Imperial College London

DrKimJelfs

Faculty of Natural SciencesDepartment of Chemistry

Senior Lecturer
 
 
 
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Contact

 

+44 (0)20 7594 3438k.jelfs Website

 
 
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Location

 

207AMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Reiss:2016:10.1002/chem.201603593,
author = {Reiss, PS and Little, MA and Santolini, V and Chong, SY and Hasell, T and Jelfs, KE and Briggs, ME and Cooper, AI},
doi = {10.1002/chem.201603593},
journal = {Chemistry},
pages = {16547--16553},
title = {Periphery-functionalized porous organic cages},
url = {http://dx.doi.org/10.1002/chem.201603593},
volume = {22},
year = {2016}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - By synthesizing derivatives of a trans-1,2-diaminocyclohexane precursor, three new functionalized porous organic cages were prepared with different chemical functionalities on the cage periphery. The introduction of twelve methyl groups (CC16) resulted in frustration of the cage packing mode, which more than doubled the surface area compared to the parent cage, CC3. The analogous installation of twelve hydroxyl groups provided an imine cage (CC17) that combines permanent porosity with the potential for post-synthetic modification of the cage exterior. Finally, the incorporation of bulky dihydroethanoanthracene groups was found to direct self-assembly towards the formation of a larger [8+12] cage, rather than the expected [4+6], cage molecule (CC18). However, CC18 was found to be non-porous, most likely due to cage collapse upon desolvation.
AU - Reiss,PS
AU - Little,MA
AU - Santolini,V
AU - Chong,SY
AU - Hasell,T
AU - Jelfs,KE
AU - Briggs,ME
AU - Cooper,AI
DO - 10.1002/chem.201603593
EP - 16553
PY - 2016///
SN - 0861-9255
SP - 16547
TI - Periphery-functionalized porous organic cages
T2 - Chemistry
UR - http://dx.doi.org/10.1002/chem.201603593
UR - http://hdl.handle.net/10044/1/42077
VL - 22
ER -