Imperial College London
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Dr Jarvist Moore Frost

Faculty of Natural Sciences, Department of Chemistry

Royal Society URF (Lecturer)
 
 
 
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Contact

 

jarvist.frost Website

 
 
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Location

 

601FMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Gallop:2018:10.1021/acs.jpclett.8b02227,
author = {Gallop, NP and Selig, O and Giubertoni, G and Bakker, HJ and Rezus, YLA and Frost, JM and Jansen, TLC and Lovrincic, R and Bakulin, AA},
doi = {10.1021/acs.jpclett.8b02227},
journal = {Journal of Physical Chemistry Letters},
pages = {5987--5997},
title = {Rotational cation dynamics in metal halide perovskites: Effect on phonons and material properties},
url = {http://dx.doi.org/10.1021/acs.jpclett.8b02227},
volume = {9},
year = {2018}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The dynamics of organic cations in metal halide hybrid perovskites (MHPs) have been investigated using numerous experimental and computational techniques because of their suspected effects on the properties of MHPs. In this Perspective, we summarize and reconcile key findings and present new data to synthesize a unified understanding of the dynamics of the cations. We conclude that theory and experiment collectively paint a relatively complete picture of rotational dynamics within MHPs. This picture is then used to discuss the consequences of structural dynamics for electron–phonon interactions and their effect on material properties by providing a brief account of key studies that correlate cation dynamics with the dynamics of the inorganic sublattice and overall device properties.
AU  - Gallop,NP
AU  - Selig,O
AU  - Giubertoni,G
AU  - Bakker,HJ
AU  - Rezus,YLA
AU  - Frost,JM
AU  - Jansen,TLC
AU  - Lovrincic,R
AU  - Bakulin,AA
DO  - 10.1021/acs.jpclett.8b02227
EP  - 5997
PY  - 2018///
SN  - 1948-7185
SP  - 5987
TI  - Rotational cation dynamics in metal halide perovskites: Effect on phonons and material properties
T2  - Journal of Physical Chemistry Letters
UR  - http://dx.doi.org/10.1021/acs.jpclett.8b02227
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000448751700012&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - https://pubs.acs.org/doi/10.1021/acs.jpclett.8b02227
UR  - http://hdl.handle.net/10044/1/74271
VL  - 9
ER  -
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