Imperial College London

ProfessorKangLi

Faculty of EngineeringDepartment of Chemical Engineering

Professor in Chemical Engineering
 
 
 
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Contact

 

+44 (0)20 7594 5676kang.li

 
 
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Location

 

419ACE ExtensionSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Rabuni:2020:10.1016/j.jpowsour.2020.228026,
author = {Rabuni, MF and Vatcharasuwan, N and Li, T and Li, K},
doi = {10.1016/j.jpowsour.2020.228026},
journal = {Journal of Power Sources},
pages = {1--9},
title = {High performance micro-monolithic reversible solid oxide electrochemical reactor},
url = {http://dx.doi.org/10.1016/j.jpowsour.2020.228026},
volume = {458},
year = {2020}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Reversible solid oxide electrochemical reactors should work efficiently in both fuel cell and electrolysis modes in order to be considered a practical technology for the energy field. In addition to improved performance, excellent electrode reversibility and stability for long-term operation are crucial for such reactors. Herein, high-performance 6-channel solid oxide electrochemical reactors for reversible operation has been successfully developed using a phase-inversion and sintering method. A unique morphology has been obtained where micro-channels were formed from multiple directions and the interchangeable thickness of sponge-like region between each channel and the exterior surface. Such micro-structured cells, which is made from commercially-available materials Ni-YSZ|YSZ|YSZ-LSM, exhibit superior performance for hydrogen (H2) fuel cell achieving 1.62 W cm−2 at 800 °C. Similarly, excellent performance for carbon dioxide (CO2) electrolysis has been demonstrated, achieving current densities up to 6.3 (3.1) A cm−2 under 1.8 (1.5) V at 800 °C. To our knowledge, such high performances are one of the highest reported values for both H2-fuel cell and CO2 electrolysis. This outstanding performance, coupled with superior mechanical robustness, promises a long-awaited alternative to the conventional tubular counterpart that would allow miniaturized system to be commercially applied in the near future.
AU - Rabuni,MF
AU - Vatcharasuwan,N
AU - Li,T
AU - Li,K
DO - 10.1016/j.jpowsour.2020.228026
EP - 9
PY - 2020///
SN - 0378-7753
SP - 1
TI - High performance micro-monolithic reversible solid oxide electrochemical reactor
T2 - Journal of Power Sources
UR - http://dx.doi.org/10.1016/j.jpowsour.2020.228026
UR - https://www.sciencedirect.com/science/article/pii/S0378775320303293?via%3Dihub
VL - 458
ER -