Imperial College London
Portrait Picture

Professor Mark R. Crimmin

Faculty of Natural Sciences, Department of Chemistry

Professor of Organometallic Chemistry
 
 
 
//

Contact

 

+44 (0)20 7594 2846m.crimmin Website

 
 
//

Location

 

501NMolecular Sciences Research HubWhite City Campus

//

Summary

 

Publications

Citation

BibTex format

@article{Kong:2019:10.1039/C9CC02818H,
author = {Kong, RY and Crimmin, MR},
doi = {10.1039/C9CC02818H},
journal = {Chem. Commun.},
pages = {6181--6184},
title = {Reversible insertion of CO into an aluminium–carbon bond},
url = {http://dx.doi.org/10.1039/C9CC02818H},
volume = {55},
year = {2019}
}
Download

RIS format (EndNote, RefMan)

TY  - JOUR
AB  - A [2.2.1] aluminium metallobicycle is capable of reversibly inserting CO to form a [2.2.2] metallobicycle at 100 °C. Computational studies reveal a highly asynchronous, but concerted, transition state for CO insertion. The coordination of CO to aluminium precedes C–C bond formation. The reversible migratory insertion of CO at aluminium thus mimics well-established transition-metal reactivity.
AU  - Kong,RY
AU  - Crimmin,MR
DO  - 10.1039/C9CC02818H
EP  - 6184
PY  - 2019///
SP  - 6181
TI  - Reversible insertion of CO into an aluminium–carbon bond
T2  - Chem. Commun.
UR  - http://dx.doi.org/10.1039/C9CC02818H
UR  - http://hdl.handle.net/10044/1/70195
VL  - 55
ER  -
Download