,4-phenylene diacetate and 2,5-diazido-1,4-phenylene dibutyrate
T2  - Acta Crystallographica Section E Structure Reports Online
UR  - http://dx.doi.org/10.1107/s1600536814013762
UR  - http://hdl.handle.net/10044/1/79494
VL  - 70
ER  -
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