Publications

BibTex format

@article{Tan:2020:10.1016/j.electacta.2020.136460,
author = {Tan, S-Y and Hallett, J and Geoff, K},
doi = {10.1016/j.electacta.2020.136460},
journal = {Electrochimica Acta},
pages = {1--11},
title = {Electrodeposition of lead from methanesulfonic acid and methanesulfonate ionic liquid derivatives},
url = {http://dx.doi.org/10.1016/j.electacta.2020.136460},
volume = {353},
year = {2020}
}

Download

RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The influence is reported of electrolyte composition on the electrochemistry of PbII and electrodeposition morphology of Pb in aqueous methanesulfonic acid (MSA) and two methanesulfonate-based ionic liquids: 1-butyl-3-methylimidazolium methanesulfonate and N,N-dimethylbutylammonium methanesulfonate. Cyclic voltammetry and chronoamperometry indicated that the reduction of PbII ions to Pb was a diffusion-controlled process proceeding via a two-electron transfer process at -0.67 V vs. Ag (1 M MSA) and involved 3-D progressive nucleation. Scanning electron microscopy showed a strong influence of deposition potential and electrolyte composition on the morphology of Pb deposits. Experimental data was used to model predictions of the specific electrical energy consumption for cathodic PbII electrodeposition coupled with either anodic oxygen evolution or PbO2 electrodeposition.
AU  - Tan,S-Y
AU  - Hallett,J
AU  - Geoff,K
DO  - 10.1016/j.electacta.2020.136460
EP  - 11
PY  - 2020///
SN  - 0013-4686
SP  - 1
TI  - Electrodeposition of lead from methanesulfonic acid and methanesulfonate ionic liquid derivatives
T2  - Electrochimica Acta
UR  - http://dx.doi.org/10.1016/j.electacta.2020.136460
UR  - https://www.sciencedirect.com/science/article/pii/S0013468620308537?via%3Dihub
UR  - http://hdl.handle.net/10044/1/79279
VL  - 353
ER  -

Download

Prof Jason P. Hallett

Contact

Location

Summary

Citation

BibTex format

RIS format (EndNote, RefMan)