Imperial College London

DrLudmillaSteier

Faculty of EngineeringDepartment of Materials

Honorary Lecturer
 
 
 
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Contact

 

l.steier

 
 
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Location

 

Molecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Mesa:2020:10.1021/acs.jpclett.0c02004,
author = {Mesa, CA and Steier, L and Moss, B and Francas, L and Thorne, JE and Grätzel, M and Durrant, JR},
doi = {10.1021/acs.jpclett.0c02004},
journal = {The Journal of Physical Chemistry Letters},
pages = {7285--7290},
title = {Impact of synthesis route on the water oxidation kinetics of hematite photoanodes},
url = {http://dx.doi.org/10.1021/acs.jpclett.0c02004},
volume = {11},
year = {2020}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Operando spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Higher temperature thermal annealing was found to correlate with a shift in the photocurrent onset potential towards less positive potentials, assigned to a suppression of both back electron-hole recombination and of charge accumulation in intraband-gap states, indicating these intraband-gap states do not contribute directly to water oxidation.
AU - Mesa,CA
AU - Steier,L
AU - Moss,B
AU - Francas,L
AU - Thorne,JE
AU - Grätzel,M
AU - Durrant,JR
DO - 10.1021/acs.jpclett.0c02004
EP - 7290
PY - 2020///
SN - 1948-7185
SP - 7285
TI - Impact of synthesis route on the water oxidation kinetics of hematite photoanodes
T2 - The Journal of Physical Chemistry Letters
UR - http://dx.doi.org/10.1021/acs.jpclett.0c02004
UR - https://pubs.acs.org/doi/10.1021/acs.jpclett.0c02004
UR - http://hdl.handle.net/10044/1/81704
VL - 11
ER -