Imperial College London

ProfessorGeoffreyMaitland

Faculty of EngineeringDepartment of Chemical Engineering

Professor of Energy Engineering
 
 
 
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Contact

 

+44 (0)20 7594 1830g.maitland Website

 
 
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Assistant

 

Mrs Sarah Payne +44 (0)20 7594 5567

 
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Location

 

401ACE ExtensionSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Hou:2014:10.1016/j.fluid.2014.12.022,
author = {Hou, S-X and Maitland, GC and Trusler, JPM},
doi = {10.1016/j.fluid.2014.12.022},
journal = {Fluid Phase Equilibria},
pages = {111--116},
title = {Phase equilibria of (CO2 + butylbenzene) and (CO2 + butylcyclohexane) at temperatures between (323.15 and 423.15) K and at pressures up to 21 MPa},
url = {http://dx.doi.org/10.1016/j.fluid.2014.12.022},
volume = {387},
year = {2014}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Experimental measurements of the phase equilibria of (CO2 + butylbenzene) and (CO2 + butylcyclohexane) have been made with an analytical apparatus at temperatures of (323.15, 373.15 and 423.15) K at pressures from 2 MPa to the mixture critical pressure. These are the first results to be published for (CO2 + butylcyclohexane), while for (CO2 + butylbenzene) they are the first at pressures above 6 MPa. To model the data, we use the Peng–Robinson equation of state with Wong–Sandler mixing rules incorporating the NRTL equation. The model describes the measured bubble point curves very well at all temperatures, except close to the mixture critical points at high pressures. The dew point curves are described well only at the lowest temperature; otherwise, deviations increase in the approach to the mixture critical point.
AU - Hou,S-X
AU - Maitland,GC
AU - Trusler,JPM
DO - 10.1016/j.fluid.2014.12.022
EP - 116
PY - 2014///
SN - 0378-3812
SP - 111
TI - Phase equilibria of (CO2 + butylbenzene) and (CO2 + butylcyclohexane) at temperatures between (323.15 and 423.15) K and at pressures up to 21 MPa
T2 - Fluid Phase Equilibria
UR - http://dx.doi.org/10.1016/j.fluid.2014.12.022
UR - http://hdl.handle.net/10044/1/23578
VL - 387
ER -