Imperial College London
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Dr F. Mark Chadwick

Faculty of Natural Sciences, Department of Chemistry

Research Fellow
 
 
 
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Contact

 

+44 (0)20 7594 5872m.chadwick

 
 
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Location

 

601KMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Clement:2019:10.1016/j.poly.2018.09.068,
author = {Clement, DD and Binding, SC and Arnold, TAQ and Chadwick, FM and Casely, IJ and Turner, ZR and Buffet, JC and O'Hare, D},
doi = {10.1016/j.poly.2018.09.068},
journal = {Polyhedron},
pages = {146--151},
title = {Synthesis and characterization of permethylpentalene titanium aryloxide and alkoxide complexes},
url = {http://dx.doi.org/10.1016/j.poly.2018.09.068},
volume = {157},
year = {2019}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - © 2018 Elsevier Ltd A series of titanium complexes containing the permethylpentalene ligand (C8Me62−; Pn∗) – Pn∗Ti(O-2,6-Me-C6H3)Cl (1), Pn∗Ti(O-2,4-tBu-C6H3)Cl (2), Pn∗Ti(OtBu)Cl (3), Pn∗Ti(O-2,6-Me-C6H3)2 (4), Pn∗Ti(OtBu)2 (5) – or the (hydro)permethylpentalene ligand (C8Me6H−; Pn∗(H)) – Pn∗(H)Ti(O-2,6-Me-C6H3)Cl2 (6) and Pn∗(H)Ti(O-2,6-Me2-C6H3)3 (7) – were prepared by the reaction of [Pn∗TiCl(μ-Cl)]2 with the corresponding potassium salt or alcohol. All complexes have been characterized by single crystal X-ray diffraction studies and NMR spectroscopy. The (hydro)permethylpentalene complexes contain a stereocenter and planar chirality which can be described as R,RP or S,SP configurations.
AU  - Clement,DD
AU  - Binding,SC
AU  - Arnold,TAQ
AU  - Chadwick,FM
AU  - Casely,IJ
AU  - Turner,ZR
AU  - Buffet,JC
AU  - O'Hare,D
DO  - 10.1016/j.poly.2018.09.068
EP  - 151
PY  - 2019///
SN  - 0277-5387
SP  - 146
TI  - Synthesis and characterization of permethylpentalene titanium aryloxide and alkoxide complexes
T2  - Polyhedron
UR  - http://dx.doi.org/10.1016/j.poly.2018.09.068
VL  - 157
ER  -
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