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BibTex format

@article{Hii:2017:10.1080/2055074X.2017.1348711,
author = {Hii, KM and Newton, MA and Nicholls, R and Brazier, JB and Nguyen, BN and Barreiro and Mulligan, C and Hellgardt and Emerich, H and Snigireva, I and Thompson, PBJ},
doi = {10.1080/2055074X.2017.1348711},
journal = {Catalysis, Structure & Reactivity},
pages = {149--156},
title = {Effect of retained chlorine in ENCAT™ 30 catalysts on the development of encapsulated Pd: insights from in situ Pd K, L3 and Cl K-edge XAS},
url = {http://dx.doi.org/10.1080/2055074X.2017.1348711},
volume = {3},
year = {2017}
}

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TY  - JOUR
AB  - In situ X-ray absorption spectroscopy (XAS) and Pd K, LIII, and Cl K-edges shows that Cl can be present in significant amounts in ENCAT™ 30 catalysts and that it can severely retard Pd nanoparticle (NP) development in flowing solvents. We also show that whilst polymeric encapsulation protects the Pd against solvent induced agglomeration of Pd nanoparticles the evidence suggests it does not prevent the formation PdHx through reaction with the aqeous ethanol solvent, and that, as received, ENCAT™ 30 NP catalysts are not, for the most part, comprised of nanoparticulate Pd0 irrespective of the presence of Cl.
AU  - Hii,KM
AU  - Newton,MA
AU  - Nicholls,R
AU  - Brazier,JB
AU  - Nguyen,BN
AU  - Barreiro
AU  - Mulligan,C
AU  - Hellgardt
AU  - Emerich,H
AU  - Snigireva,I
AU  - Thompson,PBJ
DO  - 10.1080/2055074X.2017.1348711
EP  - 156
PY  - 2017///
SN  - 2055-074X
SP  - 149
TI  - Effect of retained chlorine in ENCAT™ 30 catalysts on the development of encapsulated Pd: insights from in situ Pd K, L3 and Cl K-edge XAS
T2  - Catalysis, Structure & Reactivity
UR  - http://dx.doi.org/10.1080/2055074X.2017.1348711
VL  - 3
ER  -

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Prof Klaus Hellgardt

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