Imperial College London
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ProfessorKimJelfs

Faculty of Natural Sciences, Department of Chemistry

Professor in Computational Materials Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 3438k.jelfs Website

 
 
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Location

 

207AMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Kearsey:2023:10.1039/d3cc00072a,
author = {Kearsey, RJ and Tarzia, A and Little, MA and Brand, MC and Clowes, R and Jelfs, KE and Cooper, AI and Greenaway, RL},
doi = {10.1039/d3cc00072a},
journal = {Chemical Communications},
pages = {3731--3734},
title = {Competitive aminal formation during the synthesis of a highly soluble, isopropyl-decorated imine porous organic cage.},
url = {http://dx.doi.org/10.1039/d3cc00072a},
volume = {59},
year = {2023}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The synthesis of a new porous organic cage decorated with isopropyl moieties (CC21) was achieved from the reaction of triformylbenzene and an isopropyl functionalised diamine. Unlike structurally analogous porous organic cages, its synthesis proved challenging due to competitive aminal formation, rationalised using control experiments and computational modelling. The use of an additional amine was found to increase conversion to the desired cage.
AU  - Kearsey,RJ
AU  - Tarzia,A
AU  - Little,MA
AU  - Brand,MC
AU  - Clowes,R
AU  - Jelfs,KE
AU  - Cooper,AI
AU  - Greenaway,RL
DO  - 10.1039/d3cc00072a
EP  - 3734
PY  - 2023///
SN  - 1359-7345
SP  - 3731
TI  - Competitive aminal formation during the synthesis of a highly soluble, isopropyl-decorated imine porous organic cage.
T2  - Chemical Communications
UR  - http://dx.doi.org/10.1039/d3cc00072a
UR  - https://www.ncbi.nlm.nih.gov/pubmed/36896582
UR  - https://pubs.rsc.org/en/content/articlelanding/2023/CC/D3CC00072A
UR  - http://hdl.handle.net/10044/1/103138
VL  - 59
ER  -
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