Imperial College London
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Dr F. Mark Chadwick

Faculty of Natural Sciences, Department of Chemistry

Research Fellow
 
 
 
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Contact

 

+44 (0)20 7594 5872m.chadwick

 
 
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Location

 

601KMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Chadwick:2019:10.1002/ange.201813780,
author = {Chadwick, FM and Curchod, BFE and Scopelliti, R and FadaeiTirani, F and Solari, E and Severin, K},
doi = {10.1002/ange.201813780},
journal = {Angewandte Chemie},
pages = {1778--1781},
title = {AzoMICs: RedoxActive Mesoionic Carbene Ligands Derived from Azoimidazolium Dyes},
url = {http://dx.doi.org/10.1002/ange.201813780},
volume = {131},
year = {2019}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - <jats:title>Abstract</jats:title><jats:p>Azoimidazolium dyes were used as precursors for mesoionic carbene ligands (AzoMICs). The properties of these ligands were examined by synthesizing Rh<jats:sup>I</jats:sup>, Au<jats:sup>I</jats:sup>, and Pd<jats:sup>II</jats:sup> complexes. Experimental (NMR, IR) and theoretical investigations show that AzoMICs are potent σdonor ligands. Yet, they feature a small singlet–triplet gap and very lowlying LUMO levels. The unique electronic properties of AzoMICs allow for reversible oneelectron reductions of the metal complexes, as evidenced by cyclic voltammetry.</jats:p>
AU  - Chadwick,FM
AU  - Curchod,BFE
AU  - Scopelliti,R
AU  - FadaeiTirani,F
AU  - Solari,E
AU  - Severin,K
DO  - 10.1002/ange.201813780
EP  - 1781
PY  - 2019///
SN  - 0044-8249
SP  - 1778
TI  - AzoMICs: RedoxActive Mesoionic Carbene Ligands Derived from Azoimidazolium Dyes
T2  - Angewandte Chemie
UR  - http://dx.doi.org/10.1002/ange.201813780
VL  - 131
ER  -
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